Related papers: Dewetting dynamics of stressed viscoelastic thin p…
The dewetting dynamics of ultrathin polymer films, e.g. in the model system of polystyrene on a polydimethylsiloxane-covered substrate, exhibits interesting behavior like a fast decay of the dewetting velocity and a maximum in the width of…
Dewetting of thin polystyrene films deposited onto silicone wafers at temperatures close to the glass transition exhibits unusual dynamics and front morphologies. Here, we present a new theoretical approach of these phenomena taking into…
The study of the dewetting of very thin polymer films has recently revealed many unexpected features (e.g. unusual rim morphologies and front velocities) which have been the focus of several theoretical models. Surprisingly, the most…
Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on…
An experimental investigation is reported on the effect of shear on the bursting of molten ultra-thin polymer films embedded in an immiscible matrix. By using an optical microscope coupled with a shearing hotstage, the dewetting dynamics,…
Ultrathin polymer films on non-wettable substrates display dynamic features which have been attributed to either viscoelastic or slip effects. Here we show that in the weak and strong slip regime effects of viscoelastic relaxation are…
The dewetting dynamics of an ultrathin film is studied in the presence of evaporation - or reaction - of adatoms on the substrate. KMC simulations are in good agreement with an analytical model with diffusion, rim facetting, and substrate…
In this paper we present a theoretical model for the dewetting of ultra-thin polymer films. Assumming that the shear-thinning properties of these films can be described by a Cross-type constitutive equation, we analyze the front morphology…
The fluid dynamics of the classical dewetting instability in ultrathin films is a non-linear process. However, the physical manifestation of the instability in terms of characteristic length and time scales can be described by a linearized…
We study the deformation and dewetting of liquid films under impinging gas jets using experimental, analytical and numerical techniques. We first derive a reduced-order model (a thin-film equation) based on the long-wave assumption and on…
The instability, dynamics and morphological transitions of patterns in thin liquid films on periodic striped surfaces (consisting of alternating less and more wettable stripes) are investigated based on 3-D nonlinear simulations that…
This work presents a study of the interfacial dynamics of thin viscoelastic films subjected to the gravitational force and substrate interactions induced by the disjoining pressure, in two spatial dimensions. The governing equation is…
Probing the fluid dynamics of thin films is an excellent tool to study the solid/liquid boundary condition. There is no need for external stimulation or pumping of the liquid due to the fact that the dewetting process, an internal…
A gradient dynamics model based on an extended interface Hamiltonian is presented that is able to describe the dynamics of structuring processes in thin films of liquid mixtures, solutions and suspensions on solid substrates including…
We investigate two destabilization mechanisms for elastic polymer films and put them into a general framework: first, instabilities due to in-plane stress and second due to an externally applied electric field normal to the film's free…
Vapor deposition on polycrystalline films can lead to staggering levels of compressive stress, exceeding even the yield strength of the films. Mysteriously, a significant part of this stress has a reversible nature: it disappears when the…
The dewetting of thin nanofilms is significantly impacted by thermal fluctuations, liquid-solid slip, and disjoining pressure, which can be described by lubrication equations augmented by appropriately scaled noise terms, known as…
We study theoretically the profile evolution of a thin viscoelastic film supported onto a no-slip flat substrate. Due to the nonconstant initial curvature at the free surface, there is a flow driven by Laplace pressure and mediated by…
Liquid films of nanometric thickness are prone to spinodal dewetting driven by disjoining pressure, meaning that a non-wetting liquid film of homogeneous thickness in the range of tens of nanometers will spontaneously break into droplets.…
The structural aspects of polyacrylamide thin films annealed at degradation threshold temperature have been studied as a function of annealing time using in situ X-ray reflectivity technique in vacuum. We observe significant decrease of…