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The random-phase approximation to the ground state correlation energy (RPA) in combination with exact exchange (EX) has brought Kohn-Sham (KS) density functional theory one step closer towards a universal, "general purpose first principles…

We investigate the behaviour of randomly cross-linked (co)polymer blends using a combination of replica theory and large-scale molecular dynamics simulations. In particular, we derive the analogue of the random phase approximation for…

Soft Condensed Matter · Physics 2009-11-13 A. V. Klopper , Carsten Svaneborg , Ralf Everaers

A two-component system of penetrable particles interacting via a gaussian core potential is considered, which may serve as a crude model for binary polymer solutions. The pair structure and thermodynamic properties are calculated within the…

Soft Condensed Matter · Physics 2007-05-23 R. Finken , J. -P. Hansen , A. A. Louis

We introduce the Korringa-Kohn-Rostocker non-local coherent potential approximation (KKR-NLCPA) for describing the electronic structure of disordered systems. The KKR-NLCPA systematically provides a hierarchy of improvements upon the widely…

Materials Science · Physics 2009-11-07 D. A. Rowlands , J. B. Staunton , B. L. Gyorffy

Although density functional theory (DFT) in principle includes even long-range interactions, standard implementations employ local or semi-local approximations of the interaction energy and fail at describing the van der Waals interactions.…

Soft Condensed Matter · Physics 2007-05-23 S. D. Chakarova , E. Schroder

We propose a novel approach to electron correlation for multireference systems. It is based on particle-hole (ph) and particle-particle (pp) theories in the second-order, developed in the random phase approximation (RPA) framework for…

Chemical Physics · Physics 2024-12-03 Aleksandra Tucholska , Yang Guo , Katarzyna Pernal

In correlated electron materials, the application of many-body techniques for the study of interaction effects or unconventional superconductivity often requires the formulation of an effective low-energy model that contains only the…

Strongly Correlated Electrons · Physics 2013-05-30 Carsten Honerkamp

Self-consistent relativistic random-phase approximation (RPA) in the radial coordinate representation is established by using the finite amplitude method (FAM). Taking the isoscalar giant monopole resonance in spherical nuclei as example,…

Nuclear Theory · Physics 2013-10-16 Haozhao Liang , Takashi Nakatsukasa , Zhongming Niu , Jie Meng

Based on an equations--of--motion approach for time--dependent pair correlations in strongly interacting Fermi liquids, we have developed a theory for describing the excitation spectrum of these systems. Compared to the known ``correlated''…

Other Condensed Matter · Physics 2009-11-11 Helga M. Böhm , Eckhard Krotscheck , Martin Panholzer

The direct random-phase approximation (dRPA) is used to calculate and compare atomization energies for the HEAT set and 10 selected molecules of the G2-1 set using both plane waves and Gaussian-type orbitals. We describe detailed procedures…

We present a practical approach to treat static and dynamical correlation accurately in large multi-configurational systems. The static correlation is accounted for using the spin-flip approach which is well known for capturing static…

Strongly Correlated Electrons · Physics 2021-02-08 Oinam Romesh Meitei , Nicholas J. Mayhall

Phase separation of the ultrasoft restricted primitive model (URPM) with Gaussian charges is re-investigated in the random phase approximation (RPA)---the 'Level A' approximation discussed by Nikoubashman, Hansen and Kahl [J. Chem. Phys.…

Statistical Mechanics · Physics 2013-02-22 Patrick B. Warren , Andrew J. Masters

We report an improved implementation for evaluating the analytical gradients of the random phase approximation (RPA) electron-correlation energy based on atomic orbitals and the localized resolution of identity scheme. The more efficient…

Materials Science · Physics 2024-04-17 Muhammad N. Tahir , Honghui Shang , Jia Li , Xinguo Ren

We extend the single-site coherent potential approximation (CPA) to include the effects of non-local disorder correlations (alloy short-range order) on the electronic structure of random alloy systems. This is achieved by mapping the…

Strongly Correlated Electrons · Physics 2009-11-10 M. S. Laad , L. Craco

We generalize the recently introduced single-boson exchange formalism to nonlocal interactions. In the functional renormalization group application to the extended Hubbard model in two dimensions, we show that the flow of the rest function…

Strongly Correlated Electrons · Physics 2024-12-11 Aiman Al-Eryani , Sarah Heinzelmann , Kilian Fraboulet , Friedrich Krien , Sabine Andergassen

We propose a streamlined combination scheme of the transcorrelation (TC) and coupled cluster (CC) theory, which not only increases the convergence rate with respect to the basis set, but also extends the applicability of the lowest order CC…

Strongly Correlated Electrons · Physics 2021-07-28 Ke Liao , Thomas Schraivogel , Hongjun Luo , Daniel Kats , Ali Alavi

A local approximation for dynamic polarizability leads to a nonlocal functional for the long-range dispersion interaction energy via an imaginary-frequency integral. We analyze several local polarizability approximations and argue that the…

Chemical Physics · Physics 2015-03-17 Oleg A. Vydrov , Troy Van Voorhis

Self-Consistent RPA is rederived in a consistent way with the help of the Coupled Cluster ground state wave function truncated at the two body level. An exact killing operator for this wave function is introduced allowing for a detailed…

Nuclear Theory · Physics 2015-06-16 M. Jemai , D. S. Delion , P. Schuck

The relativistic random-phase approximation (RRPA) plus phonon-coupling (PC) model is applied in the analysis of E1 strength distributions in $^{208}$Pb and $^{132}$Sn, for which data on pygmy dipole resonances (PDR) have recently been…

Nuclear Theory · Physics 2008-11-26 E. Litvinova , P. Ring , D. Vretenar

While the coherent potential approximation (CPA) is the prevalent method for the study of disordered electronic systems, it fails to capture non-local correlations and Anderson localization. To incorporate such effects, we extend the dual…

Strongly Correlated Electrons · Physics 2013-05-08 H. Terletska , S. -X. Yang , Z. Y. Meng , J. Moreno , M. Jarrell
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