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Highly ordered periodic arrays of silver nanoparticles have been fabricated which exhibit surface plasmon resonances in the visible spectrum. We demonstrate the ability of these structures to alter the fluorescence properties of vicinal dye…

Other Condensed Matter · Physics 2009-11-13 Nic Cade , Tom Ritman-Meer , David Richards

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

We demonstrate Purcell-like enhancement of Rayleigh scattering into a single optical mode of a Fabry-Perot resonator for several thermal atomic and molecular gases. The light is detuned by more than an octave, in this case by hundreds of…

Quantum Physics · Physics 2010-06-14 Michael Motsch , Martin Zeppenfeld , Pepijn W. H. Pinkse , Gerhard Rempe

We propose and demonstrate a novel technique that combines Raman scattering and optical cycling in molecules with diagonal Franck-Condon factors. This resonance Raman optical cycling manipulates molecules to behave like efficient…

Atomic Physics · Physics 2021-08-26 J. C. Shaw , J. C. Schnaubelt , D. J. McCarron

We investigate the quantum optical properties of a single photon emitter coupled to a finite-size metal nanoparticle using a photon Green function technique that rigorously quantizes the electromagnetic fields. We first obtain pronounced…

Mesoscale and Nanoscale Physics · Physics 2012-02-07 C. Van Vlack , Philip Trøst Kristensen , S. Hughes

Quantum entanglement offers an incredible resource for enhancing the sensing and spectroscopic probes. Here we develop a microscopic theory for the stimulated Raman scattering (SRS) using entangled photons. We demonstrate that the…

Quantum Physics · Physics 2026-01-21 Mingran Zhang , Jiahao Joel Fan , Frank Schlawin , Zhedong Zhang

Raman spectroscopy is a powerful tool to detect, analyze and identify molecules. It has been a long-history pursuit to push the detection limit of Raman spectroscopy down to the fundamental single-molecule (SM) level. Due to the tiny cross…

Optics · Physics 2023-11-10 Haiyao Yang , Haoran Mo , Lihong Hong , Zhi-Yuan Li

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

We show that spontaneous Raman scattering of incident radiation can be observed in cavity-QED systems without external enhancement or coupling to any vibrational degree of freedom. Raman scattering processes can be evidenced as resonances…

Single dye molecules at cryogenic temperatures display many spectroscopic phenomena known from free atoms and are thus promising candidates for fundamental quantum optical studies. However, the existing techniques for the detection of…

Quantum Physics · Physics 2008-02-12 Gert Wrigge , Ilja Gerhardt , Jaesuk Hwang , Gert Zumofen , Vahid Sandoghdar

Surface enhanced Raman scattering (SERS) effects on tin dioxide in the form of bulk material, nanostructured thin films and colloidal solutions were investigated. Raman spectra are characterized by the three Raman scattering peaks at 478,…

Materials Science · Physics 2015-06-03 Enza Fazio , Fortunato Neri , Salvatore Savasta , Salvatore Spadaro , Sebastiano Trusso

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We investigate the coupling of a single molecule to a single spherical gold nanoparticle acting as a nano-antenna. Using scanning probe technology, we position the particle in front of the molecule with nanometer accuracy and measure a…

Other Condensed Matter · Physics 2009-11-11 S. Kuehn , U. Hakanson , L. Rogobete , V. Sandoghdar

The coupling of nanostructures with emitters opens ways for the realization of man-made subwavelength light emitting elements. In this article, we investigate the modification of fluorescence when an emitter is placed close to a…

Other Condensed Matter · Physics 2009-11-13 S. Kuehn , G. Mori , M. Agio , V. Sandoghdar

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

We demonstrate a single-photon source based on a quantum dot in a micropost microcavity that exhibits a large Purcell factor together with a small multi-photon probability. For a quantum dot on resonance with the cavity, the spontaneous…

Quantum Physics · Physics 2009-11-10 Jelena Vuckovic , David Fattal , Charles Santori , Glenn Solomon , Yoshihisa Yamamoto

A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , M. Meyer , P. G. Etchegoin

We theoretically investigate the enhancement of surface enhanced Raman spectroscopy (SERS) using hyperbolic stratified nanostructures and compare to metal nanoresonators. The photon Green function of each nanostructure within its…

Integrated photonic circuits provide a versatile toolbox of functionalities for advanced quantum optics applications. Here, we demonstrate an essential component of such a system in the form of a Purcell enhanced single-photon source based…

Mesoscale and Nanoscale Physics · Physics 2020-09-11 Łukasz Dusanowski , Dominik Köck , Eunso Shin , Soon-Hong Kwon , Christian Schneider , Sven Höfling

We report the observations of spontaneous Raman scattering in silicon photonic crystal waveguides. Continuous-wave measurements of Stokes emission for both wavelength and power dependence is reported in single line-defect waveguides in…

Optics · Physics 2009-11-13 J. F. McMillan , M. Yu , D. L. Kwong , C. W. Wong