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Isolated hydrogen and hydrogen pairs in bulk diamond matrix have been studied using density functional theory calculations. The electronic structure and stability of isolated and paired hydrogen defects are investigated at different…

Materials Science · Physics 2014-04-28 Ashutosh Upadhyay , Akhilesh Kumar Singh , Amit Kumar

We investigate the equilibrium geometries and the systematics of bonding in various isomers of a 24-atom boron cluster using Born-Oppenheimer molecular dynamics within the framework of density functional theory. The isomers studied are the…

Atomic and Molecular Clusters · Physics 2009-11-10 S. Chacko , D. G. Kanhere , I. Boustani

A multitude of observed boron-based materials have outstanding superconducting, mechanical, and refractory properties. Yet, the structure, the composition, and the very existence of some reported metal boride (M-B) compounds have been a…

Materials Science · Physics 2014-10-03 A. G. Van Der Geest , A. N. Kolmogorov

We present {\it ab initio} density-functional calculations of molecular solids formed from C$_{28}$-derived closed-shell fullerenes. Solid C$_{28}$H$_4$ is found to bind weakly and exhibits many of the electronic structure features of solid…

Superconductivity · Physics 2009-11-10 Nichols A. Romero , Jeongnim Kim , Richard M. Martin

We investigate a supersolid state in hardcore boson models on the face-centered-cubic (FCC) lattice. The supersolid state is characterized by a coexistence of crystalline order and superfluidity. Using a quantum Monte Carlo method based on…

Superconductivity · Physics 2009-11-11 Takahumi Suzuki , Naoki Kawashima

Despite the composition close to glassy forming alloys, face centered cubic (FCC) Co81.8Si9.1B9.1, designed based on Co9B atomic cluster (polyhedral), are synthesized as singlephase ribbons successfully. These ribbons, with grain sizes of…

Materials Science · Physics 2019-02-15 Jiliang Zhang , Guangcun Shan , Yuefei Zhang , Fazhu Ding , Chan Hung Shek

The crystal structure of iron in the Earth's inner core remains debated. Most recent experiments suggest a hexagonal-close-packed (hcp) phase. In simulations, it has been generally agreed that the hcp-Fe is stable at inner core pressures…

Geophysics · Physics 2018-04-17 Rostislav Hrubiak , Yue Meng , Guoyin Shen

A set of general constructing schemes is unveiled to predict a large family of stable boron monoelemental, hollow fullerenes with magic numbers 32+8k (k>=0). The remarkable stabilities of these new boron fullerenes are then studied by…

Materials Science · Physics 2009-11-13 Qing-Bo Yan , Xian-Lei Sheng , Qing-Rong Zheng , Li-Zhi Zhang , Gang Su

Dense QCD at zero temperature with a large number of colors is a crystal. We show that in the holographic dual description, the crystal is made out of pairs of dyons with $e=g=\pm 1$ charges in a salt-like arrangement. We argue that with…

High Energy Physics - Theory · Physics 2010-05-25 Mannque Rho , Sang-Jin Sin , Ismail Zahed

Motivated by contradicting reports in the literature, we have investigated the structural stability of tungsten nanoparticles using density functional theory calculations. The comparison of BCC, FCC, A15, disordered, and icosahedral…

Materials Science · Physics 2024-04-08 Laurent Pizzagalli , Sandrine Brochard , Julien Godet , Julien Durinck

We have found that a beryllium (Be) atom on nanostructured materials with H2 molecules generates a Kubas-like dihydrogen complex [H. Lee et al. arXiv:1002.2247v1 (2010)]. Here, we investigate the feasibility of Be-decorated fullerenes for…

Materials Science · Physics 2015-05-18 Hoonkyung Lee , Bing Huang , Wenhui Duan , Jisoon Ihm

A systematic first-principles study within density functional theory on the geometrical structures and electronic properties of unconventional fullerene C64 and its derivatives C64X4 (X = H; F;Cl;Br) has been performed. By searching through…

Materials Science · Physics 2008-01-23 Qing-Bo Yan , Qing-Rong Zheng , Gang Su

This work demonstrates that the convex hull of formation energies for solid compounds involving elements from hydrogen to uranium admits a remarkably simple description over the 92-dimensional space of chemical compositions, despite the…

In this study, based on density functional theory (DFT), we propose a new branch of pseudo-fullerenes which contain triple bonds with sp hybridization. We should call these new nanostructures fullerynes, according to IUPAC. We present four…

Materials Science · Physics 2020-03-24 Mohammad Qasemnazhand , Farhad Khoeini , Farah Marsusi

Structural, mechanical, electronic, and thermodynamic properties of fluorite and tetragonal phases of ZrH$_{2}$ are systematically studied by employing the density functional theory within generalized gradient approximation. The existence…

Materials Science · Physics 2010-08-02 Peng Zhang , Bao-Tian Wang , Chao-Hui He , Ping Zhang

Plasticity in body centered cubic (bcc) refractory metals are largely due to the stress tensor induced either by solute or thermal activation. The mechanism of the solute atom(s) residence causes instability in such metals. Earlier research…

Materials Science · Physics 2021-07-23 Henry Martin , Peter Amoako-Yirenkyi , Eric Kwabena Kyeh Abavare

Single crystal elastic constants of bcc iron and bct FeC and FeN alloys, martensites, have been evaluated by ab initio calculations based on the density functional theory. The energy of a strained crystal has been computed using the…

Materials Science · Physics 2015-08-04 Maaouia Souissi , Hiroshi Numakura

We use ab initio density functional calculations to study the formation and structural as well as thermal stability of cellular foam-like carbon nanostructures. These systems with a mixed $sp^2/sp^3$ bonding character may be viewed as…

Materials Science · Physics 2015-06-11 Zhen Zhu , David Tománek

A good hydrogen storage material should adsorb hydrogen in high concentrations and with optimal binding energies. Numerous mixed carbon boron fullerenes which are decorated with metal atoms were previously constructed by hand and proposed…

Materials Science · Physics 2018-02-13 Deb Sankar De , Santanu Saha , Luigi Genovese , Stefan Goedecker

A free-energy functional for a crystal that contains both the symmetry conserved and symmetry broken parts of the direct pair correlation function is developed. The free-energy functional is used to investigate the crystallization of fluids…

Soft Condensed Matter · Physics 2015-05-13 Swarn Lata Singh , Yashwant Singh