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Maxwell's velocity distribution is known to be universally valid across systems and phases. Here we present a new and general derivation that uses the central limit theorem (CLT) of the probability theory. This essentially uses the idea…

Statistical Mechanics · Physics 2022-06-13 Sangita Mondal , Biman Bagchi

An alternative equilibrium stochastic dynamics for a Brownian particle in inhomogeneous space is derived. Such a dynamics can model the motion of a complex molecule in its conformation space when in equilibrium with a uniform heat bath. The…

Statistical Mechanics · Physics 2016-12-20 A. Bhattacharyay

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate…

Statistical Mechanics · Physics 2008-07-11 Peter Talkner , Peter Hanggi , Manuel Morillo

We build solutions to Kac's particle system and show that their empirical measures converge to the solution of the space-homogeneous Boltzmann equation in the regime of very soft potentials. This proves propagation of chaos for the last…

Analysis of PDEs · Mathematics 2026-04-16 Côme Tabary

A simplified relativistic kinetic theory for gases with internal degrees of freedom, based on a BGK-type collision term, is considered. First the Boltzmann equation is rewritten in tetrad form and then thermal coefficients are determined to…

General Relativity and Quantum Cosmology · Physics 2026-04-13 Philip Semrén , Michael Bradley , João M. S. Oliveira , M. Piedade Machado Ramos

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

Weak solutions to the homogeneous Boltzmann equation with increasing energy have been constructed by Lu and Wennberg. We consider an underlying microscopic stochastic model with binary collision (Kac's model) and show that these solutions…

Mathematical Physics · Physics 2022-03-31 Giada Basile , Dario Benedetto , Lorenzo Bertini , Emanuele Caglioti

Consider the linear Boltzmann equation of radiative transfer in a half-space, with constant scattering coefficient $\sigma$. Assume that, on the boundary of the half-space, the radiation intensity satisfies the Lambert (i.e. diffuse)…

Analysis of PDEs · Mathematics 2018-09-18 Claude Bardos , François Golse , Iván Moyano

Understanding how systems respond to external perturbations is a fundamental challenge in physics, particularly for non-equilibrium and non-stationary processes. The fluctuation-dissipation theorem provides a complete framework for…

Statistical Mechanics · Physics 2026-05-06 Jiming Zheng , Zhiyue Lu

The Markovian diffusion theory in the phase space is generalized within the framework of the general theory of relativity. The introduction of moving orthonormal frame vectors both for the position as well the velocity space enables to…

General Relativity and Quantum Cosmology · Physics 2014-11-20 Joachim Herrmann

In this paper we propose a novel approach to construct macroscopic balance equations and constitutive equations describing various irreversible phenomena. It is based on the general principles of non-equilibrium thermodynamics and consists…

Statistical Mechanics · Physics 2014-11-27 Liu Hong , Zaibao Yang , Yi Zhu , Wen-An Yong

The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…

Statistical Mechanics · Physics 2008-11-01 Giovanni Gallavotti

Based on a cocycle structure, we identify a new derivation of the Boltzmann distribution for finite energy-level systems from the maximal entropy principle (MEP). Our approach does not rely on the method of the Lagrange multiplier, and it…

Statistical Mechanics · Physics 2025-12-30 Chuan-Tsung Chan , Chan-Yi Chang , Zhong-Tang Wu

A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…

Statistical Mechanics · Physics 2009-10-31 R. K. P. Zia , L. B. Shaw , B. Schmittmann , R. J. Astalos

This paper studies the large time behavior of aggregation-diffusion equations. For one spatial dimension with certain assumptions on the interaction potential, the diffusion index $m$, and the initial data, we prove the convergence to the…

Analysis of PDEs · Mathematics 2021-08-23 Ruiwen Shu

In this paper, we consider the spatially inhomogeneous diffusively driven inelastic Boltzmann equation in different cases: the restitution coefficient can be constant or can depend on the impact velocity (which is a more physically relevant…

Analysis of PDEs · Mathematics 2015-12-04 Isabelle Tristani

It is well known that ergodic theory can be used to formally prove a weak form of relaxation to equilibrium for finite, mixing, Hamiltonian systems. In this Letter we extend this proof to any dynamics that preserves a mixing equilibrium…

Statistical Mechanics · Physics 2018-12-18 Denis J. Evans , Stephen R. Williams , Lamberto Rondoni , Debra J. Searles

We derive a theoretical model which describes Bose-Einstein condensation in an open driven-dissipative system. It includes external pumping of a thermal reservoir, finite life time of the condensed particles and energy relaxation. The…

Quantum Gases · Physics 2015-06-17 D. D. Solnyshkov , H. Terças , K. Dini , G. Malpuech

This note proves an upper bound for the fluctuations of a second-class particle in the totally asymmetric simple exclusion process. The proof needs a lower tail estimate for the last-passage growth model associated with the exclusion…

Probability · Mathematics 2007-05-23 Timo Seppalainen