English

Computational investigation of static multipole polarizabilities and sum rules for ground-state hydrogen-like ions

Atomic Physics 2015-06-05 v1 Chemical Physics

Abstract

High precision multipole polarizabilities, α\alpha_{\ell} for 4\ell \le 4 of the 1s1s ground state of the hydrogen isoelectronic series are obtained from the Dirac equation using the B-spline method with Notre Dame boundary conditions. Compact analytic expressions for the polarizabilities as a function of ZZ with a relative accuracy of 106^{-6} up to Z=100Z = 100 are determined by fitting to the calculated polarizabilities. The oscillator strengths satisfy the sum rules if0i()=0\sum_i f^{(\ell)}_{0i} = 0 for all multipoles from =1\ell = 1 to =4\ell = 4. The dispersion coefficients for the long-range H-H and H-He+^+ interactions are given.

Keywords

Cite

@article{arxiv.1205.6883,
  title  = {Computational investigation of static multipole polarizabilities and sum rules for ground-state hydrogen-like ions},
  author = {Li-Yan Tang and Yong-Hui Zhang and Xian-Zhou Zhang and Jun Jiang and J. Mitroy},
  journal= {arXiv preprint arXiv:1205.6883},
  year   = {2015}
}

Comments

8 figures, 8 tables