Related papers: Electric dipole rovibrational transitions in HD mo…
We propose a systematic, model-independent treatment of electric dipole transitions of heavy quarkonium. Within an effective field theory, concretely potential non-relativistic QCD, the relativistic corrections of relative order $v^2$ to…
Permanent dipole moments of electronics states in non-centro-symmetric materials play pivotal role in many phenomena. Correctly evaluating them presents an arduous task and usually requires full knowledge of the band structure as well as…
We propose a novel approach to calculate dynamical processes at ultrafast time scale in molecules in which vibrational and electronic motions are strongly mixed. The relevant electronic orbitals and their interactions are described by a…
The resonant transfer of energy from the inversion sublevels in NH$_3$ to He atoms in triplet Rydberg states with principal quantum number $n=38$ has been controlled using electric fields below 15 V/cm in intrabeam collisions at…
Rate coefficients for dissociative recombination and state-to-state rotational transitions of the D$_{2}^{+}$ ion induced by collisions with very low-energy electrons have been reported following our previous studies on HD$^{+}$ and…
Variational calculations of excited electronic states are carried out by finding saddle points on the surface that describes how the energy of the system varies as a function of the electronic degrees of freedom. This approach has several…
Energies of np (n=6-9), ns (n=7-9), nd (n=6-8), and nf (n=5-6) states in Tl I and Pb II are obtained using relativistic many-body perturbation theory. Reduced matrix elements, oscillator strengths, transition rates, and lifetimes are…
We study the effect of a strong static homogeneous electric field on the highly excited rovibrational levels of the LiCs dimer in its electronic ground state. Our full rovibrational investigation of the system includes the interaction with…
We compute the radiative ro-vibrational emission spectrum of H2 involving quasibound states via a simple numerical method of resolution of the Schr\"odinger equation by introducing a modifed effective molecular potential. The comparison of…
Obtaining ultracold samples of dipolar molecules is a current challenge which requires an accurate knowledge of their electronic properties to guide the ongoing experiments. Alkali hydride molecules have permanent dipole significantly…
Relativistic formulas for the electric quadrupole moment of a hydrogenlike atom, induced by the hyperfine interaction, are derived for $ns_{1/2}$ and $np_{1/2}$ states. Both the magnetic dipole and electric quadrupole hyperfine interactions…
Accurate experimental values for the vibrational ground tone or fundamental vibrational energy splitting of H$_2$, HD, and D$_2$ are presented. Absolute accuracies of $2\times10^{-4}$ cm$^{-1}$ are obtained from Doppler-free laser…
Recently we reported a high precision optical frequency measurement of the (v,L):(0,2)->(8,3) vibrational overtone transition in trapped deuterated molecular hydrogen (HD+) ions at 10 mK temperature. Achieving a resolution of 0.85…
The calculation of the hindered roton-phonon energy levels of a hydrogen molecule in a confining potential with different symmetries is systematized for the case when the rotational angular momentum $J$ is a good quantum number. One goal of…
Transition intensities for small molecules such as water and CO$_2$ can now be computed with such high accuracy that they are being used to systematically replace measurements in standard databases. These calculations use high accuracy ab…
A dressed-state perturbation theory beyond the rotating waveapproxi-mation (RWA) is presented to investigate the interaction between a two level electronic transition of the polar molecules and a quantized cavity field. Analytical…
We consider the 1-D motion of an electron under a periodic force and taking into account the effect of radiation reaction dissipation force on its motion, using the formulation of the radiation reaction force as a function of the external…
The current constraint on the electron electric dipole moment ($e$EDM), $|d_e|<4.1\times 10^{-30}$ ${e {\cdotp} {\rm cm}}$ (90\% confidence), was recently established using the trapped $^{180}$Hf$^{19}$F$^+$ molecular ions in the $J=1$…
Recent advances in the high sensitivity spectroscopy have made it possible, in combination with accurate theoretical predictions, to observe for the first time very weak electric quadrupole transitions in a polar polyatomic molecule of…
We studied the hadronic decays of excited states of heavy mesons (D, D_s, B and B_s) to lighter states by emission of pi, eta or K. Wavefunctions and energy levels of these excited states are determined using a Dirac equation for the light…