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A procedure is described for the precise nonrelativistic evaluation of the dipole polarizabilities of H_2^+ and D_2^+ that avoids any approximation based on the size of the electron mass relative to the nucleus mass. The procedure is…

Atomic Physics · Physics 2007-05-23 J. M. Taylor , A. Dalgarno , J. F. Babb

The static dipole polarizability for the hydrogen molecular ions H$_2^+$, HD$^+$, and D$_2^+$ are calculated. These new data for polarizability takes into account the leading order relativistic corrections to the wave function of the…

Atomic Physics · Physics 2017-02-01 D. T. Aznabayev , A. K Bekbaev , S. A. Zhaugasheva , V. I. Korobov

The static and dynamic electric multipolar polarizabilities and second hyperpolarizabilities of the H$_2^+$, D$_2^+$, and HD$^+$ molecular ions in the ground and first excited states are calculated nonrelativistically using explicitly…

Atomic Physics · Physics 2014-09-23 Li-Yan Tang , Zong-Chao Yan , Ting-Yun Shi , James F. Babb

The dynamic dipole polarizabilities for the Li atom and the Be+ ion in the 2s and 2p states are calculated using the variational method with a Hylleraas basis. The present polarizabilities represent the definitive values in the…

Atomic Physics · Physics 2015-05-18 Li-Yan Tang , Zong-Chao Yan , Ting-Yun Shi , J. Mitroy

In this paper, using a standard quantum chemistry approach based on pseudopotentials for atomic core representation, Gaussian basis sets, and effective core polarization potentials, we investigate the electronic properties of the MgH$^+$…

Quantum Physics · Physics 2015-05-13 Mireille Aymar , Romain Guérout , Mohamed Sahlaoui , Olivier Dulieu

The electric dipole polarizabilities of $^3$H, $^3$He, and $^4$He are calculated directly using the Schr\"odinger equation with the latest generation of two- and three-nucleon interactions. These polarizabilities are necessary in order to…

Nuclear Theory · Physics 2010-05-27 I. Stetcu , S. Quaglioni , J. L. Friar , A. C. Hayes , P. Navrátil

The oscillator strengths of the $H^+_2$ molecular ion, $1s\sigma_{g}-2p\sigma_{u}$, $1s\sigma_{g}-2p\pi_{u}$ are calculated within the Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been used…

Atomic Physics · Physics 2010-07-27 Ts. Tsogbayar , Ts. Banzragch

We have calculated electric-dipole polarizabilities of the 3s^2 ^1S_0, 3s3p ^3P_0, and 3s3p ^1P_1 states of the Si^{2+} ion using recently developed configuration interaction + all-order method. Detailed evaluation of the uncertainties of…

Atomic Physics · Physics 2013-06-12 M. S. Safronova , S. G. Porsev , M. G. Kozlov , Charles W. Clark

We present high-precision non-relativistic variational calculations of bound vibrational-rotational state energies for the $H_2^+$ and $D_2^+$ molecular ions in each of the lowest electronic states of $\Sigma_g$, $\Sigma_u$, and $\Pi_u$…

Atomic Physics · Physics 2007-05-23 J. M. Taylor , Zong-Chao Yan , A. Dalgarno , J. F. Babb

The static electric dipole polarizability of $\mathrm{Na_N}$ clusters with even N has been calculated in a collective, axially averaged and a three-dimensional, finite-field approach for $2\le N \le 20$, including the ionic structure of the…

Atomic and Molecular Clusters · Physics 2009-10-31 S. Kümmel , T. Berkus , P. -G. Reinhard , M. Brack

The non-relativistic static and dynamic dipole polarizabilities of hydrogen atom experiencing a cylindrical confinement are investigated. Two methods based on B-Splines are used for the computations of the energies and wavefunctions. The…

Atomic Physics · Physics 2013-08-15 S. A. Ndengué , O. Motapon , R. L. Melingui Melono , A. J. Etindele

High precision multipole polarizabilities, $\alpha_{\ell}$ for $\ell \le 4$ of the $1s$ ground state of the hydrogen isoelectronic series are obtained from the Dirac equation using the B-spline method with Notre Dame boundary conditions.…

Atomic Physics · Physics 2015-06-05 Li-Yan Tang , Yong-Hui Zhang , Xian-Zhou Zhang , Jun Jiang , J. Mitroy

The recently reported precise experimental determination of the dipole polarizability of the H_2^+ molecular ion ground state [P.L. Jacobson, R.A. Komara, W.G. Sturrus, and S.R. Lundeen, Phys. Rev. A 62, 012509 (2000)] reveals a discrepancy…

Atomic Physics · Physics 2009-11-06 V. I. Korobov

The static dipole polarizability of metastable states in the kaonic helium atoms is studied. We use the complex coordinate rotation method to properly account for the resonant nature of the states. Our calculations show that some of the…

Atomic Physics · Physics 2024-08-30 D. T. Aznabayev , A. K. Bekbaev , V. I. Korobov

Three simple $7-, (7+3)-, 10-$parametric trial functions for the ${\rm H}_3^+$ molecular ion are presented. Each of them provides subsequently the most accurate approximation for the Born-Oppenheimer ground state energy among…

Quantum Physics · Physics 2015-05-28 J. C. Lopez Vieyra , A. V. Turbiner , H. Medel Cobaxin

We report on highly accurate calculations of Born-Oppenheimer potentials for excited $n\,\Sigma^{+}$ states of the hydrogen molecule for all possible combinations of singlet/triplet and gerade/ungerade symmetries up to $n=7$. A relative…

Atomic Physics · Physics 2023-02-28 Michał Siłkowski , Magdalena Zientkiewicz , Krzysztof Pachucki

The polarizabilities and hyperpolarizabilities of the Be$^+$ ion in the $2^2S$ state and the $2^2P$ state are determined. Calculations are performed using two independent methods: i) variationally determined wave functions using Hylleraas…

Atomic Physics · Physics 2009-10-21 Li-Yan Tang , Jun-Yi Zhang , Zong-Chao Yan , Ting-Yun Shi , James F. Babb , J. Mitroy

Experimental results and high-level quantum chemical ab initio calculations of the static polarizability $\alpha_0=\alpha(\omega=0)$ of the cadmium ${^1S_0}$ state are still in marked disagreement. Here we analyze this discrepancy by using…

Chemical Physics · Physics 2022-09-05 Uwe Hohm

Using a single trial function we perform an accurate calculation of the ground state $1\sigma_g$ of the hydrogenic molecular ion $H^+_2$ in a constant uniform magnetic field ranging $0-10^{13}$ G. We show that this trial function also makes…

Astrophysics · Physics 2009-10-30 J. C. Lopez , P. O. Hess , A. Turbiner

Matching for a wavefunction the WKB expansion at large distances and Taylor expansion at small distances leads to a compact, few-parametric uniform approximation found in {\it J. Phys. B44, 101002 (2011)}. The ten low-lying eigenstates of…

Quantum Physics · Physics 2019-08-13 Horacio Olivares-Pilón , Alexander V. Turbiner
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