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In this paper we collect some new observations about periodic critical points and local minimizers of a nonlocal isoperimetric problem, arising in the modeling of diblock copolymers. In the main result, by means of a purely variational…

Analysis of PDEs · Mathematics 2017-11-21 Riccardo Cristoferi

We consider a non local isoperimetric problem arising as the sharp interface limit of the Ohta-Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows…

Analysis of PDEs · Mathematics 2013-07-24 Vesa Julin , Giovanni Pisante

In this paper we consider nonlinearly elastic, frame-indifferent, and singularly perturbed two-well models for materials undergoing solid-solid phase transitions in any space dimensions, and we perform a simultaneous passage to…

Analysis of PDEs · Mathematics 2020-05-11 Elisa Davoli , Manuel Friedrich

We consider a model of a random copolymer at a selective interface which undergoes a localization/delocalization transition. In spite of the several rigorous results available for this model, the theoretical characterization of the phase…

Mathematical Physics · Physics 2007-05-23 F. Caravenna , G. Giacomin , M. Gubinelli

We discuss the local minimality of certain configurations for a nonlocal isoperimetric problem used to model microphase separation in diblock copolymer melts. We show that critical configurations with positive second variation are local…

Analysis of PDEs · Mathematics 2015-06-12 Emilio Acerbi , Nicola Fusco , Massimiliano Morini

We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove…

Mathematical Physics · Physics 2007-10-30 Yves van Gennip , Mark A. Peletier

Particles interacting through long-range attraction and short-range repulsion given by power-laws have been widely used to model physical and biological systems, and to predict or explain many of the patterns they display. Apart from rare…

Optimization and Control · Mathematics 2022-05-19 Cameron Davies , Tongseok Lim , Robert J. McCann

For a diblock copolymer with total chain length $\gamma>0$ and mass ratio $m\in(-1,1)$, we consider the problem of minimizing the doubly nonlocal free energy $$ \mathcal{E}_{\varepsilon}(u) =\mathcal{H}(u) +\frac{1}{\varepsilon^{2s}}…

Analysis of PDEs · Mathematics 2020-11-16 Hardy Chan , Masomeh Jamshid Nejad , Juncheng Wei

We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…

Analysis of PDEs · Mathematics 2019-12-20 Stan Alama , Lia Bronsard , Xinyang Lu , Chong Wang

We consider a one-dimensional diffusion process with coefficients that are periodic outside of a finite 'interface region'. The question investigated in this article is the limiting long time / large scale behaviour of such a process under…

Probability · Mathematics 2010-05-14 Martin Hairer , Charles Manson

In this paper we study a new model for patterns in two dimensions, inspired by diblock copolymer melts with a dominant phase. The model is simple enough to be amenable not only to numerics but also to analysis, yet sophisticated enough to…

Analysis of PDEs · Mathematics 2013-12-06 D. P. Bourne , M. A. Peletier , S. M. Roper

We study localization and many-body localization transition in one dimensional systems in the presence of deterministic quasi-periodic potential. We use single-particle excitations obtained through single-particle Green's function in real…

Disordered Systems and Neural Networks · Physics 2024-03-15 Yogeshwar Prasad , Arti Garg

This paper is concerned with the macroscopic behavior of global energy minimizers in the three-dimensional sharp interface unscreened Ohta-Kawasaki model of diblock copolymer melts. This model is also referred to as the nuclear liquid drop…

Mathematical Physics · Physics 2016-07-19 Hans Knuepfer , Cyrill Muratov , Matteo Novaga

We give a detailed description of the geometry of single droplet patterns in a nonlocal isoperimetric problem. In particular we focus on the sharp interface limit of the Ohta-Kawasaki free energy for diblock copolymers, regarded as a…

Analysis of PDEs · Mathematics 2011-10-04 Marco Cicalese , Emanuele Spadaro

A variational model for describing the morphology of two-phase continua by allowing for the interplay between coherent and incoherent interfaces is introduced. Coherent interfaces are characterized by the microscopical arrangement of atoms…

Analysis of PDEs · Mathematics 2023-10-24 Randy Llerena , Paolo Piovano

We propose a new coarse-grained model for the description of liquid-vapor phase separation of colloid-polymer mixtures. The hard-sphere repulsion between colloids and between colloids and polymers, which is used in the well-known…

Soft Condensed Matter · Physics 2009-11-13 Jochen Zausch , Peter Virnau , Kurt Binder , Juergen Horbach , Richard L. Vink

We propose a new preconditioner for the Ohta--Kawasaki equation, a nonlocal Cahn--Hilliard equation that describes the evolution of diblock copolymer melts. We devise a computable approximation to the inverse of the Schur complement of the…

Numerical Analysis · Mathematics 2016-03-16 Patrick E. Farrell , John W. Pearson

We present a computer-assisted proof of heteroclinic connections in the one-dimensional Ohta-Kawasaki model of diblock copolymers. The model is a fourth-order parabolic partial differential equation subject to homogeneous Neumann boundary…

Analysis of PDEs · Mathematics 2020-05-29 Jacek Cyranka , Thomas Wanner

We consider a variational model for periodic partitions of the upper half-space into three regions, where two of them have prescribed volume and are subject to the geometrical constraint that their union is the subgraph of a function, whose…

Analysis of PDEs · Mathematics 2022-10-19 Marco Bonacini , Riccardo Cristoferi

We numerically investigate local defectiveness control of self-assembled diblock copolymer patterns through appropriate substrate design. We use a nonlocal Cahn-Hilliard (CH) equation for the phase separation dynamics of diblock copolymers.…

Soft Condensed Matter · Physics 2017-02-13 D. Jeong , Y. Choi , J. Kim
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