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We develop a microscopic model for fluorescence of a molecule (or semiconductor quantum dot) near a small metal nanoparticle. When a molecule is situated close to metal surface, its fluorescence is quenched due to energy transfer to the…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Vitaliy N. Pustovit , Tigran V. Shahbazyan

It was predicted long ago that ultra-thin metallic films must exhibit unusual optical properties for radiation frequencies from rf to infrared domain. A film would remain highly reflective even when it is orders of magnitude thinner than a…

Optics · Physics 2018-06-19 Alexander E. Kaplan

The influence of morphology on the optical properties of silver nanoparticles is studied. A general relationship between the surface plasmon resonances and the morphology of each nanoparticle is established. The optical response is…

Chemical Physics · Physics 2007-05-23 A. L. Gonzalez , C. Noguez

We study the modification of the far-field cross sections and the near-field enhancement for gold and silver nanospheres illuminated by a tightly focused beam. Using a multipole-expansion approach we obtain an analytical solution to the…

Optics · Physics 2008-04-02 Nassiredin M. Mojarad , Vahid Sandoghdar , Mario Agio

We predict the simultaneous occurrence of two fundamental phenomena for metal nanoparticles possessing sharp corners: First, the main plasmonic dipolar mode experiences strong red shift with decreasing corner curvature radius; its resonant…

Optics · Physics 2015-06-05 B. Sturman , E. Podivilov , M. Gorkunov

The combined effect of electron-electron interactions and spin-orbit scattering in metal nanoparticles can be studied by measuring splitting of electron levels in magnetic field ($g$ factors) in tunneling spectroscopy experiments. Using…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Denis A. Gorokhov , Piet W. Brouwer

Metallic nanoparticles were shown to affect F\"orster energy transfer between fluorophore pairs. However, to date, the net plasmonic effect on FRET is still under dispute, with experiments showing efficiency enhancement and reduction. This…

The optical response of materials based on gold nanoparticle assemblies depends on many parameters regarding both material morphology and light excitation characteristics. In this paper, the interplay between the optical and thermal…

Raman spectroscopy is a powerful technique to characterize materials. It probes non-destructively chemical composition, crystallinity, defects, strain and coupling phenomena. However, the Raman response of surfaces or thin films is often…

Noble metal nanoparticles show specific optical properties due to the excitation of localized surface plasmons that make them attractive candidates for highly sensitive bionanosensors. The underlying physical principle is either an…

We demonstrate experimentally and support by a theoretical analysis an effect of asymmetric spectrum broadening, which results from doping of silver nanoparticles into a heavy-glass matrix, 90(0.5WO3-0.3SbPO4-0.2PbO)-10AgCl. The strong…

Optics · Physics 2015-05-27 N. Zhavoronkov , R. Driben , B. A. Bregadiolli , M. Nalin , B. A. Malomed

Raman scattering experiments from silver nanocrystals embedded in films of amorphous silica are reported. In addition to the low-frequency peak due to vibrational quadrupolar modes, a broadband is observed in the high-frequency range, with…

Condensed Matter · Physics 2007-05-23 H. Portales , E. Duval , L. Saviot , M. Fujii , M. Sumitomo , S. Hayashi

A method is proposed for determining the temperature of hot electrons in a metallic nanoparticle embedded in a dielectric matrix under ultrashort laser pulses irradiation. The amplitude and power of the longitudinal spherical acoustic…

Mesoscale and Nanoscale Physics · Physics 2017-12-15 N. I. Grigorchuk

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

Interaction between plasmonic nanostructures and molecules is modeled based on the concept of quantized optical cavity for surface enhanced Raman scattering process. We have found that the background emission from plasmonic nanostructures…

Optics · Physics 2017-03-22 Yuqing Cheng , Jingyi Zhao , Te Wen , Guantao Li , Jianning Xu , Qihuang Gong , Guowei Lu

The combination of nanodiamonds with plasmonic metal particles is being explored for synergic effects that can enhance biosensing and antibacterial treatments, energy harvesting, photocatalysis, and quantum centres. Here we systematically…

Photoluminescence is a phenomenon of significant interest due to its wide range of technological applications in plasmonics, nanolasers, spasers, lasing spasers, loss compensation and gain in metamaterials, and luminescent media.…

Optics · Physics 2016-06-14 Tapashree Roy , Edward T. F. Rogers , Nikolay I. Zheludev

The ability to modulate light at high speeds is of paramount importance for telecommunications, information processing, and medical imaging technologies. This has stimulated intense efforts to master optoelectronic switching at visible and…

Mesoscale and Nanoscale Physics · Physics 2014-04-01 A. Manjavacas , F. J. Garcia de Abajo

We aim to clarify the role that absorption plays in nonlinear optical processes in a variety of metallic nanostructures and show how it relates to emission and conversion efficiency. We define a figure of merit that establishes the…

We investigate an array of metal nanoparticles as a channel for nanophotonic quantum communication and the generation of quantum plasmonic interference. We consider the transfer of quantum states, including single-qubits as plasmonic…

Quantum Physics · Physics 2013-12-25 Changhyoup Lee , Mark Tame , James Lim , Jinhyoung Lee