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Using the recently developed N-th order muffin-tin orbital-based downfolding technique in combination with the Dynamical Mean Field theory, we investigate the electronic properties of the much discussed Mott insulator TiOCl in the…

Strongly Correlated Electrons · Physics 2009-11-10 T. Saha-Dasgupta , A. Lichtenstein , R. Valenti

We present the phonon spectrum of TiOCl computed using hybrid density functional theory (DFT). A complete analysis of the spectrum is performed for the space group Pmmn (high symmetry phase) and the space group P2_1/m (low symmetry phase),…

Strongly Correlated Electrons · Physics 2009-11-13 L. Pisani , R. Valenti , B. Montanari , N. M. Harrison

Based on a combination of cluster dynamical mean field theory (DMFT) and density functional calculations, we calculated the angle-integrated spectral density in the layered $s=1/2$ quantum magnet TiOCl. The agreement with recent…

Strongly Correlated Electrons · Physics 2009-11-11 T. Saha-Dasgupta , A. Lichtenstein , M. Hoinkis , S. Glawion , M. Sing , R. Claessen , R. Valenti

The single-particle spectral function measures the density of electronic states (DOS) in a material as a function of both momentum and energy, providing central insights into phenomena such as superconductivity and Mott insulators. While…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Joonho Jang , Heun Mo Yoo , Loren Pfeiffer , Ken West , K. W. Baldwin , Raymond Ashoori

The remarkable properties of (1T-)TiSe$_2$ among the transition metal dichalcogenides have attracted the attention of many researchers due to its peculiar behavior during the charge density wave (CDW) transition. Therefore, it is highly…

Materials Science · Physics 2024-02-08 Shin-ichiro Tanaka , Shigemasa Suga , Keiji Ueno , Keisuke Fukutani , Fumihiko Matsui

We analyze the electronic structure and level alignment of transition-metal phthalocyanine (MPc) molecules adsorbed on two-dimensional MoS$_2$ employing density functional theory (DFT) calculations. We develop a procedure for…

Materials Science · Physics 2024-06-12 Qunfei Zhou , Zhen-Fei Liu , Tobin J. Marks , Pierre Darancet

The recent advances in angle resolved photoemission techniques allowed the unambiguous experimental confirmation of spin charge decoupling in quasi one dimensional (1D) Mott insulators. This opportunity stimulates a quantitative analysis of…

Strongly Correlated Electrons · Physics 2015-05-14 Valeria Lante , Alberto Parola

The spectral weight evolution of the low-dimensional Mott insulator TiOCl upon alkali-metal dosing has been studied by photoelectron spectroscopy. We observe a spectral weight transfer between the lower Hubbard band and an additional peak…

Strongly Correlated Electrons · Physics 2015-05-13 M. Sing , S. Glawion , M. Schlachter , M. R. Scholz , K. Goss , J. Heidler , G. Berner , R. Claessen

We have studied the electronic structure of the two-dimensional Heisenberg antiferromagnet VOCl using photoemission spectroscopy and density functional theory including local Coulomb repulsion. From calculated exchange integrals and the…

Strongly Correlated Electrons · Physics 2009-10-16 S. Glawion , M. R. Scholz , Y. -Z. Zhang , R. Valenti , T. Saha-Dasgupta , M. Klemm , J. Hemberger , S. Horn , M. Sing , R. Claessen

We studied the transmittance and reflectance of the low-dimensional Mott-Hubbard insulator TiOCl in the infrared and visible frequency range as a function of pressure. The strong suppression of the transmittance and the abrupt increase of…

Strongly Correlated Electrons · Physics 2012-06-05 C. A. Kuntscher , S. Frank , A. Pashkin , M. Hoinkis , M. Klemm , M. Sing , S. Horn , R. Claessen

Electronic structure calculations on the low dimensional spin-1/2 compound TiOCl were performed at several pressures in the orthorhombic phase, finding that the structure is quasi-one-dimensional. The Ti3+ (d1) ions have one t2g orbital…

Strongly Correlated Electrons · Physics 2010-12-15 A. Piñeiro , V. Pardo , D. Baldomir , S. Blanco-Canosa , F. Rivadulla , J. E. Arias , J. Rivas

The application of pressure can induce transitions between unconventional quantum phases in correlated materials. The inorganic compound TiOCl, composed of chains of S=1/2 Ti ions, is an ideal realization of a spin-Peierls system with a…

Strongly Correlated Electrons · Physics 2018-02-21 Costel R. Rotundu , Jiajia Wen , Wei He , Yongseong Choi , Daniel Haskel , Young S. Lee

The low-energy properties of transition metal oxides (TMOs) are governed by the electrons occupying strongly correlated $d$-orbitals that are hybridized with surrounding ligand oxygen $p$ orbitals to varying degrees. Their physics is thus…

Strongly Correlated Electrons · Physics 2025-08-05 Samuel Milner , Steven Johnston , Adrian Feiguin

We analyze the dielectric-function spectra of low dimensional transition metal dichalcogenides (TMDCs) using a fully analytical model of the complex dielectric function that is applicable in fractional dimensional space. We extract the…

Materials Science · Physics 2018-12-04 A. Thilagam

In inertial confinement fusion (ICF), Thomson scattering (TS) is a widely used diagnostic technique for probing plasma conditions. We present a first-principles numerical approach to obtaining scattered light signals of ion acoustic…

We derive the statistical limit of the spectral autocorrelation function and of the survival probability for the indirect photodissociation of molecules in the regime of non-overlapping resonances. The results are derived in the framework…

chao-dyn · Physics 2016-09-28 Y. Alhassid , Yan V. Fyodorov

We present a relativistic time-dependent density functional theory (TDDFT) approach for the simulation of resonant inelastic X-ray scattering (RIXS) spectra, based on both a full four-component (4c) Dirac-Coulomb Hamiltonian and a modern…

Chemical Physics · Physics 2026-04-17 Lukas Konecny , Muhammed A. Dada , Daniel R. Nascimento , Michal Repisky

We have performed a comparative study of the electronic structures of the spin-Peierls systems TiOCl and TiOBr by means of photoemission spectroscopy and density functional calculations. While the overall electronic structure of these…

Strongly Correlated Electrons · Physics 2009-11-11 M. Hoinkis , M. Sing , S. Glawion , L. Pisani , R. Valenti , S. van Smaalen , M. Klemm , S. Horn , R. Claessen

We have studied the S=1/2 quasi-one-dimensional antiferromagnet TiOCl using single crystal x-ray diffraction and inelastic x-ray scattering techniques. The Ti ions form staggered spin chains which dimerize below Tc1 = 66 K and have an…

Strongly Correlated Electrons · Physics 2009-11-13 E. T. Abel , K. Matan , F. C. Chou , E. D. Isaacs , D. E. Moncton , H. Sinn , A. Alatas , Y. S. Lee

Spectral weight functions are easily obtained from two-point correlation functions and they might be used to distinguish single-particle from multi-particle states in a finite-volume lattice calculation, a problem crucial for many lattice…

High Energy Physics - Lattice · Physics 2014-11-21 Zhi-Yuan Niu , De-Chuan Du , Bao-Zhong Guo , Ning Li , Chuan Liu , Hang Liu
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