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Related papers: Polymer desorption under pulling: a novel dichotom…

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Forced desorption of a semiflexible polymer chain on a solid substrate is theoretically investigated. The pulling force versus displacement is studied for different adsorption energy and persistence length P. It is found that the…

Statistical Mechanics · Physics 2015-06-19 Pui-Man Lam , Yi Zhen

We investigate the cooperative effects of a single finite chain of monomers near an attractive substrate by first constructing a conformational pseudo-phase diagram based on the thermal fluctuations of energetic and structural quantities.…

Soft Condensed Matter · Physics 2011-07-01 Monika Möddel , Wolfhard Janke , Michael Bachmann

We deduce the qualitative phase diagram of a long flexible neutral polymer chain immersed in a poor solvent near an attracting surface using phenomenological arguments. The actual positions of the phase boundaries are estimated numerically…

Statistical Mechanics · Physics 2009-11-07 R. Rajesh , Deepak Dhar , Debaprasad Giri , Sanjay Kumar , Yashwant Singh

Polymer adsorption on fractally rough walls of varying dimensionality is studied by renormalization group methods on hierarchical lattices. Exact results are obtained for deterministic walls. The adsorption transition is found continuous…

Statistical Mechanics · Physics 2007-05-23 G. Giugliarelli , A. L. Stella

In order to study long chain polymers many lattice models accommodate a pulling force applied to a particular part of the chain, often a free endpoint. This is in addition to well-studied features such as energetic interaction between the…

Statistical Mechanics · Physics 2023-07-19 C. J. Bradly , A. L. Owczarek

A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate…

Soft Condensed Matter · Physics 2009-11-13 Jutta Luettmer-Strathmann , Federica Rampf , Wolfgang Paul , Kurt Binder

Using Molecular Dynamics simulations, we study the force-induced detachment of a coarse-grained model polymer chain from an adhesive substrate. One of the chain ends is thereby pulled at constant speed off the attractive substrate and the…

Soft Condensed Matter · Physics 2015-06-22 J. Paturej , A. Erbas , A. Milchev , V. G. Rostiashvili

We analyze equilibrium properties and adsorption desorption phase transition behaviour of a linear semiflexible copolymer chain under constrained geometrical situation on square lattice in a good solvent. One dimensional stair shaped line…

Statistical Mechanics · Physics 2010-06-04 Pramod Kumar Mishra

The behavior of a strongly charged polymer adsorbed on an oppositely charged surface of low-dielectric constant is formulated by the functional integral method. By separating the translational, conformational, and fluctuational degrees of…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

We consider the adsorption of a semiflexible polymer chain onto interfaces and surfaces by using the differential equation of the distribution function $G(R,L)$ of the end-to-end distance $R$, which is associated with the moment expansion…

Soft Condensed Matter · Physics 2009-11-07 Semjon Stepanow

We study the problem of adsorption and collapse transition of a linear polymer chain situated in a fractal container represented by a 4-simplex lattice and interacting with a surface adsorbed linear polymer chain. The adsorbed chain…

Statistical Mechanics · Physics 2009-10-31 Sanjay Kumar , Yashwant Singh

An applied tension force changes the equilibrium conformations of a polymer chain tethered to a planar substrate and thus affects the adsorption transition as well as the coil-globule and crystallization transitions. Conversely, solvent…

Soft Condensed Matter · Physics 2015-06-22 Jutta Luettmer-Strathmann , Kurt Binder

We investigated the influence of short- and long-range correlated quenched disorder introduced into the medium on the process of adsorption of long-flexible polymer chains on a wall by using the field theoretical approach in $d=4-\epsilon$…

Disordered Systems and Neural Networks · Physics 2007-05-23 Z. Usatenko , A. Ciach

We formulate and characterize a model to describe the dynamics of semiflexible polymers in the presence of activity due to motor proteins attached irreversibly to a substrate, and a transverse pulling force acting on one end of the…

Biological Physics · Physics 2016-02-12 Abhishek Chaudhuri , Debasish Chaudhuri

Conformations of partially or fully adsorbed semiflexible polymer chains are studied varying both contour length $L$, chain stiffness, $\kappa$, and the strength of the adsorption potential over a wide range. Molecular Dynamics simulations…

Soft Condensed Matter · Physics 2019-10-02 Andrey Milchev , Kurt Binder

A phase diagram for a surface-interacting long flexible polymer chain in a two-dimensional poor solvent where the possibility of collapse exists is determined using exact enumeration method. A model of a self-attracting self avoiding walk…

Statistical Mechanics · Physics 2007-05-23 Yashwant Singh , Debaprasad Giri , Sanjay Kumar

We study self-avoiding walks on the square lattice restricted to a square box of side $L$ weighted by a length fugacity without restriction of their end points. This models a confined polymer in dilute solution. The model admits a phase…

Statistical Mechanics · Physics 2022-07-22 C. J. Bradly , A. L. Owczarek

We use Brownian dynamics simulations and analytical theory to compare two prominent types of single molecule transitions. One is the adsorption transition of a loop (a chain with two ends bound to an attractive substrate) driven by an…

Monte Carlo simulations using an explicit solvent model indicate a new pathway for translocation of a polymer chain through a lipid bilayer. We consider a polymer chain composed of repeat units with a given hydrophobicity and a…

Soft Condensed Matter · Physics 2012-05-22 Jens-Uwe Sommer , Marco Werner , Vladimir A. Baulin

In detailed microcanonical analyses of densities of states obtained by extensive multicanonical Monte Carlo computer simulations, we investigate the caloric properties of conformational transitions adsorbing polymers experience near…

Statistical Mechanics · Physics 2019-03-27 Monika Möddel , Wolfhard Janke , Michael Bachmann