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We investigate magic-wavelength trapping of ultracold bialkali molecules in the vicinity of weak optical transitions from the vibrational ground state of the X$^1\Sigma^+$ potential to low-lying rovibrational states of the b$^3\Pi_0$…

Quantum Physics · Physics 2021-04-14 Q. Guan , S. L. Cornish , S. Kotochigova

We report results of ab initio calculation of the spin-rotational Hamiltonian parameters including P- and P,T-odd terms for the BaF molecule. The ground state wave function of BaF molecule is found with the help of the Relativistic…

Atomic Physics · Physics 2009-10-30 M. Kozlov , A. Titov , N. Mosyagin , P. Souchko

We investigate a system of two polarized molecules in a layered trap. The molecules reside in adjacent layers and interact purely via the dipole-dipole interaction. We determine the properties of the ground state of the system as a function…

Atomic and Molecular Clusters · Physics 2011-06-01 D. V. Fedorov , J. R. Armstrong , N. T. Zinner , A. S. Jensen

The scattering and spectroscopic properties of molecular halo states can serve as sensitive probes of the constancy of the electron-to-proton mass ratio $\beta=m_e/m_p$. Since halo states are formed by resonant $s$-wave interactions, their…

Chemical Physics · Physics 2019-05-14 Alec Owens , Vladimir Špirko

Based on a simplest molecular orbital theory of H$_{2}^{+}$, a three-parameter model potential function is proposed to describe ground-state diatomic systems with closed-shell and/or S-type valence-shell constituents over a significantly…

Chemical Physics · Physics 2009-11-11 Rui-Hua Xie , Jiangbin Gong

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

The vibrational motion equations of both homo and hetero-nuclei diatomic molecules are here derived for the first time. A diatomic molecule is first considered as a one dimensional quantum mechanics oscillator. The second and third-order…

Quantum Physics · Physics 2015-09-01 Jafar Jahanpanah , Mohsen Esmaeilzadeh

We consider the quantum entanglement of the electronic and vibrational degrees of freedom in molecules with a tendency towards double welled potentials using model coupled harmonic diabatic potential-energy surfaces. The von Neumann entropy…

Quantum Physics · Physics 2012-02-24 Laura K. McKemmish , Ross H. McKenzie , Noel S. Hush , Jeffrey R. Reimers

We argue that the results proposed recently for the $\mathrm{a}^3\Sigma_u^+$ electronic state of $^7\mathrm{Li}_2$ do not exhibit any physical utility because the canonical vibrational partition function for an excited electronic state…

Chemical Physics · Physics 2021-12-21 Francisco M. Fernández

A beam of diatomic molecules scattered off a standing wave laser mode splits according to the rovibrational quantum state of the molecules. Our numerical calculation shows that single state resolution can be achieved by properly tuned,…

Quantum Physics · Physics 2009-11-06 P. Domokos , T. Kiss , J. Janszky

Dynamic perturbation equations are derived for a generic stationary state of an elastic string model -- of the kind appropriate for representing a superconducting cosmic string -- in a flat background. In the case of a circular equilibrium…

High Energy Physics - Theory · Physics 2009-11-10 Brandon Carter , Xavier Martin

Peculiarities of the intermolecular rovibrational quantum dynamics of the methane-argon complex are studied using a new, ab initio potential energy surface [Y. N. Kalugina, S. E. Lokshtanov, V. N. Cherepanov, and A. A. Vigasin, J. Chem.…

Chemical Physics · Physics 2019-06-26 Dávid Ferenc , Edit Mátyus

Torque is ubiquitous in many molecular systems, including collisions, chemical reactions, vibrations, electronic excitations and especially rotor molecules. We present a straightforward theoretical method based on forces acting on atoms and…

Chemical Physics · Physics 2016-11-23 Rui-Qin Zhang , Yan-Ling Zhao , Fei Qi , Klaus Hermann , Michel A. Van Hove

Optical trapping of molecules with long coherence times is crucial for many protocols in quantum information and metrology. However, the factors that limit the lifetimes of the trapped molecules remain elusive and require improved…

Atomic Physics · Physics 2020-10-14 K. H. Leung , I. Majewska , H. Bekker , C. -H. Lee , E. Tiberi , S. S. Kondov , R. Moszynski , T. Zelevinsky

We experimentally study the optical- and terahertz- induced rotational dynamics of asymmetric molecules in the gas phase. Terahertz and optical fields are identified as two distinct control handles over asymmetric molecules, as they couple…

Chemical Physics · Physics 2016-09-07 Ran Damari , Shimshon Kallush , Sharly Fleischer

We provide analytical results for the perturbative correction to the current-voltage relation through a vibrating molecule for weak electron-phonon coupling. The nonlinear conductance exhibits a step-like feature at $eV=\hbar \omega_0$,…

Mesoscale and Nanoscale Physics · Physics 2008-03-14 R. Egger , A. O. Gogolin

In collisions at ultralow temperatures, molecules will possess Feshbach resonances, foreign to ultracold atoms, whose virtual excited states consist of rotations of the molecules. We estimate the mean spacing and mean widths of these…

Atomic Physics · Physics 2009-11-07 J. L. Bohn , A. V. Avdeenkov , M. P. Deskevich

Using the method of breaking of circular symmetry and of subsequent symmetry restoration via projection techiques, we present calculations for the ground-state energies and excitation spectra of N-electron parabolic quantum dots in strong…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Yuesong Li , Constantine Yannouleas , Uzi Landman

According to the Schiff theorem, the atomic electrons completely screen the atomic nucleus from an external static electric field. However, this is not the case if the field is time-dependent. Electronic orbitals in atoms either shield the…

Atomic Physics · Physics 2019-01-30 H. B. Tran Tan , V. V. Flambaum , I. B. Samsonov

We study the motion of a charged particle around a weakly magnetized rotating black hole. We classify the fate of a charged particle kicked out from the innermost stable circular orbit. We find that the final fate of the charged particle…

General Relativity and Quantum Cosmology · Physics 2015-09-03 Ryo Shiose , Masashi Kimura , Takeshi Chiba