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Energy transfer from photoexcited zero-dimensional systems to metallic systems plays a prominent role in modern day materials science. A situation of particular interest concerns the interaction between a photoexcited dipole and an…

Chemical Physics · Physics 2013-04-30 Zheyuan Chen , Stéphane Berciaud , Colin Nuckolls , Tony F. Heinz , Louis E. Brus

Enhanced Raman scattering can be obtained by injecting a seeded light field which is correlated with the initially prepared collective atomic excitation. This Raman amplification process can be used to realize atom-light hybrid…

Quantum Physics · Physics 2016-08-24 Zhao-Dan Chen , Chun-Hua Yuan , Hong-Mei Ma , Dong Li , L. Q. Chen , Z. Y. Ou , Weiping Zhang

The effects of visible and infrared light on potassium atoms embedded in a nanoporous glass matrix are investigated. Photodesorption by visible light enhances the atomic mobility and causes the formation of metallic nanoparticles. Two…

In colloid and nanoparticle chemistry, particle size, shape, crystallinity, surface morphology and composition are controlled by employing the mechanisms of burst nucleation, diffusional growth, aggregation, or their combinations. Here we…

Materials Science · Physics 2013-05-01 I. Sevonkaev , V. Privman , D. Goia

We propose a method for increasing the Raman scattering from an ensemble of molecules by up to four orders of magnitude. Our method requires an additional coherent source of IR radiation with the half-frequency of the Stokes shift. This…

Quantum Physics · Physics 2019-04-24 V. Yu. Shishkov , E. S. Andrianov , A. A. Pukhov , A. P. Vinogradov , A. A. Lisyansky

In crystalline nanoparticles the Raman peak is downshifted with respect to the bulk material and has asymmetric broadening. These effects are straightly related to the finite size of nanoparticles, giving the perspective to use the Raman…

Mesoscale and Nanoscale Physics · Physics 2018-09-05 S. V. Koniakhin , O. I. Utesov , I. N. Terterov , A. V. Siklitskaya , D. Solnyshkov , A. G. Yashenkin

The thermodynamics and kinetics of crystallization of nanoparticles, as opposed to bulk phases, may be influenced by surface and size effects. We investigate the importance of such factors in the crystallization process of gold, silver, and…

Statistical Mechanics · Physics 2024-07-09 Arthur France-Lanord , Sarath Menon , Julien Lam

The polarization behavior of metallic nano-rods has been analyzed by means of the finite-difference-time-domain method. When the average spacing between the nano-rods is less than a half wavelength, the layer reflects the light polarized…

Optics · Physics 2013-06-25 Young-Gu Ju

The acoustic vibrations of single monomers and dimers of gold nanoparticles were investigated by measuring for the first time their ultra-low frequency micro-Raman scattering. This experiment provides access not only to the frequency of the…

Low voltage transmission electron microscopy (<=80 kV) has many applications in imaging beam-sensitive samples, such as metallic nanoparticles, which may become damaged at higher voltages. To improve resolution, spherical aberration can be…

Instrumentation and Detectors · Physics 2022-07-27 Frances Quigley , Patrick McBean , Peter O'Donovan , Jonathan J. P. Peters , Lewys Jones

Light absorption and scattering of plasmonic metal nanoparticles can lead to non-equilibrium charge carriers, intense electromagnetic near-fields, and heat generation, with promising applications in a vast range of fields, from chemical and…

Optics · Physics 2020-08-27 Guillaume Baffou , Ivan Bordacchini , Andrea Baldi , Romain Quidant

Controlled integration of metallic nanoparticles (NPs) onto photonic nanostructures enables realization of complex devices for extreme light confinement and enhanced light-matter interaction. This can be achieved combining…

We develop a theory to model the interaction of graphene substrate with localized plasmon resonances in metallic nanoparticles. The influence of a graphene substrate on the surface plasmon resonances is described using an effective…

In our recent paper [Phys. Rev. B 65, 075316 (2002)], the selection rules for the Raman scattering in spherical nanocrystals are analyzed. Here we show, that a physically expedient choice of the coordinate system, related to the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 E. P. Pokatilov , S. N. Klimin , V. M. Fomin , J. T. Devreese , F. W. Wise

We study the effect of the electromagnetic environment on the resonance frequency of plasmonic excitations in dimers of interacting metallic nanoparticles. The coupling between plasmons and vacuum electromagnetic fluctuations induces a…

Mesoscale and Nanoscale Physics · Physics 2017-10-11 Charles A. Downing , Eros Mariani , Guillaume Weick

Electronic excitations in metallic nanoparticles in the optical regime that have been of great importance in surface enhanced spectroscopy and emerging applications of molecular plasmonics, due to control and confinement of electromagnetic…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Marouane Salhi , Ali Passian , George Siopsis

The Raman effect -- inelastic scattering of light by lattice vibrations (phonons) -- produces an optical response closely tied to a material's crystal structure. Here we show that resonant optical excitation of IR and Raman phonons gives…

Materials Science · Physics 2021-07-07 Guru Khalsa , Nicole A. Benedek , Jeffrey Moses

We devise new optical antennas that reduce the excited-state radiative lifetimes of emitters to the order of 100 femtoseconds while maintaining quantum efficiencies of about 80% at a broadband operation. Here, we combine metallic…

Optics · Physics 2015-06-05 Xue-Wen Chen , Mario Agio , Vahid Sandoghdar

In this paper, matters considering the immersion of gold nanoparticles inside a magnetic medium are investigated experimentally and theoretically. Three samples with periodic arrays of Au cylinders where studied: particles on a surface of…

Diamond nanoparticles (nanodiamonds) have been recently proposed as new labels for cellular imaging. For small nanodiamonds (size <40 nm) resonant laser scattering and Raman scattering cross-sections are too small to allow single…