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Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…

Statistical Mechanics · Physics 2007-05-23 C. Jarzynski

Exchange energy statistics between two bodies at different thermal equilibrium obey the Jarzynski-W\'ojcik fluctuation theorem. The corresponding energy scale factor is the difference of the inverse temperatures associated to the bodies at…

The fluctuation theorem of the Crooks type is studied for thermodynamic nonlinear- multivariate systems. In particular, a bivariate system having a limit cycle is discussed in detail. It is explicitly shown how the time reversal operation…

Statistical Mechanics · Physics 2014-02-27 Yasuyuki Matsuo

Recent studies using the quantum information theoretic approach to thermodynamics show that the presence of coherence in quantum systems generates corrections to classical fluctuation theorems. To explicate the physical origins and…

Quantum Physics · Physics 2019-02-26 Z. Holmes , S. Weidt , D. Jennings , J. Anders , F. Mintert

We extend the Exchange Fluctuation Theorem for energy exchange between thermal quantum systems beyond the assumption of molecular chaos, and describe the non-equilibrium exchange dynamics of correlated quantum states. The relation…

Quantum Physics · Physics 2015-10-14 Sania Jevtic , David Jennings , Terry Rudolph , Yuji Hirono , Shojun Nakayama , Mio Murao

In this paper we aim at characterizing the effect of stochastic fluctuations on the distribution of the energy exchanged by a quantum system with an external environment under sequences of quantum measurements performed at random times.…

Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

"Quantum mechanics must be regarded as open systems. On one hand, this is due to the fact that, like in classical physics, any realistic system is subjected to a coupling to an uncontrollable environment which influences it in a…

Quantum Physics · Physics 2007-05-23 S. Nicolosi

For driven open systems in contact with multiple heat reservoirs, we find the marginal distributions of work or heat do not satisfy any fluctuation theorem, but only the joint distribution of work and heat satisfies a family of fluctuation…

Statistical Mechanics · Physics 2023-03-08 Jin-Fu Chen , H. T. Quan

We derive fluctuation relations for a many-body quantum system prepared in a Generalised Gibbs Ensemble subject to a general nonequilibrium protocol. By considering isolated integrable systems, we find generalisations to the Tasaki-Crooks…

Statistical Mechanics · Physics 2015-06-19 James M. Hickey , Sam Genway

It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions…

Quantum Physics · Physics 2018-06-14 Harry J. D. Miller , Janet Anders

It has recently been argued that a self-consistency condition involving the Jarzynski equality (JE) and the Crooks fluctuation theorem (CFT) is violated for a simple Brownian process [L. Y. Chen, J. Chem. Phys. 129, 091101 (2008)]. This…

Statistical Mechanics · Physics 2009-07-14 Artur B. Adib

The nonzero ground-state energy of the quantum mechanical harmonic oscillator implies quantum fluctuations around the minimum of the potential with the mean square value proportional to Planck's constant. In classical mechanics thermal…

Quantum Physics · Physics 2020-09-02 K. Schönhammer

In this brief report, following the recent developments on formulating a quantum analogue of the classical energy equipartition theorem for open systems where the heat bath comprises of independent oscillators, i.e. bosonic degrees of…

Statistical Mechanics · Physics 2022-06-14 Jasleen Kaur , Aritra Ghosh , Malay Bandyopadhyay

The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…

Statistical Mechanics · Physics 2008-11-01 Giovanni Gallavotti

The Trajectory Class Fluctuation Theorem (TCFT) substantially strengthens the Second Law of Thermodynamics -- that, in point of fact, can be a rather weak bound on resource fluxes. Practically, it improves empirical estimates of free…

Statistical Mechanics · Physics 2024-04-30 Gregory Wimsatt , Alexander B. Boyd , James P. Crutchfield

The statistics of heat exchange between two classical or quantum finite systems initially prepared at different temperatures are shown to obey a fluctuation theorem.

Statistical Mechanics · Physics 2009-11-10 Christopher Jarzynski , Daniel K. Wojcik

We study the heat transfer between two finite quantum systems initially at different temperatures. We find that a recently proposed fluctuation theorem for heat exchange, namely the exchange fluctuation theorem [C. Jarzynski and D. K.…

Statistical Mechanics · Physics 2009-07-03 Shiho Akagawa , Naomichi Hatano