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We demonstrate that it is possible to mechanically exfoliate graphene under ultra high vacuum conditions on the atomically well defined surface of single crystalline silicon. The flakes are several hundred nanometers in lateral size and…

Materials Science · Physics 2015-06-05 O. Ochedowski , G. Begall , N. Scheuschner , M. El Kharrazi , J. Maultzsch , M. Schleberger

We demonstrate the temperature-mediated and completely reversible process of desorption-readsorption of water on a few layers of epitaxial graphene on a 4H-SiC(0001) substrate. We show that under ambient conditions water forms solid…

Mesoscale and Nanoscale Physics · Physics 2012-04-17 Tim L. Burnett , Jack Patten , Olga Kazakova

Using helium-3 atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4$^\circ$ rotated…

Mesoscale and Nanoscale Physics · Physics 2022-12-15 Emanuel Bahn , Anton Tamtögl , John Ellis , William Allison , Peter Fouquet

We report our results on the adsorption of noble gases such as argon, krypton and xenon on a graphene sheet, using Grand Canonical Monte Carlo (GCMC) simulations. We calculated the two-dimensional gas-liquid critical temperature for each…

Materials Science · Physics 2016-09-08 Sidi M. Maiga , Silvina M. Gatica

We predict the stability of a new extended two-dimensional hydrocarbon on the basis of first-principles total energy calculations. The compound that we call graphane is a fully saturated hydrocarbon derived from a single graphene sheet with…

Materials Science · Physics 2007-05-23 Jorge O. Sofo , Ajay S. Chaudhari , Greg D. Barber

Doped graphene sheets are pseudochiral two-dimensional Fermi liquids with abnormal electron-electron interaction physics. We address graphene's Fermi liquid properties quantitatively using a microscopic random-phase-approximation theory and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Marco Polini , Reza Asgari , Yafis Barlas , T. Pereg-Barnea , A. H. MacDonald

This review on graphene, a one atom thick, two-dimensional sheet of carbon atoms, starts with a general description of the graphene electronic structure as well as a basic experimental toolkit for identifying and handling this material.…

Materials Science · Physics 2010-11-22 Caterina Soldano , Ather Mahmood , Erik Dujardin

We aim to understand how the van der Waals force between neutral adatoms and a graphene layer is modified by uniaxial strain and electron correlation effects. A detailed analysis is presented for three atoms (He, H, and Na) and graphene…

Mesoscale and Nanoscale Physics · Physics 2016-05-11 Nathan S. Nichols , Adrian Del Maestro , Carlos Wexler , Valeri N. Kotov

Heterostructures involving graphene and bismuth, with their ability to absorb light over a very wide energy range, are of interest for engineering next-generation opto-electronics. Critical to the technological application of such…

Materials Science · Physics 2020-05-20 Ivan I. Naumov , Pratibha Dev

We present an approach to the melting of graphene based on nucleation theory for a first order phase transition from the 2D solid to the 3D liquid via an intermediate quasi-2D liquid. The applicability of nucleation theory, supported by the…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 J. H. Los , K. V. Zakharchenko , M. I. Katsnelson , Annalisa Fasolino

First-principles plane wave calculations predict that Li can be adsorbed on graphene forming a uniform and stable coverage on both sides. A significant part of the electronic charge of the Li-$2s$ orbital is donated to graphene and is…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 C. Ataca , E. Akturk , S. Ciraci , H. Ustunel

The deposition of atomically thin highly uniform chemically derived graphene (CDG) films on 300 mm SiO2/Si wafers is reported. We demonstrate that the very thin films can be lifted off to form uniform membranes than can be free-standing or…

Materials Science · Physics 2009-12-11 Hisato Yamaguchi , Goki Eda , Cecilia Mattevi , HoKwon Kim , Manish Chhowalla

Most of hydrocarbons are either molecular structures or linear polymeric chains. Discovery of graphene and manufacturing of its monohydride -- graphane incite interest in search for three-dimensional hydrocarbon polymers. However up to now…

Materials Science · Physics 2021-11-30 M. V. Kondrin , V. V. Brazhkin

The adsorption energies and orientation of methanol on graphene are determined from first-principles density functional calculations. We employ the well-tested vdW-DF method that seamlessly includes dispersion interactions with all of the…

Materials Science · Physics 2013-03-18 Elsebeth Schroder

Atomically thin graphene exhibits fascinating mechanical properties, although its hardness and transverse stiffness are inferior to those of diamond. To date, there hasn't been any practical demonstration of the transformation of…

Graphene, a two-dimensional monolayer of sp2-bonded carbon atoms in a honeycomb lattice, possesses exceptional electronic, mechanical, and quantum properties, making it highly attractive for energy storage, spintronics, and…

Materials Science · Physics 2025-12-30 Chien-Hsu Chen , Huan Niu , Hung-Kai Yu , Tsung Te Lin , Yao-Tung Hsu

Because of the dominant role of the surface of molecules and their individuality, molecules behave dis-tinctively in a confined space, which has far-reaching implications in many physical, chemical and bio-logical systems. Here, we…

Mesoscale and Nanoscale Physics · Physics 2014-04-29 DaeEung Lee , Gwanghyun Ahn , Sunmin Ryu

Vacancies in graphene present sites of altered chemical reactivity and open possibilities to tune graphene properties by defect engineering. The understanding of chemical reactivity of such defects is essential for successful implementation…

First-principles DFT levels of calculations have been carried out in order to study the structural stability and electronic properties of hydrogen passivated graphene (H-graphene) clusters. Two different shaped clusters, rectangular and…

Materials Science · Physics 2014-05-02 Deepak B Karki , Narayan P Adhikari

1.8 micrometer-thick magnesium hydride films were synthesized in a single-step process by reactive plasma-assisted sputtering. The MgH2 thin films, which were deposited on two types of flexible surfaces (namely graphite and polyimide foils)…

Applied Physics · Physics 2023-11-03 Huy Le-Quoc , Marie Coste , Ana Lacoste , L. Laversenne