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The equipartition theorem states that in equilibrium thermal energy is equally distributed among uncoupled degrees of freedom which appear quadratically in the system's Hamiltonian. However, for spatially coupled degrees of freedom --- such…

Statistical Mechanics · Physics 2015-07-14 Yohai Bar-Sinai , Eran Bouchbinder

The transition between a regime in which thermodynamic relations apply only to ensembles of small systems coupled to a large environment and a regime in which they can be used to characterize individual macroscopic systems is analyzed in…

Statistical Mechanics · Physics 2015-05-30 Alberto Suárez , Robert Silbey , Irwin Oppenheim

A quantum analog of friction (understood as a completely positive, Markovian, translation-invariant and phenomenological model of dissipation) is known to be in odds with the detailed balance in the thermodynamic limit. We show that this is…

Quantum Physics · Physics 2018-11-07 Dmitry V. Zhdanov , Denys I. Bondar , Tamar Seideman

A simple class of chaotic systems in a random environment is considered and the fluctuation theorem is extended under the assumption of reversibility.

Chaotic Dynamics · Physics 2008-02-01 F. Bonetto , G. Gallavotti , G. Gentile

We study the statistics of energy fluctuations in a three-level quantum system subject to a sequence of projective quantum measurements. We check that, as expected, the quantum Jarzynski equality holds provided that the initial state is…

Quantum Physics · Physics 2020-03-25 Guido Giachetti , Stefano Gherardini , Andrea Trombettoni , Stefano Ruffo

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

Firstly the fluctuation theorems (FT) for expended work in a driven nonequilibrium system, isolated or thermostatted, together with the ensuing Jarzynski work-energy (W-E) relationships, will be discussed and reobtained. Secondly, the…

Statistical Mechanics · Physics 2016-10-31 Carolyne M. Van Vliet

A fluctuation relation for the heat exchange of an open quantum system under a thermalizing Markovian dynamics is derived. We show that the probability of that the system absorbs an amount of heat from its bath, at a given time interval,…

Quantum Physics · Physics 2018-04-09 Mehdi Ramezani , Mehdi Golshani , Ali T. Rezakhani

Maintained by environmental fluxes, biological systems are thermodynamic processes that operate far from equilibrium without detailed-balance dynamics. Yet, they often exhibit well defined nonequilibrium steady states (NESSs). More…

Statistical Mechanics · Physics 2017-08-02 P. M. Riechers , J. P. Crutchfield

In classical Markov jump processes, current fluctuations can only be reduced at the cost of increased dissipation. To explore how quantum effects influence this trade-off, we analyze the uncertainty of steady-state currents in Markovian…

Statistical Mechanics · Physics 2021-07-09 Paul Menczel , Eetu Loisa , Kay Brandner , Christian Flindt

In this note we review recent progress about fluctuation relations and their applicability to free energy recovery in single molecule experiments. We underline the importance of the operational definition for the mechanical work and the…

Statistical Mechanics · Physics 2015-05-27 Anna Alemany , Marco Ribezzi , Felix Ritort

Structure-forming systems are ubiquitous in nature, ranging from atoms building molecules to self-assembly of colloidal amphibolic particles. The understanding of the underlying thermodynamics of such systems remains an important problem.…

Statistical Mechanics · Physics 2021-02-26 Jan Korbel , Simon David Lindner , Rudolf Hanel , Stefan Thurner

Since the first suggestion of the Jarzynski equality many derivations of this equality have been presented in both, the classical and the quantum context. While the approaches and settings greatly differ from one to another, they all appear…

Quantum Physics · Physics 2016-07-20 F. Jin , R. Steinigeweg , H. De Raedt , K. Michielsen , M. Campisi , J. Gemmer

Here we investigate the impact of temporal entanglement on a system's ability to perform thermodynamical work. We show that while the quantum version of the Jarzynski equality remains satisfied even in the presence of temporal entanglement,…

Quantum Physics · Physics 2012-04-26 Vlatko Vedral

Starting out from the recently established quantum correlation function expression of the characteristic function for the work performed by a force protocol on the system [cond-mat/0703213] the quantum version of the Crooks fluctuation…

Statistical Mechanics · Physics 2007-06-21 Peter Talkner , Peter Hanggi

Noncommutativity of observables is a central feature of quantum physics. It plays a fundamental role in the formulation of the uncertainty principle for complementary variables and strongly affects the laws of thermodynamics for systems…

Quantum Physics · Physics 2025-10-07 Franklin L. S. Rodrigues , Eric Lutz

The theory of quantum thermodynamics investigates how the concepts of heat, work, and temperature can be carried over to the quantum realm, where fluctuations and randomness are fundamentally unavoidable. These lecture notes provide an…

Quantum Physics · Physics 2026-04-17 Patrick P. Potts

Most non-equilibrium processes in thermodynamics are quantified only by inequalities, however the Jarzynski relation presents a remarkably simple and general equality relating non-equilibrium quantities with the equilibrium free energy, and…

Quantum Physics · Physics 2018-04-04 T. P. Xiong , L. L. Yan , F. Zhou , K. Rehan , D. F. Liang , L. Chen , W. L. Yang , Z. H. Ma , M. Feng , V. Vedral

It is shown that the recently proposed quantum analogue of classical energy equipartition theorem for two paradigmatic, exactly solved models (i.e., a free Brownian particle and a dissipative harmonic oscillator) also holds true for all…

Quantum Physics · Physics 2021-02-05 Jerzy Łuczka