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We formulate statistical mechanics based on a pure quantum state, which we call a ``thermal pure quantum (TPQ) state''. A single TPQ state gives not only equilibrium values of mechanical variables, such as magnetization and correlation…

Statistical Mechanics · Physics 2017-08-23 Sho Sugiura , Akira Shimizu

We introduce a machine-learning density-functional-theory formalism for the spinless Hubbard model in one dimension at both zero and finite temperature. In the zero-temperature case this establishes a one-to-one relation between the site…

Strongly Correlated Electrons · Physics 2021-06-16 James Nelson , Rajarshi Tiwari , Stefano Sanvito

The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…

Quantum Physics · Physics 2014-10-28 Michał Horodecki , Jonathan Oppenheim

In this study, variations with respect to temperature of the increments of enthalpy and Gibbs energy, arising in the dissolution of proteins in water, have been investigated by the methods of statistical thermodynamics. In this formalism,…

Statistical Mechanics · Physics 2007-05-23 G. Oylumluoglu , F. Buyukkilic , D. Demirhan

Thermodynamics (in concert with its sister discipline, statistical physics) can be regarded as a data reduction scheme based on partitioning a total system into a subsystem and a bath that weakly interact with each other. The ubiquity and…

Statistical Mechanics · Physics 2009-11-11 David Ford , Steven Huntsman

We explore the thermodynamics of quantum processes (quantum channels) by axiomatically introducing the free energy for channels, defined via the quantum relative entropy with an absolutely thermal channel whose fixed output is in…

Quantum Physics · Physics 2026-01-23 Himanshu Badhani , Dhanuja G. S. , Siddhartha Das

Foundations of thermodynamics in special theory of relativity are considered. We argue that from the phenomenological point of view the correct relativistic transformations of heat and absolute temperature are given by the formulae proposed…

Statistical Mechanics · Physics 2015-05-20 Maciej Przanowski , Jaromir Tosiek

Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…

General Physics · Physics 2009-11-13 David Sands

We formulate thermodynamics of economic systems in terms of an arbitrary probability distribution for a conserved economic quantity. As in statistical physics, thermodynamic macroeconomic variables emerge as the mean value of microeconomic…

Statistical Finance · Quantitative Finance 2011-05-26 H. Quevedo , M. N. Quevedo

Starting from an algebraic approach of quantum physics it has been shown via the Tomita-Takesaki theorem and the KMS condition that the canonical density matrix contains the dynamics of the system provided we use a rescaling of time. In…

Statistical Mechanics · Physics 2009-02-06 J. P. Badiali

We provide an exact expression of the moment of the partition function for random energy models of finite system size, generalizing an earlier expression for a grand canonical version of the discrete random energy model presented by the…

Disordered Systems and Neural Networks · Physics 2009-11-13 Kenzo Ogure , Yoshiyuki Kabashima

We derive a necessary and sufficient condition for the thermalization of a local observable in a closed quantum system which offers an alternative explanation, independent of the eigenstate thermalization hypothesis, for the thermalization…

Statistical Mechanics · Physics 2014-04-11 J. Sirker , N. P. Konstantinidis , F. Andraschko , N. Sedlmayr

Consider an FPU chain composed of $N\gg 1$ particles, and endow the phase space with the Gibbs measure corresponding to a small temperature $\beta^{-1}$. Given a fixed $K<N$, we construct $K$ packets of normal modes whose energies are…

Mathematical Physics · Physics 2015-06-16 Alberto Maiocchi , Dario Bambusi , Andrea Carati

Thermodynamic stability of statistical systems requires that susceptibilities be semipositive and finite. Susceptibilities are known to be related to the fluctuations of extensive observable quantities. This relation becomes nontrivial,…

Statistical Mechanics · Physics 2009-11-11 V. I. Yukalov

I argue here that both the first and second laws of thermodynamics, generally understood to be quintessentially physical in nature, can be equally well described as being about certain types of information without the need to invoke…

Data Analysis, Statistics and Probability · Physics 2013-10-02 V. J. Vieland

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

This paper investigates whether the framework of fractional quantum mechanics can broaden our perspective of black hole thermodynamics. Concretely, we employ a {\it space-fractional} derivative \cite{Rie} as our main tool. Moreover, we…

General Relativity and Quantum Cosmology · Physics 2021-07-27 S. Jalalzadeh , F. Rodrigues da Silva , P. V. Moniz

We investigate the probability distribution of the quantum fluctuations of thermodynamic functions of finite, ballistic, phase-coherent Fermi gases. Depending on the chaotic or integrable nature of the underlying classical dynamics, on the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 P. Leboeuf , A. G. Monastra

The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…

Quantum Physics · Physics 2015-05-18 X. L. Huang , B. Cui , X. X. Yi