Related papers: Electric dipole rovibrational transitions in HD mo…
We present an accurate theoretical determination of rovibrational energy levels of the hydrogen molecule and its isotopologues in its electronic ground state. We consider all significant corrections to the Born-Oppenheimer approximation,…
We present a unified variational treatment of the electric quadrupole (E2) matrix elements, Einstein coefficients, and line strengths for general open-shell diatomic molecules in the general purpose diatomic code \Duo. Transformation…
The electric dipole moment of the hydrogen-like atom induced by a monopole moving outside the electron shell is calculated. The correction to the energy of the ground state of the hydrogen atom due to this interaction is calculated.
The dynamics of the reaction H + OH $\to$ O (3P) + H2 have been studied in a series of quasi-classical trajectory (QCT) calculations and transition state theory (TST) methods using high quality 3A' and 3A'' potential energy surfaces (PESs).…
Accurate photodissociation cross sections have been obtained for the A-X electronic transition of HeH+ using ab initio potential curves and dipole transition moments. Partial cross sections have been evaluated for all rotational transitions…
Resonant energy transfer (RET), between equal parity 1s65s$^3\mathrm{S}_1$ and 1s66s$^3\mathrm{S}_1$ Rydberg levels in helium has been observed in low-temperature ($\sim80$ mK) collisions with ammonia molecules which undergo inversion…
Current situation in studies of mean lifetimes of excited electronic-vibro-rotational states of hydrogen molecule (including the H2, D2, HD and T2 isotopomers) is reviewed in brief. All measured values of the lifetimes (published before…
We study energy levels of two heteronuclear molecules moving in a spherically symmetric harmonic trap. A role of electric dipole interactions is compared and contrasted with our earlier results (https://arxiv.org/abs/1512.00631) for two…
Theoretical studies are presented how the electric dipole moment (EDM) of the electron in H-like ions in electrostatic storage rings can sensitively be determined. With the proposed experiments a new constraint of about $10^{-29}$ e cm for…
A general variational approach for computing the rovibrational dynamics of polyatomic molecules in the presence of external electric fields is presented. Highly accurate, full-dimensional variational calculations provide a basis of…
This paper is aimed at presenting a simple vibronic model for describing the dipolar reorientation in crystals by means of reaction rate theory. The Hamiltonian of an isolated dipole is simplified so as to render the problem solvable.…
It is observed that low-lying transitions of an interstitial hydrogen adatom on a metallic lattice correspond classically to dipoles oscillating at frequencies where band electrons typically have a low electromagnetic absorption. Such…
In hot plasmas, a temperature of a few tens of eV is sufficient for producing highly stripped ions where multipole transitions become important. At low density, the transitions from tightly bound inner shells lead to electric-quadrupole…
We investigate interactions between the proton spin, the deuteron spin, and the orbital angular momentum in the electronic ground state of the HD molecule. These interactions lead to hyperfine splittings of molecular energy levels. Our…
The spectra (rotational, rotation-vibrational or electronic) of diatomic molecules due to transitions involving only closed-shell ($^1\Sigma$) electronic states follow very regular, simple patterns and their theoretical analysis is usually…
The energy interval between the ground and the P-wave excited states of the recently discovered positronium molecule Ps_2 is evaluated, including the relativistic and the leading logarithmic radiative corrections, E_P-E_S = 0.181 586 7(8)…
Electric quadrupole strength functions have been deduced from averages of a large number of $E2$ transition strengths calculated within the shell model for the nuclides $^{94}$Mo and $^{95}$Mo. These strength functions are at variance with…
The electric dipole moments (EDMs) of neutron-odd nuclei with even protons are systematically evaluated. We first derive the relation between the EDM and the magnetic moment operators by making use of the core polarization scheme. This…
We have completed measurements of two low-lying excited-state electric-dipole (E1) transition amplitudes in lead. Our measured reduced matrix elements of the $(6s^2 6p^2)^3P_1 \to (6s^2 6p7s)^3P_0$ transition at 368.3 nm and the 405.8 nm…
Electric dipole moment (EDM) experiments are at the fore-front of search for physics beyond the standard model. The next generation searches promise to improve by several orders of magnitude the current EDM sensitivity levels.