Finite-time fluctuation theorem for diffusion-influenced surface reactions on spherical and Janus catalytic particles
Statistical Mechanics
2018-12-24 v1
Abstract
A finite-time fluctuation theorem for the diffusion-influenced surface reaction A <=> B is investigated for spherical and Janus catalytic particles. The finite-time rates and thermodynamic force are analytically calculated by solving diffusion equations with the special boundary conditions of the finite-time fluctuation theorem. Theory is compared with numerical simulations carried out with two different methods: a random walk algorithm and multiparticle collision dynamics.
Keywords
Cite
@article{arxiv.1807.06553,
title = {Finite-time fluctuation theorem for diffusion-influenced surface reactions on spherical and Janus catalytic particles},
author = {Pierre Gaspard and Patrick Grosfils and Mu-Jie Huang and Raymond Kapral},
journal= {arXiv preprint arXiv:1807.06553},
year = {2018}
}