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In Raman spectroscopy of graphite and graphene, the $D$ band at $\sim 1355$cm$^{-1}$ is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the $D$ band is closely related to a very…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ken-ichi Sasaki , Yasuhiro Tokura , Tetsuomi Sogawa

We calculate the static polarizability of multilayer graphene and study the effect of stacking arrangement, carrier density, and onsite energy difference on graphene screening properties. At low densities, the energy spectrum of multilayer…

Materials Science · Physics 2012-08-14 Hongki Min , E. H. Hwang , S. Das Sarma

Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain,…

Materials Science · Physics 2015-06-16 Andrea C. Ferrari , Denis M. Basko

We report strong variations in the Raman spectra for different single-layer graphene samples obtained by micromechanical cleavage, which reveals the presence of excess charges, even in the absence of intentional doping. Doping…

Materials Science · Physics 2008-01-07 C. Casiraghi , S. Pisana , K. S. Novoselov , A. K. Geim , A. C. Ferrari

The Raman shift, broadening, and relative Raman intensities of bilayer graphene are computed as functions of the electron concentration. We include dynamic effects for the phonon frequencies and we consider the gap induced in the band…

Materials Science · Physics 2009-09-11 Paola Gava , Michele Lazzeri , A. Marco Saitta , Francesco Mauri

On-surface synthesis enables the fabrication of graphene nanoribbons (GNRs) with atomic precision, allowing their electronic, optical, and magnetic properties to be tuned by engineering edge structure and width. Progress on the synthesis of…

An effective-mass theory with a deformation-induced (an axial) gauge field is proposed as a theoretical framework to study graphene edge. Though the gauge field is singular at edge, it can represent the boundary condition and this framework…

Mesoscale and Nanoscale Physics · Physics 2010-07-19 Ken-ichi Sasaki , Katsunori Wakabayashi

Charged impurity (CI) scattering is one of the dominant factors that affect the carrier mobility in graphene. In this paper, we use Raman spectroscopy to probe the charged impurities in suspended graphene. We find that the 2D band intensity…

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

Materials Science · Physics 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone

The Raman $2D$-band -important for the analysis of graphene- shows a splitting for uniaxial strain. The splitting depends on the strength and direction of the applied strain and on the polarization of the incident and outgoing light. We…

Materials Science · Physics 2010-12-07 Marcel Mohr , Janina Maultzsch , Christian Thomsen

In this report, we present Raman spectroscopy investigation of the thermal stability and dynamics of graphene edges. It was found that graphene edges (both armchair and zigzag) are not stable and undergo modifications even at temperature as…

Materials Science · Physics 2010-12-15 Ya Nan Xu , Da Zhan , Lei Liu , Hui Suo , Zhen Hua Ni , Thuong Thuong Nguyen , Chun Zhao , Ze Xiang Shen

The deformation of monolayer graphene, produced by chemical vapor deposition (CVD), on a polyester film substrate has been investigated through the use of Raman spectroscopy. It has been found that the microstructure of the CVD graphene…

Confocal Raman spectroscopy is a versatile, non-invasive investigation tool and a major workhorse for graphene characterization. Here we show that the experimentally observed Raman 2D line width is a measure of nanometer-scale strain…

The use of Raman scattering techniques to study the mechanical properties of graphene films is reviewed here. The determination of Gruneisen parameters of suspended graphene sheets under uni- and bi-axial strain is discussed and the values…

Materials Science · Physics 2015-05-19 Nicola Ferralis

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Sven Reichardt , Ludger Wirtz

Graphite is a well-studied material with known electronic and optical properties. Graphene, on the other hand, which is just one layer of carbon atoms arranged in a hexagonal lattice, has been studied theoretically for quite some time but…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 F. Molitor , D. Graf , C. Stampfer , T. Ihn , K. Ensslin

Rhombohedral graphite (RG) shows strong correlations in its topological flat band and is pivotal for exploring emergent, correlated electronic phenomena. One key advantage is the enhancement of electronic interactions with the increase in…

The energy of arbitrary graphene edge is derived in analytical form. It contains a "chemical phase shift", determined by the chemical conditions at the edge. Direct atomistic computations support the universal nature of the relationship.…

Mesoscale and Nanoscale Physics · Physics 2010-12-06 Yuanyue Liu , Alex Dobrinsky , Boris I. Yakobson

Raman spectroscopy is a powerful tool for characterizing the local properties of graphene. Here, we introduce a method for evaluating unknown strain configurations and simultaneous doping. It relies on separating the effects of hydrostatic…

Nanometer-scale graphene objects are attracting much research interest because of newly emerging properties originating from quantum confinement effects. We present Raman spectroscopy studies of graphene nanoribbons (GNRs) which are known…

Materials Science · Physics 2012-01-23 Sunmin Ryu , Janina Maultzsch , Melinda Y. Han , Philip Kim , Louis E. Brus