Related papers: Finite Bath Fluctuation Theorem
We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…
Quantum thermodynamic quantities, normally formulated with the assumption of weak system-bath coupling (SBC), can often be contested in physical circumstances with strong SBC. This work presents an alternative treatment that enables us to…
We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…
We study the Fluctuation Theorem (FT) for entropy production in chaotic discrete-time dynamical systems on compact metric spaces, and extend it to empirical measures, all continuous potentials, and all weak Gibbs states. In particular, we…
Fluctuation-dissipation relation ensures thermodynamic equilibrium of a particle immersed in a heat bath. We will show that, under certain circumstances, the fluctuation-dissipation relation fails to ensure equilibrium between the immersed…
The canonical ensemble plays a crucial role in statistical mechanics in and out of equilibrium. For example, the standard derivation of the fluctuation theorem relies on the assumption that the initial state of the heat bath is the…
There is presently considerable interest in accurately simulating the evolution of open systems for which Markovian master equations fail. Examples are systems that are time-dependent and/or strongly damped. A number of elegant methods have…
We elucidate the connection between various fluctuation theorems by a microcanonical version of the Crooks relation. We derive the microscopically exact expression for the work distribution in an idealized Joule experiment, namely for an…
Fluctuation theorems are a class of equalities that express universal properties of the probability distribution of a fluctuating path functional such as heat, work or entropy production over an ensemble of trajectories during a…
We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…
The Fluctuation Theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium…
A finite-time fluctuation theorem for the diffusion-influenced surface reaction A <=> B is investigated for spherical and Janus catalytic particles. The finite-time rates and thermodynamic force are analytically calculated by solving…
In the last two decades, fluctuation theorems have been proved formally and demonstrated experimentally for several variables (such as entropy production, work, or flux) and different noises causing the fluctuations (of either thermal or…
Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small systems. Their general validity arbitrarily far from equilibrium makes them invaluable in nonequilibrium physics. So far, experimental studies of…
The Fluctuation Theorems are a group of exact relations that remain valid irrespective of how far the system has been driven away from equilibrium. Other than having practical applications, like determination of equilibrium free energy…
Almost a century ago, Johnson and Nyquist presented evidence of fluctuating electrical current and the governing fluctuation dissipation theorem (FDT). Whether, likewise, temperature T can fluctuate is a controversial topic and has led to…
A colloidal particle immersed in a bath of bacteria is a typical example of a passive particle in an active bath. To model this, we take an overdamped harmonically trapped particle subjected to a thermal and a non-equilibrium noise arising…
A new effective theory framework for fluctuating hydrodynamics in the relativistic regime is derived using standard thermodynamical principles and general properties of non-equilibrium stochastic dynamics. For the first time, we establish…
We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the…
We obtain the Crooks and the Jarzynski non-equilibrium fluctuation relations using a direct quantum-mechanical approach for a finite system that is either isolated or coupled not too strongly to a heat bath. These results were hitherto…