Diffusion coefficient power laws and defect-driven glassy dynamics in swap acceleration
Abstract
Particle swaps can drastically accelerate dynamics in glass. The mechanism is expected to be vital for a fundamental understanding of glassy dynamics. To extract defining features, we propose a partial swappability with a fraction {\phi_s} of swap-initiating particles, which can only swap locally with each other or with regular particles. We focus on the swap-dominating regime. At all temperatures studied, particle diffusion coefficients scale with {\phi_s} in unexpected power laws with temperature-dependent exponents, consistent with the kinetic picture of glass transition. At small {\phi_s}, swap-initiators, becoming defect particles, induce remarkably typical glassy dynamics of regular particles. This supports defect models of glass.
Cite
@article{arxiv.2111.11697,
title = {Diffusion coefficient power laws and defect-driven glassy dynamics in swap acceleration},
author = {Gautham Gopinath and Chun-Shing Lee and Xin-Yuan Gao and Xiao-Dong An and Chor-Hoi Chan and Cho-Tung Yip and Hai-Yao Deng and Chi-Hang Lam},
journal= {arXiv preprint arXiv:2111.11697},
year = {2022}
}
Comments
14 pages, 20 figures