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It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where…

Chaotic Dynamics · Physics 2009-11-07 J. R. Dorfman , P. Gaspard , T. Gilbert

The laws of thermodynamics apply to biophysical systems on the nanoscale as described by the framework of stochastic thermodynamics. This theory provides universal, exact relations for quantities like work, which have been verified in…

Statistical Mechanics · Physics 2024-09-26 Julius Degünther , Jann van der Meer , Udo Seifert

A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…

Statistical Mechanics · Physics 2009-04-15 Hao Ge

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

Modern developments in nonequilibrium thermodynamics have significant implications for the origins of life. The reasons for this are closely related to a generalized version of the second law of thermodynamics recently found for entropy…

General Physics · Physics 2022-04-04 Gerald E. Marsh

We show that systems driven by an external force and described by Nose-Hoover dynamics allow for a consistent nonequilibrium thermodynamics description when the thermostatted variable is initially assumed in a state of canonical…

Statistical Mechanics · Physics 2011-08-11 Massimiliano Esposito , Takaaki Monnai

A pair of symmetric expressions for the second law of thermodynamics is put forward. The conservation and transfer of entropy is discussed and applied to problems like biology, culture and life itself. A new explanation is given to the…

Quantum Physics · Physics 2007-05-23 Wang Zhen

We study nonequilibrium thermodynamic properties of a driven one-dimensional quantum fluid by combining nonlinear Luttinger liquid theory with the quantum kinetic equation. In particular, we derive an entropy production consistent with the…

Mesoscale and Nanoscale Physics · Physics 2019-10-09 Edvin G. Idrisov , Thomas L. Schmidt

A system can be driven out of equilibrium by both time-dependent and nonconservative forces, which gives rise to a decomposition of the dissipation into two non-negative components, called the excess and housekeeping entropy productions. We…

Statistical Mechanics · Physics 2023-05-31 Takuya Kamijima , Sosuke Ito , Andreas Dechant , Takahiro Sagawa

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

Statistical Mechanics · Physics 2013-05-30 Ian J. Ford , Richard E. Spinney

We compare several definitions of entropy production rate introduced in the literature from a large variety of situations and motivations, and then analyze their relations with memory effects. Considering a relevant experimental example of…

Quantum Physics · Physics 2026-01-30 Guillaume Théret , Dominique Sugny , Camille L. Latune

We analyze the dynamics of a simple but nontrivial classical Hamiltonian system of infinitely many coupled rotators. We assume that this infinite system is driven out of thermal equilibrium either because energy is injected by an external…

Statistical Mechanics · Physics 2015-06-25 David Ruelle

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Several comments are given to previous proofs of the generalised second law of thermodynamics: black hole entropy plus ordinary matter entropy never decreases for a thermally closed system. Arguments in favour of its truism are given in the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 S. -T. Sung

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…

Quantum Physics · Physics 2021-04-09 M. X. Luo , X. Wang

From the previously obtained solutions of the Fokker - Planck equation for Rayleigh gas (small impurity of heavy particles in a thermostat of light particles) with sources and without them, the entropy production was calculated. In a system…

Statistical Mechanics · Physics 2016-10-11 P. A. Tadjibaev , D. P. Tadjibaev

We solve a set of selected exercises on rotational motion requiring a mechanical and thermodynamical analysis. When non-conservative forces or thermal effects are present, a complete study must use the first law of thermodynamics together…

Classical Physics · Physics 2014-04-08 Julio Güémez , Manuel Fiolhais