Related papers: Water, O2 and Ice in Molecular Clouds
A broad array of interstellar absorption features that appear in the ultraviolet spectra of bright sources allows us to measure the abundances and ionization states of many important heavy elements that exist as free atoms in the…
H$_{\rm I}$ 21-cm and $^{12}$CO 2.6-mm line emissions respectively trace the atomic and molecular gas phases, but they miss most of the opaque H$_{\rm I}$ and diffuse H$_2$ present in the Dark Neutral Medium (DNM) at the transition between…
The relative desorption energies of CO and N$_2$ are key to interpretations of observed interstellar CO and N$_2$ abundance patterns, including the well-documented CO and N$_2$H$^+$ anti-correlations in disks, protostars and molecular cloud…
We present a theoretical investigation of CN and HCN molecule formation in dense interstellar clouds. We study the gas-phase CN and HCN production efficiencies from the outer photon-dominated regions (PDRs) into the opaque cosmic-ray…
The cosmic-ray ionization rate (CRIR, $\zeta_2$) is one of the key parameters controlling the formation and destruction of various molecules in molecular clouds. However, the current most commonly used CRIR tracers, such as H$_3^+$, OH$^+$,…
ABRIDGED: Context: HI and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds. However, until recently, we have not had spectrally resolved C+ surveys to…
The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the…
We re-examine the constraints provided by Herschel Space Observatory data regarding cold water emission from protoplanetary disks. Previous disk models that were used to interpret observed water emission concluded that oxygen (O/H) is…
To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…
Measurements of molecular hydrogen (H_2) column densities are presented for the first six rotational levels (J=0 to 5) for 73 extragalactic targets observed with FUSE. All of these have a final signal-to-noise ratio larger than \snlimit,…
We have developed the first gas-grain chemical model for oxygen fractionation (also including sulphur fractionation) in dense molecular clouds, demonstrating that gas-phase chemistry generates variable oxygen fractionation levels, with a…
The current Venus climate is largely regulated by globally-covered concentrated sulfuric acid clouds from binary condensation of sulfuric acid (H2SO4) and water (H2O). To understand this complicated H2SO4-H2O gas-cloud system, previous…
The Orion Bar is the archetypal edge-on molecular cloud surface illuminated by strong ultraviolet radiation from nearby massive stars. Owing to the close distance to Orion (about 1,350 light-year), the effects of stellar feedback on the…
We present models for the chemistry in gas moving towards the ionization front of an HII region. When it is far from the ionization front, the gas is highly depleted of elements more massive than helium. However, as it approaches the…
Context: The abundance of key molecules determines the level of cooling that is necessary for the formation of stars and planetary systems. In this context, one needs to understand the details of the time dependent oxygen chemistry, leading…
We present a study of the cold atomic hydrogen (HI) content of molecular clouds simulated within the SILCC-Zoom project. We produce synthetic observations of HI at 21 cm including HI self-absorption (HISA) and observational effects. We find…
Context. The earliest phases of high-mass star formation are poorly understood. Aims. Our goal is to determine the physical conditions and kinematic structure of massive star-forming cloud clumps. Methods. We analyze H$_2$O 557 GHz line…
Molecular clouds, which harbor the birthplaces of stars, form out of the atomic phase of the interstellar medium (ISM). We aim to characterize the atomic and molecular phases of the ISM and set their physical properties into the context of…
(Abridged) Aims & Methods. A two-dimensional, semi-analytical model is presented that follows, for the first time, the chemical evolution from a collapsing molecular cloud (a pre-stellar core) to a protostar and circumstellar disk. The…
We present a study of the three-dimensional structure of the molecular clouds in the Galactic Centre (GC) using CO emission and OH absorption lines. Two CO isotopologue lines, $^{12}$CO ($J$=1$\rightarrow$0) and $^{13}$CO…