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We discuss the microscopic mechanisms by which low-temperature amorphous states, such as ultrastable glasses, transform into equilibrium fluids, after a sudden temperature increase. Experiments suggest that this process is similar to the…

Statistical Mechanics · Physics 2016-07-05 Robert L. Jack , Ludovic Berthier

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

Soft Condensed Matter · Physics 2010-10-01 Luca Cipelletti , Eric R. Weeks

We report the combined results of molecular dynamics simulations and theoretical calculations concerning various dynamical arrest transitions in a model system representing a dipolar fluid, namely, N (softcore) rigid spheres interacting…

The effect of cooling on the brittleness of glasses in general, and bulk metallic glasses (BMGs) in particular, is usually studied with continuously varying cooling rates; slower cooling rates lead to stiffer, harder, and more brittle…

Materials Science · Physics 2025-01-27 Achraf Atila , Sergey V. Sukhomlinov , Marc J. Honecker , Martin H. Müser

We use a mixture of a polymer and its dimer to control dynamics in a manner inspired by \emph{pinning} a fraction of the system. In our system of $\alpha$-methyl styrene, where the polymer has a glass transition at higher temperature than…

Soft Condensed Matter · Physics 2021-10-29 Genki Kikumoto , Naohiro Torii , Koji Fukao , C. Patrick Royall , Haruhiko Yao , Yasuo Saruyama , Soichi Tatsumi

Using positional data from video-microscopy of a two-dimensional colloidal system and from simulations of hard discs we determine the wave-vector-dependent normal mode spring constants in the supercooled fluid and glassy state,…

Soft Condensed Matter · Physics 2012-10-26 Christian L. Klix , Florian Ebert , Fabian Weysser , Matthias Fuchs , Georg Maret , Peter Keim

We address the crystallization of monodisperse hard spheres in terms of the properties of finite- size crystalline clusters. By means of large scale event-driven Molecular Dynamics simulations, we study systems at different packing…

Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s}…

Disordered Systems and Neural Networks · Physics 2022-11-01 Gautham Gopinath , Chun-Shing Lee , Xin-Yuan Gao , Xiao-Dong An , Chor-Hoi Chan , Cho-Tung Yip , Hai-Yao Deng , Chi-Hang Lam

The art of making structural, polymeric and metallic glasses is rapidly developing with many applications. A limitation to their use is their mechanical stability: under increasing external strain all amorphous solids respond elastically to…

Soft Condensed Matter · Physics 2015-05-19 Smarajit Karmakar , Edan Lerner , Itamar Procaccia

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

The dramatic dynamic slowing down associated with the glass transition is considered by many to be related to the existence of a static length scale that grows when temperature decreases. Defining, identifying and measuring such a length is…

Statistical Mechanics · Physics 2014-05-29 Giulio Biroli , Smarajit Karmakar , Itamar Procaccia

When the cooling rate $v$ is smaller than a certain material-dependent threshold, the glass transition temperature $T_g$ becomes to a certain degree the "material parameter" being nearly independent on the cooling rate. The common method to…

Chemical Physics · Physics 2020-11-25 N. M. Chtchelkatchev , R. E. Ryltsev , V. Ankudinov , V. N. Ryzhov , M. Apel , P. K. Galenko

Using a realistic flexible molecule model of the fragile glass former orthoterphenyl, we calculate via molecular dynamics simulation the collective dynamic structure factor, recently measured in this system by Inelastic X-ray Scattering.…

Soft Condensed Matter · Physics 2009-11-07 S. Mossa , G. Monaco , G. Ruocco , M. Sampoli , F. Sette

The recently-developed non-equilibrium extension of the self-consistent generalized Langevin equation theory of irreversible relaxation [Phys. Rev. E (2010) 82, 061503; ibid. 061504] is applied to the description of the irreversible process…

Soft Condensed Matter · Physics 2013-05-29 Luis Enrique Sanchez-Diaz , Pedro Ramirez-Gonzalez , Magdaleno Medina-Noyola

In stark contrast with the conventional understanding of the glass transition, where the transition from glass to liquid appears as a dynamic process where atoms/molecules cooperatively relax into the equilibrium phase, we experimentally…

Disordered Systems and Neural Networks · Physics 2023-01-10 Ana Vila-Costa , Marta Gonzalez-Silveira , Cristian Rodríguez-Tinoco , Marta Rodríguez-López , Javier Rodríguez-Viejo

Sizable glass formers feature numerous unique properties and potential applications, but many questions regarding their glass transition dynamics have not been resolved yet. Here we analyzed structural relaxation times measured as a…

Soft Condensed Matter · Physics 2024-03-08 Marzena Rams-Baron , Alfred Blazytko , Riccardo Casalini , Marian Paluch

Key to resolving the scientific challenge of the glass transition is to understand the origin of the massive increase in viscosity of liquids cooled below their melting temperature (avoiding crystallisation). A number of competing and often…

Soft Condensed Matter · Physics 2018-09-12 C. Patrick Royall , Francesco Turci , Soichi Tatsumi , John Russo , Joshua Robinson

We review recent results from computer simulation studies of polymer glasses, from chain dynamics around the glass transition temperature Tg to the mechanical behaviour below Tg. These results clearly show that modern computer simulations…

Materials Science · Physics 2010-09-29 Jean-Louis Barrat , Joerg Baschnagel , Alexei Lyulin

We consider the critical properties of points of continuous glass transition as one can find in liquids in presence of constraints or in liquids in porous media. Through a one loop analysis we show that the critical Replica Field Theory…

Statistical Mechanics · Physics 2015-03-20 Silvio Franz , Giorgio Parisi , Federico Ricci-Tersenghi

In this Letter, we analyze the quantum dynamics of the perceptron model: a particle is constrained on a $N$-dimensional sphere, with $N\to \infty$, and subjected to a set of randomly placed hard-wall potentials. This model has several…

Disordered Systems and Neural Networks · Physics 2021-05-05 Claudia Artiaco , Federico Balducci , Giorgio Parisi , Antonello Scardicchio
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