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The kinetics of an initially undercooled solid-liquid melt is studied by means of a generalized Phase Field model, which describes the dynamics of an ordering non-conserved field phi (e.g. solid-liquid order parameter) coupled to a…

Condensed Matter · Physics 2009-10-30 Umberto Marini Bettolo Marconi , Andrea Crisanti , Giulia Iori

During the directional solidification of peritectic alloys, two stable solid phases (parent and peritectic) grow competitively into a metastable liquid phase of larger impurity content than either solid phase. When the parent or both solid…

Materials Science · Physics 2009-10-31 Tak Shing Lo , Alain Karma , Mathis Plapp

We present dynamical density functional theory results for the time evolution of the density distribution of a sedimenting model two-dimensional binary mixture of colloids. The interplay between the bulk phase behaviour of the mixture, its…

Soft Condensed Matter · Physics 2015-06-17 Alexandr Malijevsky , Andrew J. Archer

The search for effective methods to fabricate bulk single-phase quasicrystalline Al-Cu-Fe alloys is currently an important task. Crucial to solving this problem is to understand mechanisms of phase formation in this system. Here we study…

Chemical Physics · Physics 2020-01-08 L. V. Kamaeva , I. V. Sterkhova , V. I. Ladyanov , R. E. Ryltsev , N. M. Chtchelkatchev

We use the Dynamic Density-Functional Formalism and the Fundamental Measure Theory as applied to a fluid of parallel hard squares to study the dynamics of heterogeneous growth of non-uniform phases with columnar and crystalline symmetries.…

Soft Condensed Matter · Physics 2022-06-07 Miguel Gonzalez-Pinto , Yuri Martinez-Raton , Enrique Velasco

Using both dynamical density functional theory and particle-resolved Brownian dynamics simulations, we explore the flow of two-dimensional colloidal solids and fluids driven through a linear channel with a geometric constriction. The flow…

Soft Condensed Matter · Physics 2016-05-25 Urs Zimmermann , Frank Smallenburg , Hartmut Löwen

This Article presents a nonequilibrium thermodynamic theory for the mean-field precipitation, aggregation and pattern formation of colloidal clusters. A variable gradient energy coefficient and the arrest of particle diffusion upon…

Soft Condensed Matter · Physics 2018-10-17 Thomas Petersen , Martin Z. Bazant , Roland J. M. Pellenq , Franz-Josef Ulm

We present a computer simulation study of the crystalline phases of hard ellipsoids of revolution. A previous study [Phys. Rev. E, \textbf{75}, 020402 (2007)] showed that for aspect ratios $a/b\ge 3$ the previously suggested stretched-fcc…

Statistical Mechanics · Physics 2015-05-13 M. Radu , P. Pfleiderer , T. Schilling

We investigate two-dimensional (2d) melting in the presence of a one-dimensional (1d) periodic potential as, for example, realized in recent experiments on 2d colloids subjected to two interfering laser beams. The topology of the phase…

Soft Condensed Matter · Physics 2009-10-31 Leo Radzihovsky , Erwin Frey , David R. Nelson

The phase field theory of crystal nucleation described in [L. Granasy, T. Borzsonyi, T. Pusztai, Phys. Rev. Lett. 88, 206105 (2002)] is applied for nucleation in hard--sphere liquids. The exact thermodynamics from molecular dynamics is…

Statistical Mechanics · Physics 2009-11-10 Laszlo Granasy , Tamas Pusztai , Zoltan Jurek , Massimo Conti , Bjorn Kvamme

Motivated by a phenomenon of phase transition in a model of alignment of self-propelled particles, we obtain a kinetic mean-field equation which is nothing else than the Doi equation (also called Smoluchowski equation) with dipolar…

Analysis of PDEs · Mathematics 2013-01-18 Amic Frouvelle , Jian-Guo Liu

A symmetric phase field model is used to study wavelength selection in two dimensions. We study the problem in a finite system using a two-pronged approach. First we construct an action and, minimizing this, we obtain the most probable…

Statistical Mechanics · Physics 2009-11-11 R. N. Costa Filho , J. M. Kosterlitz , Enzo Granato

A phase-field model that allows for quantitative simulations of low-speed eutectic and peritectic solidification under typical experimental conditions is developed. Its cornerstone is a smooth free-energy functional, designed so that the…

Materials Science · Physics 2009-11-11 R. Folch , M. Plapp

We develop a dynamical density functional theory based model for the drying of colloidal films on planar surfaces. We consider mixtures of two different sizes of hard-sphere colloids. Depending on the solvent evaporation rate and the…

Soft Condensed Matter · Physics 2021-01-28 Boshen He , Ignacio Martin-Fabiani , Roland Roth , Gyula I. Tóth , Andrew J. Archer

The primary factors controlling defect stability in phase-field crystal (PFC) models are examined, with illustrative examples involving several existing variations of the model. Guidelines are presented for constructing models with stable…

Materials Science · Physics 2015-06-11 Joel Berry , Nikolas Provatas , Jörg Rottler , Chad W. Sinclair

An electric-field-induced phase transition and pattern formation in a binary dielectric fluid layer are studied using a coarse-grained free energy functional. The electrostatic part of the free energy is a nonlinear functional of the…

Soft Condensed Matter · Physics 2007-05-23 M. D. Johnson , X. Duan , Brett Riley , Aniket Bhattacharya , Weili Luo

We present a phase field model of solidification which includes the effects of the crystalline orientation in the solid phase. This model describes grain boundaries as well as solid-liquid boundaries within a unified framework. With an…

Materials Science · Physics 2009-11-07 Alexander E. Lobkovsky , James A. Warren

The description of surface-diffusion controlled dynamics via the phase-field method is less trivial than it appears at first sight. A seemingly straightforward approach from the literature is shown to fail to produce the correct…

Computational Physics · Physics 2017-03-13 Clemens Mueller-Gugenberger , Robert Spatschek , Klaus Kassner

We propose a phase-field theory for enriched continua. To generalize classical phase-field models, we derive the phase-field gradient theory based on balances of microforces, microtorques, and mass. We focus on materials where second…

Mathematical Physics · Physics 2020-02-12 Luis Espath , Victor Calo

In numerous solution-processed thin films, a complex morphology resulting from liquid-liquid phase separation (LLPS) or from polycrystallization arises during the drying or subsequent processing steps. The morphology has a strong influence…

Applied Physics · Physics 2022-06-28 Olivier J. J. Ronsin , Jens Harting