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We report the detection of unusual superconductivity up to 49 K in single crystalline CaFe2As2 via electron-doping by partial replacement of Ca by rare-earth. The superconducting transition observed suggests the possible existence of two…

Superconductivity · Physics 2011-10-28 B. Lv , L. Z. Deng , M. Gooch , F. Y. Wei , Y. Y. Sun , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

Single crystals of the compound LaFePO were prepared using a flux growth technique at high temperatures. Electrical resistivity measurements reveal metallic behavior and a resistive transition to the superconducting state at a critical…

Superconductivity · Physics 2008-09-10 J. J. Hamlin , R. E. Baumbach , D. A. Zocco , T. A. Sayles , M. B. Maple

Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the…

We have performed several high-pressure resistivity experiments on the recently discovered superconductors La[O_{0.89}F_{0.11}]FeAs and Ce[O_{0.88}F_{0.12}]FeAs. At ambient pressure, these materials have superconducting onset temperatures…

Co-doping of lanthanum and phosphorus in CaFe2As2 induces superconductivity at 45 K. This superconducting transition temperature is higher than the 38 K transition in Ba1-xKxFe2As2, which is the maximum found thus far among the 122 phases.…

High pressure electrical resistance and x-ray diffraction measurements have been performed on ruthenium-doped Ba(Fe0.9Ru0.1)2As2, up to pressures of 32 GPa and down to temperatures of 10 K, using designer diamond anvils under…

Superconductivity · Physics 2014-04-15 Walter Uhoya , Georgiy M. Tsoi , Yogesh K. Vohra , Athena S. Sefat , Samuel T. Weir

Single crystals of mixed alkaline earth metal iron arsenide materials of Ba1-xSrxFe2As2 and Ba0.5Sr0.5(Fe1-yCoy)2As2 are synthesized via the self-flux method. Ba1-xSrxFe2As2 display spin-density wave features (TN) at temperatures…

The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity up to Tc = 38 K in (Ba1-xKx)Fe2As2 with x =…

Superconductivity · Physics 2008-09-06 Marianne Rotter , Marcus Tegel , Dirk Johrendt

We report pressure-induced superconductivity in a single crystal of CaFe2As2. At atmospheric pressure, this material is antiferromagnetic below 170 K but under an applied pressure of 0.69 GPa becomes superconducting, with a transition…

Superconductivity · Physics 2008-07-18 Tuson Park , Eunsung Park , Hanoh Lee , T. Klimczuk , E D Bauer , F Ronning , J D Thompson

We report appearance of superconductivity at 5K in NdO0.5F0.5BiS2 and supplement the discovery [1] of the same in layered sulfide based ZrCuSiAs type compounds. The bulk polycrystalline compound is synthesized by conventional solid state…

Superconductivity · Physics 2015-06-11 Rajveer Jha , Anuj Kumar , Shiva Kumar Singh , V. P. S. Awana

A new hight Tc Fe-based compound system, AFe2As2 with A = K, Cs, K/Sr and Cs/Sr has been found. Through electron-doping, Tc of the A = K and Cs compounds rises to ~37 K, and finally enter a spin-density-wave state (SDW) through further…

Superconductivity · Physics 2008-09-09 K. Sasmal , B. Lv , B. Lorenz , A. Guloy , F. Chen , Y. Xue , C. W. Chu

We report the successful substitution of cobalt, nickel, and copper for iron in the 1038 phase parent compound Ca$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) yielding Ca$_{10}$(Fe$_{1-x}$Co$_x$As)$_{10}$(Pt$_3$As$_8$),…

Superconductivity · Physics 2014-10-29 Tobias Stürzer , Fabian Kessler , Dirk Johrendt

We report appearance of superconductivity in CeO0.5F0.5BiS2. The bulk polycrystalline samples CeOBiS2 and CeO0.5F0.5BiS2 are synthesized by conventional solid state reaction route via vacuum encapsulation technique. Detailed structural…

Superconductivity · Physics 2014-01-21 Rajveer Jha , V. P. S. Awana

The recently discovered quaternary arsenide oxide superconductor La[O1-xFx]FeAs with the superconducting critical transition temperature (Tc) of 26 K [1], has been quickly expanded to another high-Tc superconducting system beyond copper…

Superconductivity at about 15.6 K was achieved in Tb_{1-x}Ca_xFeAsO by partially substituting Tb^{3+} with Ca^{2+} in the nominal doping region x = 0.40 \sim 0.50. A detailed investigation was carried out in a typical sample with doping…

Superconductivity · Physics 2010-02-28 Gang Mu , Bin Zeng , Peng Cheng , Xiyu Zhu , Fei Han , Bing Shen , Hai-Hu Wen

We report synthesis and superconductivity at 3.7K in PrO0.5F0.5BiS2. The newly discovered material belongs to the layered sulfide based REO0.5F0.5BiS2 compounds having ZrCuSiAs type structure. The bulk polycrystalline compound is…

Superconductivity · Physics 2013-03-08 Rajveer Jha , Anuj Kumar , Shiva Kumar Singh , V. P. S. Awana

The optical properties of the iron-chalcogenide superconductor K{0.8}Fe{2-y}Se2, with a critical temperature Tc = 31 K, have been measured over a wide frequency range in the a-b planes above and below Tc. The conductivity is incoherent at…

Superconductivity · Physics 2012-05-28 C. C. Homes , Z. J. Xu , J. S. Wen , G. D. Gu

We have successfully grown single crystalline NaFeAs with cobalt or phosphor doping. Bulk superconductivity occurs in NaFe$_{0.95}$Co$_{0.05}$As at 19 K while much higher transition temperature is observed in NaFeAs$_{0.8}$P$_{0.2}$, in…

Superconductivity · Physics 2010-02-03 T. -L. Xia , J. B. He , D. M. Wang , G. F. Chen

Two correlated superconducting phases are identified in layered superconductor BaTi2(Sb1-xBix)2O (x=0.16), with the superconducting transition temperatures of TC = 6 K (the high TC phase) and 3.4 K (the low TC Phase), respectively. The 6 K…

Superconductivity · Physics 2015-06-19 Y. Wu , X. L. Dong , M. W. Ma , H. X. Yang , C. Zhang , F. Zhou , X. J. Zhou , Z. X. Zhao

The intermetallic compounds AAl2-xSix, where A = Ca, Sr or Ba, crystallize in the C32 structure, same as the recently discovered MgB2 with a high superconducting transition temperature of 39 K. For x = 1, superconductivity has been observed…

Superconductivity · Physics 2009-11-07 B. Lorenz , J. Lenzi , J. Cmaidalka , R. L. Meng , Y. Y. Sun , Y. Y. Xue , C. W. Chu