Related papers: Gibbs' theorem for open systems with incomplete st…
The Boltzmann and Gibbs approaches to statistical mechanics have very different definitions of equilibrium and entropy. The problems associated with this are discussed and it is suggested that they can be resolved, to produce a version of…
There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other…
A statistical system is classically defined on a set of microstates $E$ by a global energy function $H : E \to \mathbb{R}$, yielding Gibbs probability measures (softmins) $\rho^\beta(H)$ for every inverse temperature $\beta = T^{-1}$. Gibbs…
We propose a unifying picture where the notion of generalized entropy is related to information theory by means of a group-theoretical approach. The group structure comes from the requirement that an entropy be well defined with respect to…
It has been suggested recently that `$q$-exponential' distributions which form the basis of Tsallis' non-extensive thermostatistical formalism may be viewed as mixtures of exponential (Gibbs) distributions characterized by a fluctuating…
We consider a generic system composed of a fixed number of particles distributed over a finite number of energy levels. We make only general assumptions about system's properties and the entropy. System's constraints other than fixed number…
We study the relative entropy density for generalized Gibbs measures. We first show its existence and obtain a familiar expression in terms of entropy and relative energy for a class of ``almost Gibbsian measures'' (almost sure continuity…
The Boltzmann--Gibbs entropy is a functional on the space of probability measures. When a state space is countable, one characterization of the Boltzmann--Gibbs entropy is given by the Shannon--Khinchin axioms, which consist of continuity,…
As the most fundamental empirical law, Zipf's law has been studied from many aspects. But its meaning is still an open problem. Some models have been constructed to explain Zipf's law. In the letter, a new concept named nonsymmetric entropy…
Using a game theory approach and a new extremal problem, Gibbs formula is proved in a most simple and general way for the classical mechanics case. A corresponding conjecture on the asymptotics of the classical entropy is formulated. For…
In this paper, we study a class of multilinear Gibbs measures with Hamiltonian given by a generalized $\mathrm{U}$-statistic and with a general base measure. Expressing the asymptotic free energy as an optimization problem over a space of…
The critique against using Boltzmann's microcanonical entropy, an "ensemble measure", as foundation of statistics is rebuffed. The confusion of the microcanonical distribution with the exponential Boltzmann-Gibbs (``BG'') distribution is…
Statistical mechanics for states with complex eigenvalues, which are described by Gel'fand triplet and represent unstable states like resonances, are discussed on the basis of principle of equal ${\it a priori}$ probability. A new entropy…
We study the temporal approach to equilibrium of the Gibbs' and conditional entropies for both invertible deterministic dynamics as well as non-invertible stochastic systems in the presence of white noise. The conditional entropy will…
A generalization of the Gibbs-von Neumann relative entropy is proposed based on the quantum BBGKY [Bogolyubov-Born-Green-Kirkwood-Yvon] hierarchy as the nonequilibrium entropy for an N-body system. By using a generalization of the…
The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…
Equilibrium statistical mechanics is intended to link the microscopic dynamics of particles to the thermodynamic laws for macroscopic quantities. However, the modern statistical theory is faced with significant difficulties, as applied to…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
Although G\"odel's incompleteness theorem made mathematician recognize that no axiomatic system could completely prove its correctness and that there is an eternal hole between our knowledge and the world, physicists so far continue to work…
In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of…