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The band offsets between crystalline and hydrogenated amorphous silicon (a-Si:H) are key parameters governing the charge transport in modern silicon hetrojunction solar cells. They are an important input for macroscopic simulators that are…

Materials Science · Physics 2017-08-02 K. Jarolimek , E. Hazrati , R. A. de Groot , G. A. de Wijs

The band offsets and the chemical bonding at the interfaces between (-201) $\beta$-Ga$_2$O$_3$ and Al$_2$O$_3$ polymorphs are studied through hybrid functional calculations. For alumina, we consider four representative phases, i.e.,…

Materials Science · Physics 2022-09-15 Sai Lyu

We demonstrate the accuracy of the hybrid functional HSE06 for computing band offsets of semiconductor alloy heterostructures. The highlight of this study is the computation of conduction band offsets with a reliability that has eluded…

Materials Science · Physics 2015-05-19 Amita Wadehra , Jeremy W. Nicklas , John W. Wilkins

Ultrawide bandgap semiconductor gallium oxide (Ga2O3) and its polymorphs have recently attracted increasing attention across physics, materials science, and electronics communities. In particular, the self-organized formation of the…

We determined the interface state density ($D_{\rm it}$) distributions in the vicinity of the conduction band edge in silicon carbide (SiC) metal-oxide-semiconductor (MOS) structures by reproducing the experimental current-voltage…

Materials Science · Physics 2020-09-07 Koji Ito , Takuma Kobayashi , Tsunenobu Kimoto

Quasiparticle calculations are performed to investigate the electronic band structures of various polymorphs of Hf and Zr oxides. The corrections with respect to density-functional-theory results are found to depend only weakly on the…

Materials Science · Physics 2015-05-14 Myrta Grüning , Riad Shaltaf , Gian-Marco Rignanese

We report first-principles density-functional pseudopotential calculations on the atomic structures, electronic properties, and band offsets of BaO/BaTiO$_3$ and SrO/SrTiO$_3$ nanosized heterojunctions grown on top of a silicon substrate.…

Materials Science · Physics 2009-11-07 Javier Junquera , Magali Zimmer , Pablo Ordejon , Philippe Ghosez

The synthesis of transition metal heterostructures is currently one of the most vivid fields in the design of novel functional materials. In this paper we propose a simple scheme to predict \emph{band alignment }and \emph{charge transfer}…

Materials Science · Physics 2017-03-07 Zhicheng Zhong , Philipp Hansmann

We use many-body perturbation theory, the state-of-the-art method for band gap calculations, to compute the band offsets at the Si/SiO$_2$ interface. We examine the adequacy of the usual approximations in this context. We show that (i) the…

Materials Science · Physics 2009-01-06 R. Shaltaf , G. -M. Rignanese , X. Gonze , Feliciano Giustino , Alfredo Pasquarello

Recent theoretical work has provided evidence that hybrid functionals, which include a fraction of exact (Hartree Fock) exchange in the density functional theory (DFT) exchange and correlation terms, significantly improve the description of…

Materials Science · Physics 2015-05-13 Xifan Wu , Eric J. Walter , Andrew M. Rappe , Roberto Car , Annabella Selloni

Despite the large number of theoretical III-V semiconductor studies reported every year, our atomistic understanding is still limited. The limitations of the theoretical approaches to yield accurate structural and electronic properties on…

Accurate band offsets are essential for predictive continuum modeling of nanostructures such as quantum wells and quantum dots formed in strained Si/Si1-xGex and Ge/Si1-xGex heterostructures. Experimental offset data for these systems…

Mesoscale and Nanoscale Physics · Physics 2026-03-16 Nathaniel M. Vegh , Pericles Philippopoulos , Raphaël J. Prentki , Wanting Zhang , Yu Zhu , Félix Beaudoin , Hong Guo

(Screened) hybrid functionals are being used more and more for solid-state calculations. Usually the fraction alpha of Hartree-Fock exchange is kept fixed during the calculation, however there is no single (universal) value for alpha which…

Materials Science · Physics 2013-10-17 David Koller , Peter Blaha , Fabien Tran

The epitaxial growth of crystalline oxides on semiconductors provides a pathway to introduce new functionalities to semiconductor devices. Key to electrically coupling crystalline oxides with semiconductors to realize functional behavior is…

Materials Science · Physics 2014-10-28 J. Moghadam , K. Ahmadi-Majlan , X. Shen , T. Droubay , M. Bowden , M. Chrysler , D. Su , S. A. Chambers , J. H. Ngai

The band alignment of semiconductor-metal interfaces plays a vital role in modern electronics, but remains difficult to predict theoretically and measure experimentally. For interfaces with strong band bending a main difficulty originates…

Utilizing three-terminal tunnel emission of ballistic electrons and holes, we have developed a method to self-consistently measure the bandgap of semiconductors and band discontinuities at semiconductor heterojunctions without any…

Mesoscale and Nanoscale Physics · Physics 2009-09-15 Wei Yi , Hong Lu , Yong Huang , Michael A. Scarpulla , Jae-Hyun Ryou , Arthur C. Gossard , Russell D. Dupuis , Venkatesh Narayanamurti

The electrical performance of a tunnel field-effect transistor depends critically on the band offset at their semiconductor heterojunction interface. Historically, it has been difficult to experimentally determine how the electronic bands…

Hybrid superconductor-semiconductor devices are currently one of the most promising platforms for realizing Majorana zero modes. Their topological properties are controlled by the band alignment of the two materials, as well as the…

Mesoscale and Nanoscale Physics · Physics 2018-08-29 August E. G. Mikkelsen , Panagiotis Kotetes , Peter Krogstrup , Karsten Flensberg

The GaAs/GaAsN interface band offset is calculated from first principles. The electrostatic potential at the core regions of the atoms is used to estimate the interface potential and align the band structures obtained from respective bulk…

Materials Science · Physics 2008-06-27 Hannu-Pekka Komsa , Eero Arola , Eric Larkins , Tapio T. Rantala

Bismuth oxyselenide (Bi$_2$O$_2$Se), a novel quasi-2D charge-carrying semiconductor, is hailed as one of the best emerging platforms for the next generation semiconductor devices. Recent efforts on developing diverse Bi$_2$O$_2$Se…

Materials Science · Physics 2024-08-07 Ke Zhang , Yusen Feng , Lei Hao , Jing Mi , Miao Du , Minghui Xu , Yan Zhao , Jianping Meng , Liang Qiao
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