Related papers: Time-dependent H2 formation and protonation
Protonated hydrogen cyanide, HCNH$^{+}$, plays a fundamental role in astrochemistry because it is an intermediary in gas-phase ion-neutral reactions within cold molecular clouds. However, the impact of the environment on the chemistry of…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
We study the changes in physical and chemical conditions during the collapse of a pre--protostellar core, starting from initial conditions appropriate to a dense molecular cloud and proceeding to the ``completely depleted'' limit. We follow…
Continuous-time, random-walk Monte Carlo simulations of H2 formation on grains have been performed for surfaces that are stochastically heated by photons. We have assumed diffuse cloud conditions and used a variety of grains of varying…
We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by…
We find that clouds of optically-thin, pressure-confined gas are prone to fragmentation as they cool below $\sim10^6$ K. This fragmentation follows the lengthscale $\sim{c}_{\text{s}}\,t_{\text{cool}}$, ultimately reaching very small scales…
The ULIRG Mrk 231 exhibits very strong water rotational lines between \lambda = 200-670\mu m, comparable to the strength of the CO rotational lines. High redshift quasars also show similar CO and H2O line properties, while starburst…
We study the influence of low levels of metal enrichment on the cooling and collapse of ionized gas in small protogalactic halos using three-dimensional, smoothed particle hydrodynamics simulations. Our initial conditions represent…
Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d ice survey, complimented with data sets on ices in cloud cores and high-mass…
We present the results of near-infrared spectroscopic observations for a sample of 12 star-forming galaxies at 1.0<z<1.5, drawn from the DEEP2 Galaxy Redshift Survey. H-beta, [OIII], H-alpha, and [NII] emission-line fluxes are measured for…
We use UV measurements of interstellar CO towards nearby stars to calculate the density in the diffuse molecular clouds containing the molecules responsible for the observed absorption. Chemical models and recent calculations of the…
ABRIDGED: Context: HI and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds. However, until recently, we have not had spectrally resolved C+ surveys to…
We model the effect of grain size distribution in a galaxy on the evolution of CO and H$_2$ abundances. The formation and dissociation of CO and H$_2$ in typical dense clouds are modelled in a manner consistent with the grain size…
There has always been a great deal of interest in the formation of H2 as well as in the binding energy released upon its formation on the surface of dust grains. The present work aims at collecting experimental evidence for how the bond…
We study the structural evolution of turbulent molecular clouds under the influence of ionizing radiation emitted from a nearby massive star by performing a high resolution parameter study with the iVINE code. The temperature is taken to be…
Hydroxyl ($\rm OH$) is known to form efficiently in cold gas ($T\sim 100$K) along with the molecule $\rm H_2$ and can be used as an efficient tracer of the diffuse molecular gas in the interstellar medium (ISM). Using a simple formalism…
We study the formation and evolution of HII regions around the first stars formed at z=10-30. We use a one-dimensional Lagrangian hydrodynamics code which self-consistently incorporates radiative transfer and non-equilibrium primordial gas…
We performed high-resolution, 3D MHD simulations and we compared to observations of translucent molecular clouds. We show that the observed populations of rotational levels of H2 can arise as a consequence of the multi-phase structure of…
We study the formation of molecular hydrogen, after the epoch of re-ionization, in the context of canonical galaxy formation theory due to hierarchical clustering. There is an initial epoch of $H_2$ production in the gas phase through the…
We present N2D+ 3-2 (IRAM) and H2D+ 1_11 - 1_10 and N2H+ 4-3 (JCMT) maps of the small cluster-forming Ophiuchus B2 core in the nearby Ophiuchus molecular cloud. In conjunction with previously published N2H+ 1-0 observations, the N2D+ data…