Related papers: Time-dependent H2 formation and protonation
Context. The earliest phases of high-mass star formation are poorly understood. Aims. Our goal is to determine the physical conditions and kinematic structure of massive star-forming cloud clumps. Methods. We analyze H$_2$O 557 GHz line…
Aims. We model a diffuse molecular cloud present along the line of sight to the star HD 102065. We compare our modeling with observations to test our understanding of physical conditions and chemistry in diffuse molecular clouds. Methods.…
According to traditional gas-phase chemical models, O2 should be abundant in molecular clouds, but until recently, attempts to detect interstellar O2 line emission with ground- and space-based observatories have failed. Following the…
The mechanisms which could lead to chemo-thermal instabilities and fragmentation during the formation of primordial protostars are investigated analytically. We introduce approximations for H2 cooling rates bridging the optically thin and…
We investigate to what degree local physical and chemical conditions are related to the evolutionary status of various objects in star-forming media. rho Oph A displays the entire sequence of low-mass star formation in a small volume of…
We present ISO observations of several H2 pure-rotational lines (from S(0) to S(5)) towards a sample of 16 molecular clouds distributed along the central ~ 500 pc of the Galaxy. We also present C18O and 13CO J=1->0 and J=2->1 observations…
(Abridged) We present a large sample of o-H$_2$D$^+$ observations in high-mass star-forming regions and discuss possible empirical correlations with relevant physical quantities to assess its role as a chronometer of star-forming regions…
We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the…
We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed…
We combine the latest observationally motivated constraints on stellar properties in dark matter haloes, along with data-driven predictions for the atomic (HI) and molecular (H$_2$) gas evolution in galaxies, to derive empirical…
The aim of this study is to investigate systematic chemical differentiation of molecules in regions of high mass star formation. We observed five prominent sites of high mass star formation in HCN, HNC, HCO+, their isotopes, C18O, C34S and…
This paper presents the third in a series of single-dish studies of molecular abundances in the envelopes around a large sample of 18 low-mass pre- and protostellar objects. It focuses on typical grain mantle products and organic molecules,…
Supersonic turbulence results in strong density fluctuations in the interstellar medium (ISM), which have a profound effect on the chemical structure. Particularly useful probes of the diffuse ISM are the ArH$^+$, OH$^+$, H$_2$O$^+$…
We present new analytic theory and radiative transfer computations for the atomic to molecular (HI-to-H2) transitions, and the build-up of atomic-hydrogen (HI) gas columns, in optically thick interstellar clouds, irradiated by…
Absorption lines from the molecules OH+, H2O+, and H3+ have been observed in a diffuse molecular cloud along a line of sight near W51 IRS2. We present the first chemical analysis that combines the information provided by all three of these…
We present the first numerical simulations that self-consistently follow the formation of dense molecular clouds in colliding flows. Our calculations include a time-dependent model for the H2 and CO chemistry that runs alongside a detailed…
We investigate the correlation between OH and H2 column densities in diffuse Galactic clouds, in order to identify potential molecular tracers of interstellar H2. For this, we analyse near-UV spectra extracted from the ESO/VLT archives…
Molecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The…
Dynamical expansion of H II regions around star clusters plays a key role in dispersing the surrounding dense gas and therefore in limiting the efficiency of star formation in molecular clouds. We use a semi-analytic method and numerical…
We present a CSO and BIMA molecular line survey of the dense, quiescent molecular environment ahead of HH2. The molecular gas is cold, 13 K, and moderately dense, 3x10^5 cm^-3. A total of 14 species has been detected (including different…