Related papers: Water, O2 and Ice in Molecular Clouds
New 3.3--3.6~$\mu$m spectra were obtained of nine young stellar objects embedded in molecular clouds. An absorption feature at $\sim$3.47~$\mu$m (2880~cm$^{-1}$) with FWHM$\sim$0.09 $\mu$m (80 cm$^{-1}$), first identified by Allamandola et…
Elemental abundances, which are often depleted with respect to the solar values, are important input parameters for kinetic models of interstellar chemistry. In particular, the amount of carbon relative to oxygen is known to have a strong…
(Abridged). In this paper, we present results from a large set of numerical simulations that demonstrate that H2 formation occurs rapidly in turbulent gas. Starting with purely atomic hydrogen, large quantities of molecular hydrogen can be…
We report results from a FUSE survey of interstellar molecular hydrogen (H2) in the Galactic disk toward 139 O-type and early B-type stars at Galactic latitudes $|b| < 10^{\circ}$, with updated photometric and parallax distances. The H2…
Oxygen is the third most abundant element in the universe, but its chemistry in the interstellar medium is still not well understood. In order to critically examine the entire oxygen budget, we attempt here initially to estimate the…
We have investigated the water abundance in shock-heated molecular gas, making use of $Herschel$ measurements of far-infrared CO and H$_2$O line emissions in combination with $Spitzer$ measurements of mid-IR H$_2$ rotational emissions. We…
Hundreds of high-velocity atomic gas clouds exist above and below the Galactic Centre, with some containing a molecular component. However, the origin of these clouds in the Milky Way's wind is unclear. This paper presents new…
The chemistry of H2O, CO and other small molecular species in an isolated pre-stellar core, L1544, has been assessed in the context of a comprehensive gas-grain chemical model, coupled to an empirically constrained physical/dynamical model.…
(Abridged) The observed presence of pure CO2 ice in protostellar envelopes is attributed to thermally induced ice segregation, but a lack of quantitative experimental data has prevented its use as a temperature probe. Quantitative…
We examine the triggering process of molecular cloud formation around diffuse HII regions. We calculate the time evolution of the shell as well as of the HII region in a two-phase neutral medium, solving the UV and FUV radiative transfer,…
Transmission spectroscopy of exoplanets has the potential to provide precise measurements of atmospheric chemical abundances, in particular of hot Jupiters whose large sizes and high temperatures make them conducive to such observations. To…
We have observed several cloud cores in the Orion B (L1630) molecular cloud in the 2-1 transitions of C18O, C17O and 13C18O. We use these data to show that a model where the cores consist of very optically thick C18O clumps cannot explain…
We present a comprehensive study of the rho Ophiuchi molecular cloud that addresses aspects of the physical structure and condition of the molecular cloud and its photodissociation region (PDR) by combining far-infrared and…
Apart from being an important coolant, H2O is known to be a tracer of high-velocity molecular gas. Recent models predict relatively high abundances behind interstellar shockwaves. The dynamical and physical conditions of the H2O emitting…
Context. Molecular Clouds (MCs) are the place where stars are formed and their feedback starts to take place, regulating the evolution of galaxies. Therefore, MCs represent the critical scale at which to study how ultra-violet (UV) photons…
We investigate the chemical history of interstellar OCS and SO2 by deriving a statistically-significant sample of gas-phase column densities towards massive protostars and comparing to observations of gas and ices towards other sources…
A new molecular hydrogen cloud is found in the sub-damped Ly-alpha absorber [log N(HI)=19.88+/-0.05] at the redshift z=1.15 toward the bright quasar HE0515-4414 (zem = 1.71). More than 30 absorption features in the Lyman band system of H2…
Aims. The mobility of H atoms on the surface of interstellar dust grains at low temperature is still a matter of debate. In dense clouds, the hydrogenation of adsorbed species (i.e., CO), as well as the subsequent deuteration of the…
We investigate the water deuteration ratio and ortho-to-para nuclear spin ratio of H2 (OPR(H2)) during the formation and early evolution of a molecular cloud, following the scenario that accretion flows sweep and accumulate HI gas to form…
Water is an important molecule in interstellar and circumstellar environments. Previous observations of mid-infrared rotational lines of OH suggest that these lines may be used to probe the photodissociation of water. In this work, cross…