Related papers: Ultracold Molecules in the Ro-Vibrational Triplet …
We report on the observation of highly excited ($\nu \sim 100)$ vibrational states of a trilobite ultralong-range Rydberg molecule in $^{87}$Rb. These states manifest spectroscopically in a regularly spaced series of peaks red-detuned from…
We explore the uses of ultracold molecules as a platform for future experiments in the field of quantum simulation, focusing on two molecular species, $^{40}$Ca$^{19}$F and $^{87}$Rb$^{133}$Cs. We report the development of coherent quantum…
N$_2$ molecules traveling in pulsed supersonic beams have been excited from their ${\mathrm{X\,^1\Sigma_{\mathrm{g}}^+}}$ ground electronic state to long-lived Rydberg states with principal quantum numbers between 39 and 48 using a…
Ultracold gases in optical lattices are of great interest, because these systems bear a great potential for applications in quantum simulations and quantum information processing, in particular when using particles with a long-range…
This Ph.D. tutorial discusses ultra-long-range Rydberg molecules, the exotic bound states of a Rydberg atom and one or more ground state atoms immersed in the Rydberg electron's wave function. This novel chemical bond is distinct from an…
Optical trapping of molecules with long coherence times is crucial for many protocols in quantum information and metrology. However, the factors that limit the lifetimes of the trapped molecules remain elusive and require improved…
We report on the realization of a multi-orbital system with ultracold atoms in the excited bands of a 3D optical lattice by selectively controlling the band population along a given lattice direction. The lifetime of the atoms in the…
Perfectly controlled molecules are at the forefront of the quest to explore chemical reactivity at ultra low temperatures. Here, we investigate for the first time the formation of the long-lived intermediates in the time-dependent…
Using a non-selective broadband detection scheme we discovered an efficient mechanism of formation of ultracold Cs$_2$ molecules in deeply bound levels ($v=1-9$) of their electronic ground state X$^1 \Sigma_g^+$. They are formed by a…
Pairs of free particles cannot form bound states in elastic collision due to momentum and energy conservation. In many ultracold experiments, however, the particles collide in the presence of an external trapping potential which can couple…
Most cold atoms experiments in microgravity platforms or in Space are achieved using atom chips, leading to limitations in terms of optical access and inhomogeneous magnetic fields. Optical dipole traps do not have these drawbacks but have…
The loss of ultracold trapped atoms in the vicinity of a Feshbach resonance is treated as a two-stage reaction, using the Breit-Wigner theory. The first stage is the formation of a resonant diatomic molecule, and the second one is its…
We often infer the state of systems in nature indirectly, for example, in high-energy physics by the interaction of particles with an ambient medium. We adapt this principle to energies $9$ orders of magnitude smaller, to classify the final…
We report on measurements of the binding energies of several weakly bound vibrational states of the paramagnetic $^{174}$Yb$^{6}$Li molecule in the electronic ground state using two-photon spectroscopy in an ultracold atomic mixture…
We investigate the effect of far-off-resonant trapping light on ultracold bosonic RbCs molecules. We use kHz-precision microwave spectroscopy to measure the differential AC Stark shifts between the ground and first excited rotational levels…
We report the realization of a heteronuclear two-atom of $^{87}$Rb-$^{85}$Rb in the ground state of an optical tweezer (OT). Starting by trapping two different isotopic single atoms, a $^{87}$Rb and a $^{85}$Rb in two strongly focused and…
We use coupled-channel calculations to explore the nature of near-threshold bound states in a simplified model of Rb+KRb. This is a prototype for systems with very strong coupling at short range and chaotic behavior for the short-range…
Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…
We have investigated magnetically tunable Feshbach resonances in ultracold collisions of Rb with Yb in its metastable $^3$P$_2$ and $^3$P$_0$ states, using coupled-channel scattering and bound-state calculations. For the $^3$P$_2$ state, we…
We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…