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Aiming at understanding the origin of the electronic contribution to ferroelectric polarization in undoped manganites, we evaluate the Berry phase of orbital-polarizable Bloch electrons as an orbital ordering (OO) establishes in the…

Strongly Correlated Electrons · Physics 2011-02-25 P. Barone , K. Yamauchi , S. Picozzi

All-electrical control of a dynamic magnetoelectric effect is demonstrated in a classical multiferroic manganite DyMnO3, a material containing coupled antiferromagnetic and ferroelectric orders. Due to intrinsic magnetoelectric coupling…

Strongly Correlated Electrons · Physics 2017-04-06 A. Shuvaev , V. Dziom , Anna Pimenov , M. Schiebl , A. A. Mukhin , A. Komarek , T. Finger , M. Braden , A. Pimenov

Electric-field controlled exchange bias in a heterostructure composed of the ferromagnetic manganite La0.7Sr0.3MO3 and the ferroelectric antiferromagnetic BiFeO3 has recently been demonstrated experimentally. By means of a microscopic model…

Strongly Correlated Electrons · Physics 2011-07-19 M. J. Calderon , S. Liang , R. Yu , J. Salafranca , S. Dong , S. Yunoki , L. Brey , A. Moreo , E. Dagotto

Charge-order-driven ferroelectrics are an emerging class of functional materials, distinct from conventional ferroelectrics, where electron-dominated switching can occur at high frequency. Despite their promise, only a few systems…

Materials Science · Physics 2020-02-19 Se Young Park , Karin M. Rabe , Jeffrey B. Neaton

We describe the design of a new magnetic ferroelectric with large spontaneous magnetization and polarization using first-principles density functional theory. The usual difficulties associated with the production of robustly-insulating…

Materials Science · Physics 2011-11-09 Pio Baettig , Nicola Spaldin

The physics of ferromagnetic doped manganites, such as \chem{La_{1-x}Ca_xMnO_3} with $x\approx0.2$--0.4, is reviewed. The concept of double exchange is discussed within the general framework of itinerant electron magnetism. The new feature…

Strongly Correlated Electrons · Physics 2015-06-24 D. M. Edwards

We present the microscopic theory of improper multiferroicity in BiMnO3, which can be summarized as follows: (1) the ferroelectric polarization is driven by the hidden antiferromagnetic order in the otherwise centrosymmetric C2/c structure;…

Materials Science · Physics 2010-11-01 I. V. Solovyev , Z. V. Pchelkina

Recent progress in the field of multiferroics led to the discovery of many new materials in which ferroelectricity is induced by cycloidal spiral orders. The direction of the electric polarization is typically constrained by spin…

Although multiferroics have undergone extensive examination for several decades, the occurrence of ferroelectricity induced by orbital order is only scarcely documented. In this study, we propose the existence of spontaneous ferroelectric…

Materials Science · Physics 2025-01-07 Xiao-Feng Luo , Xu He , Rui Wang , Hongjun Xiang , Jin-Zhu Zhao

Multiferroics, materials where spontaneous long-range magnetic and dipolar orders coexist, represent an attractive class of compounds, which combine rich and fascinating fundamental physics with a technologically appealing potential for…

Materials Science · Physics 2015-05-13 Silvia Picozzi , Claude Ederer

Two dimensional multiferroics inherit prominent physical properties from both low dimensional materials and magnetoelectric materials, and can go beyond their three dimensional counterparts for their unique structures. Here, based on…

Materials Science · Physics 2021-09-29 Mingyu Zhao , Jun Chen , Shan-Shan Wang , Ming An , Shuai Dong

We show that charge ordered rare-earth nickelates of the type RNiO3 (R= Ho, Lu, Pr and Nd) are multiferroic with very large magnetically induced ferroelectric (FE) polarizations. This we determine from first principles electronic structure…

Strongly Correlated Electrons · Physics 2010-07-15 Gianluca Giovannetti , Sanjeev Kumar , Daniel Khomskii , Silvia Picozzi , Jeroen van den Brink

Inspired by the strong experimental evidence for the coexistence of localized and itinerant charge carriers close to the metal-insulator transition in the ferromagnetic phase of colossal magnetoresistive manganese perovskites, for a…

Strongly Correlated Electrons · Physics 2007-05-23 A. Weisse , J. Loos , H. Fehske

A new type of multiferroicity was experimentally discovered in 2003 in a perovskite manganite TbMnO$_3$ where its ferroelectricity is induced by cycloidally ordered Mn spins. Susequently, such spin-cycloid multiferroic phase was also…

Strongly Correlated Electrons · Physics 2025-02-14 Masahito Mochizuki

Magnetic structures and the relationship between spin and charge-orbital orderings of an A-site ordered double-perovskite manganite SmBaMn2O6, an anticipated multiferroic material, were investigated by means of neutron diffraction. The spin…

Strongly Correlated Electrons · Physics 2021-07-14 Ryoji Kiyanagi , Shigeki Yamada , Hiroshi Aoki , Hajime Sagayama , Taketo Moyoshi , Akiko Nakao , Takahisa Arima

We report on structural, magnetic, dielectric, and thermodynamic properties of (Eu:Y)MnO3 for Y doping levels 0 <= x < 1. This system resembles the multiferroic perovskite manganites RMnO3 (with R= Gd, Dy, Tb) but without the interference…

Strongly Correlated Electrons · Physics 2015-06-25 J. Hemberger , F. Schrettle , A. Pimenov , P. Lunkenheimer , V. Yu. Ivanov , A. A. Mukhin , A. M. Balbashov , A. Loidl

The Zener polarons recently found in half-doped manganites are usually seen as mixed valence entities ruled by a double exchange Hamiltonian involving only correlated electrons of the metals. They can however be considered as ferrimagnetic…

Strongly Correlated Electrons · Physics 2015-06-25 Roland Bastardis , Nathalie Guihery , Nicolas Suaud

Multiferroics where at least two primary ferroic orders are present and coupled in a single system constitute an important class of materials. They attracted special consideration as they present both intriguing fundamental physics problems…

The possibility of multiferroicity arising from charge ordering in LuFe2O4 and structurally related rare earth ferrites is reviewed. Recent experimental work on macroscopic indications of ferroelectricity and microscopic determination of…

Strongly Correlated Electrons · Physics 2013-06-13 Manuel Angst

In rhombohedral CaMn7O12, an improper ferroelectric polarization of magnitude 2870 {\mu}C m-2 is induced by an incommensurate helical magnetic structure that evolves below TN1 = 90 K. The electric polarization was found to be constrained to…

Strongly Correlated Electrons · Physics 2015-05-30 R. D. Johnson , L. C. Chapon , D. D. Khalyavin , P. Manuel , P. G. Radaelli , C. Martin