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We report electrically switchable polarization and ferroelectric domain scaling over a thickness range of 5-100 nm in BiFeO3 films deposited on [110] vicinal substrates. The BiFeO3 films of variable thickness were deposited with SrRuO3…

The proton ordering model for the KH$_{2}$PO$_{4}$ type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we…

Materials Science · Physics 2015-02-10 A. S. Vdovych , A. P. Moina , R. R. Levitskii , I. R. Zachek

Layers of perovskites, found in 3D materials, 2D heterostructures, and nanotubes, often distort from high symmetry to facilitate dipole polarisation that is exploitable in many applications. Using density-functional theory calculations,…

Materials Science · Physics 2025-11-14 Shaowen Xu , Jeffrey R. Reimers , Fanhao Jia , Wei Ren

We investigated the time-dependent polarization switching behaviors of (111)-preferred polycrystalline Pb(ZrxTi1-x)O3 thin films with various Zr concentrations. We could explain all the polarization switching behaviors well by assuming…

Materials Science · Physics 2009-11-13 J. Y. Jo , S. M. Yang , H. S. Han , D. J. Kim , W. S. Choi , T. W. Noh , T. K. Song , J. -G. Yoon , C. -Y. Koo , J. -H. Cheon , S. -H. Kim

The observation of ferroelectric, ferromagnetic and ferroelastic phases in thin films of binary oxides attract the broad interest of scientists and engineers. However, the theoretical consideration of observed behaviour physical nature was…

Materials Science · Physics 2020-12-08 Maya Glinchuk , Anna Morozovska , Lesya Yurchenko

To elucidate a novel pressure-temperature phase diagram of the quasi-one-dimensional mixed-stack charge-transfer (CT) complex TTF-CA, we study the quasi-one-dimensional spin-1 Blume-Emery-Griffith (BEG) model. In addition to the local…

Strongly Correlated Electrons · Physics 2009-11-10 Jun-ichiro Kishine , Tadeusz Luty , Kenji Yonemitsu

Low dimensional ferroelectrics are highly desired for applications and full of exotic physics. Here a functionalized MXene Hf$_2$CF$_2$ monolayer is theoretically studied, which manifests a nonpolar to polar transition upon moderate biaxial…

Materials Science · Physics 2021-11-17 Ziwen Wang , Ning Ding , Churen Gui , Shanshan Wang , Ming An , Shuai Dong

Ferroelectricity and metallicity cannot coexist due to the screening effect of conducting electrons, and a large number of stable monolayers with 1T/1T$^{\prime}$ phase lack spontaneous polarization due to inversion symmetry. In this work,…

Materials Science · Physics 2023-09-26 Haohao Sheng , Zhong Fang , Zhijun Wang

Materials with ferroelectrically switchable topological properties are of interest for both fundamental physics and practical applications. Using first-principles calculations, we find that stacking ferroelectric $\alpha$-In$_2$Se$_3$…

Materials Science · Physics 2024-02-29 Zhiqiang Tian , Ziming Zhu , Jiang Zeng , Chao-Fei Liu , Yurong Yang , Anlian Pan , Mingxing Chen

A stochastic model of electric field-driven polarization reversal in orthorhombic ferroelectrics is advanced, providing a description of their temporal electromechanical response. The theory accounts for all possible parallel and sequential…

The temperature-dependent polarization of SrTiO_3 thin films is investigated using confocal scanning optical microscopy. A homogeneous out-of-plane and inhomogeneous in-plane ferroelectric phase are identified from images of the linear…

Materials Science · Physics 2009-11-07 Oleg Tikhomirov , Hua Jiang , Jeremy Levy

A long standing problem of domain switching process - how domains nucleate - is examined in ultrathin ferroelectric films. We demonstrate that the large depolarization fields in ultrathin films could significantly lower the nucleation…

Materials Science · Physics 2009-11-11 J. Y. Jo , D. J. Kim , Y. S. Kim , S. -B. Choe , T. K. Song , J. -G. Yoon , T. W. Noh

We present a general, systematic theory of electromagnetism and chirality in crystalline solids. Symmetry is its basic guiding principle, enabling us to consider macroscopic multipole densities without reference to any specific microscopic…

Materials Science · Physics 2025-06-26 R. Winkler , U. Zülicke

Simulating percolation and critical phenomena of labelled species inside films composed of single-component linear homogeneous macromolecules using molecular Monte Carlo method in 3 dimensions, we study dependence of these conducting…

Soft Condensed Matter · Physics 2019-09-05 Yuki Norizoe , Hiroshi Morita

Theoretical investigation demonstrates that the composite bilayer (i.e., chiral-magnetic/ferroelectric bilayer) offers the possibility of electric-induced magnetic Skyrmions [Phys. Rev. B \textbf{94}, 014311 (2016)]. In this Article, we…

Mesoscale and Nanoscale Physics · Physics 2016-08-29 Zidong Wang , Malcolm Grimson

In a recent letter [Phys. Rev. Lett. {\bf 75}, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of…

Disordered Systems and Neural Networks · Physics 2009-10-30 G. Ayton , M. J. P. Gingras , G. N. Patey

Flexible ferroelectrics possess significant potential for wearable electronics and bio-inspired devices, yet their electromechanical coupling mechanisms under dynamic bending remain elusive. This study employs phase-field simulations to…

Materials Science · Physics 2025-12-16 Changqing Guo , Letao Yang , Jing Wang , Houbing Huang

Strong coupling between electrical and mechanical phenomena and the presence of switchable polarization have enabled applications of ferroelectric materials for nonvolatile memories (FeRAM), data storage, and ferroelectric lithography.…

Organic ferroelectric materials are in demand in the growing field of environmentally friendly, lightweight electronics. Donor-Acceptor charge transfer crystals have been recently proposed as a new class of organic ferroelectrics, which may…

Materials Science · Physics 2024-11-26 Alberto Girlando

The hyperfine interaction between the quadrupole moment of atomic nuclei and the electric field gradient (EFG) provides information on the electronic charge distribution close to a given atomic site. In ferroelectric materials, the loss of…

Materials Science · Physics 2012-07-31 J. N. Gonçalves , A. Stroppa , J. G. Correia , T. Butz , S. Picozzi , A. S. Fenta , V. S. Amaral