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We theoretically propose to directly observe the chiral nature of charge carriers in graphene mono- and bilayers within a controlled scattering experiment. The charge located on a capacitively coupled scanning probe microscope (SPM) tip…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Matthias Braun , Luca Chirolli , Guido Burkard

Graphene was deposited on a transparent and flexible substrate and tensile strain up to ~0.8% was loaded by stretching the substrate in one direction. Raman spectra of strained graphene show significant redshifts of 2D and G band (-27.8…

Materials Science · Physics 2008-10-21 Zhen Hua Ni , Ting Yu , Yun Hao Lu , Ying Ying Wang , Yuan Ping Feng , Ze Xiang Shen

Creating defects in graphene by hydrogenation, either to achieve hydrogen chemisorption or partial etching, is a way to open an electronic band gap in graphene. Understanding the range of stability conditions of partially etched or…

The intensity ratio between two major Raman bands in graphene is one of the most important information for physics of graphene and has been believed to represent various intrinsic properties of graphene without critical assessment of…

A simple, non-invasive method using Raman spectroscopy for the estimation of the thickness of graphene layers grown epitaxially on silicon carbide (SiC) is presented, enabling simultaneous determination of thickness, grain size and disorder…

Materials Science · Physics 2015-05-13 Shriram Shivaraman , M. V. S. Chandrashekhar , John J. Boeckl , Michael G. Spencer

We report a molecular dynamics study on the tensile mechanics of graphene as gradually rotating the tensile direction from armchair to zigzag direction, covering the complete range of chiral directions which has never been explored so far.…

Materials Science · Physics 2013-01-30 Young In Jhon , Myung S. Jhon

In this work we explore mechanical properties of graphene samples of variable thickness. For this purpose, we coupled a high pressure sapphire anvil cell to a micro-Raman spectrometer. From the evolution of the G band frequency with stress…

We uncover the interlayer shear mode of multi-layer graphene samples, ranging from bilayer-graphene (BLG) to bulk graphite, and show that the corresponding Raman peak measures the interlayer coupling. This peak scales from~43cm-1 in bulk…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 P. H. Tan , W. P. Han , W. J. Zhao , Z. H. Wu , K. Chang , H. Wang , Y. F. Wang , N. Bonini , N. Marzari , G. Savini , A. Lombardo , A. C. Ferrari

We propose a mechanical granular graphene obtained by replacing the carbon atoms with macroscopic spherical stainless steel beads in contact. The experimental measured dispersion relation is presented, in conjunction with evidence of the…

Applied Physics · Physics 2019-06-05 Li-Yang Zheng , Florian Allein , Vincent Tournat , Vitalyi Gusev , Georgios Theocharis

Avoiding charge density variations and impurities in graphene is vital for high-quality graphene-based devices. Here, we demonstrate an optical method using Raman 2D peak-split to monitor charge density variations in the range 1-25e10 cm-2.…

Applied Physics · Physics 2020-05-12 Zhuofa Chen , Nathan Ullberg , Mounika Vutukuru , David Barton , Anna K Swan

Raman scattering data were collected on graphite monochromator. Spectra were interpreted in terms of the space group $P6_3mc$, a subgroup of space group $P6_3/mmc$. The latter has commonly been used for the interpretation of Raman…

Materials Science · Physics 2007-05-23 Y. Fujioka , J. Frantti , E. Yasuda , Y. Tanabe , M. Kakihana

Vibrational properties of graphene nanoribbons are examined with density functional based tight-binding method and non-resonant bond polarization theory. We show that the recently discovered reconstructed zigzag edge can be identified from…

Materials Science · Physics 2009-11-13 S. Malola , H. Häkkinen , P. Koskinen

Bottom-up approaches allow the production of ultra-narrow and atomically precise graphene nanoribbons (GNRs), with electronic and optical properties controlled by the specific atomic structure. Combining Raman spectroscopy and ab-initio…

Electrochemical exfoliation is one of the most promising methods for scalable production of graphene. However, limited understanding of its Raman spectrum as well as lack of measurement standards for graphene strongly limit its industrial…

We study theoretically the coherent electron focusing in graphene nanoribbons. Using semiclassical and numerical tight binding calculations we show that perfect armchair edges give rise to equidistant peaks in the focusing spectrum. In the…

Mesoscale and Nanoscale Physics · Physics 2010-03-22 Peter Rakyta , Andor Kormanyos , Jozsef Cserti , Pekka Koskinen

The band structures of strained graphene nanoribbons (GNRs) are examined by a tight binding Hamiltonian that is directly related to the type and strength of strains. Compared to the two-dimensional graphene whose band gap remains close to…

Mesoscale and Nanoscale Physics · Physics 2010-01-20 Yang Lu , Jing Guo

The 1+1 layer folded graphene sheets that deviate from AB stacking are successfully fabricated and their electronic structures are investigated by Raman spectroscopy. Significant blue shift of the 2D band of folded graphene compared to that…

Materials Science · Physics 2009-11-13 Zhenhua Ni , Yingying Wang , Ting Yu , Yumeng You , Zexiang Shen

We study the 2D Raman band of in-plane uniaxially strained graphene within a non-orthogonal tight-binding model. At non-zero strain, the obtained 2D band splits into two subbands at strain angles $0^{\circ}$ and $30^{\circ}$ or into three…

Mesoscale and Nanoscale Physics · Physics 2013-06-11 Valentin N. Popov , Philippe Lambin

Experiments are finally revealing intricate facts about graphene which go beyond the ideal picture of relativistic Dirac fermions in pristine two dimensional (2D) space, two years after its first isolation. While observations of rippling…

Other Condensed Matter · Physics 2009-11-13 Eun-Ah Kim , A. H. Castro Neto

The absolute integrated intensity of the single-phonon Raman peak at 1580 cm^{-1} is calculated for a clean graphene monolayer. The resulting intensity is determined by the trigonal warping of the electronic bands and the anisotropy of the…

Materials Science · Physics 2015-05-14 Denis Basko