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We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that: (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square…

Analysis of PDEs · Mathematics 2022-08-26 Thierry Bodineau , Isabelle Gallagher , Laure Saint-Raymond , Sergio Simonella

We introduce a variational formulation of the homogeneous Boltzmann equation, with hard-sphere cross section, which selects the unique energy conserving solution. We prove that this solution arises from the microscopic dynamics, namely…

Mathematical Physics · Physics 2026-04-09 Giada Basile , Dario Benedetto , Carlo Orrieri

We prove an inequality on the Wasserstein distance with quadratic cost between two solutions of the spatially homogeneous Boltzmann equation without angular cutoff, from which we deduce some uniqueness results. In particular, we obtain a…

Analysis of PDEs · Mathematics 2009-11-13 Nicolas Fournier , Hélène Guérin

An ensemble of classical subsystems interacting with surrounding particles has been considered. In general case, a phase volume of the subsystems ensemble was shown to be a function of time. The evolutional equations of the ensemble are…

Statistical Mechanics · Physics 2015-06-24 S. R. Sharov

In ordinary statistical mechanics the Boltzmann-Shannon entropy is related to the Maxwell-Bolzmann distribution $p_i$ by means of a twofold link. The first link is differential and is offered by the Jaynes Maximum Entropy Principle. The…

Statistical Mechanics · Physics 2009-10-02 G. Kaniadakis

The entropy definition in the microcanonical ensemble is revisited. We propose a novel definition for the microcanonical entropy that resolve the debate on the correct definition of the microcanonical entropy. In particular we show that…

Statistical Mechanics · Physics 2019-08-15 Roberto Franzosi

Plastino and Curado [Phys. Rev. E 72, 047103 (2005)] recently determined the equilibrium probability distribution for the canonical ensemble using only phenomenological thermodynamical laws as an alternative to the entropy maximization…

Statistical Mechanics · Physics 2015-05-27 Thomas Oikonomou , Gokhan Baris Bagci , Ugur Tirnakli

We calculate the probability distribution of work for an exactly solvable model of a system interacting with its environment. The system of interest is a harmonic oscillator with a time dependent control parameter, the environment is…

Statistical Mechanics · Physics 2015-06-17 Yigit Subasi , Christopher Jarzynski

A distributional symmetry is invariance of a distribution under a group of transformations. Exchangeability and stationarity are examples. We explain that a result of ergodic theory provides a law of large numbers: If the group satisfies…

Statistics Theory · Mathematics 2021-11-30 Morgane Austern , Peter Orbanz

We study the process of equilibration between two non-extensive subsystems in the framework of a particular non-extensive Boltzmann equation. We have found that even subsystems with different non-extensive properties achieve a common…

Statistical Mechanics · Physics 2007-05-23 T. S. Biro , G. Purcsel

The sampling of Boltzmann distributions by stochastic Markov processes, can be strongly limited by the crossing time of high (free) energy barriers. As a result, the system may stay trapped in metastable states, and the relaxation time to…

Statistical Mechanics · Physics 2015-05-13 Henri Orland

The notion of negative absolute temperature emerges naturally from Boltzmann's definition of "surface" microcanonical entropy in isolated systems with a bounded energy density. Recently, the well-posedness of such construct has been…

Statistical Mechanics · Physics 2017-05-31 Pierfrancesco Buonsante , Roberto Franzosi , Augusto Smerzi

The linear Boltzmann equation for elastic and/or inelastic scattering is applied to derive the distribution function of a spatially homogeneous system of charged particles spreading in a host medium of two-level atoms and subjected to…

Statistical Mechanics · Physics 2009-11-13 A. Rossani , A. M. Scarfone

Stationary non-equilibrium states describe steady flows through macroscopic systems. Although they represent the simplest generalization of equilibrium states, they exhibit a variety of new phenomena. Within a statistical mechanics…

Statistical Mechanics · Physics 2015-12-18 Lorenzo Bertini , Alberto De Sole , Davide Gabrielli , Giovanni Jona-Lasinio , Claudio Landim

We propose a new formulation of the fluctuating lattice Boltzmann equation that is consistent with both equilibrium statististical mechanics and fluctuating hydrodynamics. The formalism is based on a generalized lattice-gas model, with each…

Soft Condensed Matter · Physics 2009-11-13 Burkhard Duenweg , Ulf D. Schiller , Anthony J. C. Ladd

We discuss in detail the asymptotic distribution of sample expectiles. First, we show uniform consistency under the assumption of a finite mean. In case of a finite second moment, we show that for expectiles other then the mean, only the…

Methodology · Statistics 2016-07-14 Hajo Holzmann , Bernhard Klar

We derive the continuous canonical distribution only by requiring the extensivity of the mean energy and the multiplicative probabilistic composition rule. The derivation is independent of the thermodynamic limit and moreover it does not…

Statistical Mechanics · Physics 2016-08-31 Thomas Oikonomou , G. Baris Bagci

This article considers the spatially inhomogeneous, non-cutoff Boltzmann equation. We construct a large-data classical solution given bounded, measurable initial data with uniform polynomial decay of mild order in the velocity variable. Our…

Analysis of PDEs · Mathematics 2023-10-17 Christopher Henderson , Stanley Snelson , Andrei Tarfulea

We consider a quantum particle coupled (with strength $\la$) to a spatial array of independent non-interacting reservoirs in thermal states (heat baths). Under the assumption that the reservoir correlations decay exponentially in time, we…

Mathematical Physics · Physics 2015-05-13 W. De Roeck , J. Frohlich , A. Pizzo

In this paper we explore the following question: can the probabilities constituting the quantum Boltzmann distribution, $P^B_n \propto e^{-E_n/kT}$, be derived from a requirement that the quantum configuration-space distribution for a…

Quantum Physics · Physics 2018-08-01 Sam Alterman , Jaeho Choi , Rebecca Durst , Sarah M. Fleming , William K. Wootters
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