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We show that the lifetime of ultracold ground-state $^{87}$Rb$^{133}$Cs molecules in an optical trap is limited by fast optical excitation of long-lived two-body collision complexes. We partially suppress this loss mechanism by applying…

Atomic Physics · Physics 2020-04-29 Philip D. Gregory , Jacob A. Blackmore , Sarah L. Bromley , Simon L. Cornish

Ultracold ground-state molecules can be formed from ultracold atoms via photoassociation followed by a spontaneous emission process. Typically, the molecular products are distributed over a range of final states. Here, we propose to use an…

Quantum Physics · Physics 2018-12-20 Tobias Kampschulte , Johannes Hecker Denschlag

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

We report on the creation of ultracold 84Sr2 molecules in the electronic ground state. The molecules are formed from atom pairs on sites of an optical lattice using stimulated Raman adiabatic passage (STIRAP). We achieve a transfer…

Quantum Gases · Physics 2012-09-18 Simon Stellmer , Benjamin Pasquiou , Rudolf Grimm , Florian Schreck

We have performed high-resolution two-photon dark-state spectroscopy of an ultracold gas of Rb molecules in the triplet ground state at a magnetic field of about 1000 G. The vibrational ladder as well as the hyperfine and low-lying…

We perform one- and two-photon high resolution spectroscopy on ultracold samples of RbCs Feshbach molecules with the aim to identify a suitable route for efficient ground-state transfer in the quantum-gas regime to produce quantum gases of…

We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based…

Atomic Physics · Physics 2015-05-19 K. Aikawa , D. Akamatsu , M. Hayashi , K. Oasa , J. Kobayashi , P. Naidon , T. Kishimoto , M. Ueda , S. Inouye

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

We have produced large samples of ultracold $^{88}$Sr$_2$ molecules in the electronic ground state in an optical lattice. The molecules are bound by 0.05 cm$^{-1}$ and are stable for several milliseconds. The fast, all-optical method of…

Atomic Physics · Physics 2015-12-22 G. Reinaudi , C. B. Osborn , M. McDonald , S. Kotochigova , T. Zelevinsky

Ultracold molecules offer entirely new possibilities for the control of quantum processes due to their rich internal structure. Recently, near quantum degenerate gases of molecules have been prepared in their rovibronic ground state. For…

Atomic Physics · Physics 2015-05-14 S. Ospelkaus , K. -K. Ni , G. Quemener , B. Neyenhuis , D. Wang , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

We report the production of ultracold RbCs molecules in the rovibronic ground state, i.e., $X^1\Sigma^+ (v=0, J=0)$, by short-range photoassociation to the $2^3\Pi_{0}$ state followed by spontaneous emission. We use narrowband depletion…

Atomic Physics · Physics 2015-06-22 Toshihiko Shimasaki , Michael Bellos , C. D. Bruzewicz , Zack Lasner , David DeMille

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

Atomic Physics · Physics 2008-10-28 Christiane P. Koch , Robert Moszynski

We report the full control over the internal states of ultracold $^{23}$Na$^{87}$Rb molecules, including vibrational, rotational and hyperfine degrees of freedom. Starting from a sample of weakly bound Feshbach molecules, we realize the…

Quantum Gases · Physics 2018-03-07 Mingyang Guo , Xin Ye , Junyu He , Goulven Quéméner , Dajun Wang

We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye

Ultracold LiCs molecules in the absolute ground state X$^1\Sigma^+$, v"=0, J"=0 are formed via a single photo-association step starting from laser-cooled atoms. The selective production of v"=0, J"=2 molecules with a 50-fold higher rate is…

Quantum Physics · Physics 2010-08-09 J. Deiglmayr , A. Grochola , M. Repp , K. Mörtlbauer , C. Glück , J. Lange , O. Dulieu , R. Wester , M. Weidemüller

We propose to create ultracold ground state molecules in an atomic Bose-Einstein condensate by adiabatic crossing of an optical Feshbach resonance. We envision a scheme where the laser intensity and possibly also frequency are linearly…

Quantum Physics · Physics 2007-05-23 Christiane P. Koch Françoise Masnou-Seeuws Ronnie Kosloff

We have produced ultracold heteronuclear YbRb$^*$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by trap loss spectroscopy in…

Quantum Physics · Physics 2016-01-20 N. Nemitz , F. Baumer , F. Münchow , S. Tassy , A. Görlitz

Recently, the quest for an ultracold and dense ensemble of polar molecules has attracted strong interest. Polar molecules have bright prospects for novel quantum gases with long-range and anisotropic interactions, for quantum information…

We create weakly-bound Li2 molecules from a degenerate two component Fermi gas by sweeping a magnetic field across a Feshbach resonance. The atom-molecule transfer efficiency can reach 85% and is studied as a function of magnetic field and…

Condensed Matter · Physics 2009-11-10 J. Cubizolles , T. Bourdel , S. J. J. M. F. Kokkelmans , G. V. Shlyapnikov , C. Salomon