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We theoretically investigate the interaction between a single molecule and a metallic nanoparticle. We develop a general quantum mechanical description for the calculation of the enhancement of radiative and non-radiative decay channels for…

Mesoscale and Nanoscale Physics · Physics 2008-01-28 Ulrich Hohenester , Andreas Truegler

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We investigate plasmon resonances in gold nanoparticles to enhance the quantum yield of upconverting materials. For this purpose, we use a rate equation model that describes the upconversion of trivalent erbium based upconverters. Changes…

Enhancement of optical response with high-index dielectric nanoparticles is attributed to the excitation of their Mie-type magnetic and electric resonances. Here we study Raman scattering from crystalline silicon nanoparticles and reveal…

In this work we study the strong confinement effects on the electromagnetic response of metallic nanoparticles. We calculate the field enhancement factor for nanospheres of various radii by using optical constants obtained from both…

Mesoscale and Nanoscale Physics · Physics 2018-02-20 Mario Zapata-Herrera , Jefferson Flórez , Angela Camacho , Hanz Y. Ramirez

We present a general model study of surface-enhanced resonant Raman scattering and fluorescence, focusing on the interplay between electromagnetic (EM) effects and the molecular dynamics as treated by a density matrix calculation. The model…

Other Condensed Matter · Physics 2007-05-23 Peter Johansson , Hongxing Xu , Mikael Käll , ;

The relations for the polarizability of the metallic nanoparticles, coated with the shell of cyanine dyes, are obtained in the article. The frequency dependencies for light absorption and scattering efficiencies, the heating of the…

Soft Condensed Matter · Physics 2024-01-18 A. V. Korotun , N. A. Smirnova , V. I. Reva , I. M. Titov , G. M. Shilo

We report on the increased extraction of light emitted by solid-state sources embedded within high refractive index materials. This is achieved by making use of a local lensing effect by sub-micron metallic rings deposited on the sample…

Optics · Physics 2017-07-27 Oliver J. Trojak , Suk In Park , Jin Dong Song , Luca Sapienza

Gold nanoparticles emit broad-band upconverted luminescence upon irradiation with pulsed infrared laser radiation. Although the phenomenon is widely observed, considerable disagreement still exists concerning the underlying physics - most…

Materials Science · Physics 2018-02-14 Lukas Roloff , Philippe Klemm , Imke Gronwald , Rupert Huber , John M. Lupton , Sebastian Bange

We report modifications to the optical properties of fluorophores in the vicinity of noble metal nanotips. The fluorescence from small clusters of quantum dots has been imaged using an apertureless scanning near-field optical microscope.…

Other Condensed Matter · Physics 2008-04-28 N. I. Cade , F. Culfaz , L. Eligal , T. Ritman-Meer , F-M. Huang , F. Festy , D. Richards

Conjugated metallic nanoparticles are a promising means to achieve ultrasensitive and multiplexed sensing in intact three-dimensional samples, especially for biological applications, via surface enhanced Raman scattering (SERS). We show…

Transient absorption and Raman scattering measurements on noble metal nanoparticles offer complimentary information on their vibrational modes and mechanical interactions with their surroundings. We have developed a comprehensive modeling…

Mesoscale and Nanoscale Physics · Physics 2024-10-29 Rachel Gelfand , Matthew Pelton

We revisit the electromagnetic heat transfer between a metallic nanoparticle and a metallic semi-infinite substrate, commonly studied using the electric dipole approximation. For infrared and microwave frequencies, we find that the magnetic…

Other Condensed Matter · Physics 2008-06-10 Pierre-Olivier Chapuis , Marine Laroche , Sebastian Volz , Jean-Jacques Greffet

We study Raman scattering in active media placed in proximity of different types of metal nanostructures, at wavelengths that display either Fabry-Perot or plasmonic resonances, or a combination of both. We use a semi-classical approach to…

Optics · Physics 2015-06-05 M. Scalora , M. A. Vincenti , D. de Ceglia , M. Grande , J. W. Haus

We describe the process of Foerster transfer between semiconductor nanoparticles in the presence of a metal subsystem (metal nanocrystals). In the presence of metal nanocrystals, the Foerster process can become faster and more long-range.…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Alexander O. Govorov , Jaebeom Lee , Nicholas A. Kotov

We present a general model study of surface-enhanced resonant Raman scattering and fluorescence focusing on the interplay between electromagnetic effects and the molecular dynamics. Our model molecule is placed close to two Ag…

Other Condensed Matter · Physics 2007-05-23 Hongxing Xu , Xue-Hua Wang , Martin P. Persson , H. Q. Xu , Mikael Kall , Peter Johansson

Metals are highly opaque, yet we show that densely packed arrays of metallic nanoparticles can be more transparent to infrared radiation than dielectrics such as germanium, even for arrays that are over 75% metal by volume. Despite strong…

Metal nanoparticles are excellent light absorbers. The absorption processes create highly excited electron-hole pairs and recently there has been interest in harnessing these hot charge carriers for photocatalysis and solar energy…

Mesoscale and Nanoscale Physics · Physics 2017-06-13 Gregory V. Hartland , Lucas V. Besteiro , Paul Johns , Alexander O. Govorov

Theoretically, the presence of a metallic nanoparticle enhances the intermolecular energy transfer. We calculate this enhancement factor with a modal approach pertaining analytical results in the case of a nanosphere. We calculate the…

Mesoscale and Nanoscale Physics · Physics 2019-07-02 Titus Sandu , Catalin Tibeica , Oana Nedelcu , Mihai Gologanu

Scattering from metal nanoparticles near their localized plasmon resonance; especially, the resonances of noble metals which are mostly in the visible or infrared part of the electromagnetic spectrum; is a way of improving light absorption…

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