Related papers: The filled skutterudite CeOs$_{4}$As$_{12}$: a hyb…
A simple tight-binding model is constructed for the description of the electronic structure of some Ce-based filled skutterudite compounds showing an energy gap or pseudogap behavior. Assuming band-diagonal electron interactions on this…
Electrical resistivity $\rho$, specific heat C, and magnetic susceptibility $\chi$ measurements made on the filled skutterudite CeRu_4As_{12} reveal non-Fermi liquid (NFL) T - dependences at low T, i.e., $\rho$(T) $\sim$ T^{1.4} and weak…
Inelastic neutron scattering (INS) and specific heat measurements have been performed on the intermediate valence compound CeRuSi$_3$, which is isostructural to the noncentrosymmetric pressure-induced superconductors CeRhSi$_3$, CeIrSi$_3$…
The Kondo semiconductor CeOs$_{2}$Al$_{10}$ exhibits an antiferromagnetic (AFM) order at $T_\mathrm{N}= 28.5$ K, whose temperature is unexpectedly high for the small ordered moment of $0.3$ $\mu_\mathrm{B}/$Ce. We have studied the effects…
Thermal conductivity measurements were performed on single crystal samples of the superconducting filled skutterudite compounds PrOs$_4$Sb$_{12}$ and PrRu$_4$Sb$_{12}$ both as a function of temperature and magnetic field applied…
We report the specific heat (SH) measurements on single crystals of hole doped $FeAs$-based superconductor $Ba_{0.6}K_{0.4}Fe_2As_2$. It is found that the electronic SH coefficient $\gamma_e(T)$ is not temperature dependent and increases…
In Kondo insulators the many-body Kondo lattice effect drives the formation of bands containing heavy charge carriers with a hybridization gap, leading to insulating properties. These renormalized bands can host non-trivial topologies…
Theoretical account is given of 4f-electron dynamics and multipole orders in Pr skutterudites with particular attention to (i) mechanism of the crystalline electric field (CEF) splitting leading to a pseudo-quartet ground state;(ii) Kondo…
We report the anisotropic changes in the electronic structure of a Kondo semiconductor CeOs$_2$Al$_{10}$ across an anomalous antiferromagnetic ordering temperature ($T_0$) of 29 K, using optical conductivity spectra. The spectra along the…
We propose new topological insulators in cerium filled skutterudite (FS) compounds based on ab initio calculations. We find that two compounds CeOs4As12 and CeOs4Sb12 are zero gap materials with band inversion between Os-d and Ce-f…
In order to clarify magnetic properties of filled skutterudites, we analyze the Anderson model including seven $f$ orbitals hybridized with an $a_{\rm u}$ conduction band using a numerical technique. For $n$=2 corresponding to Pr-based…
On the basis of density functional theory (DFT) calculations thermoelectric properties are derived for Sb-doped skutterudites MPt$_4$Ge$_{12-x}$Sb$_x$ with M=Ba,La,Th. It is predicted that the originally very small absolute values of…
Our ultrasound results obtained in pulsed magnetic fields show that the filled-skutterudite compound SmOs$_4$Sb$_{12}$ has the $\Gamma_{67}$ quartet crystalline-electric-field ground state. This fact suggests that the multipolar degrees of…
Numerical calculations simulate transport experiments in carbon nanotube quantum dots (P. Jarillo-Herrero et al., Nature 434, 484 (2005)), where a strongly enhanced Kondo temperature T_K ~ 8K was associated with the SU(4) symmetry of the…
Specific heat and transport measurements have revealed an unconventional heavy-fermion (HF) state in SmOs4Sb12 single crystals. The electronic specific-heat coefficient (gamma=0.82 J/K^2mol) and the coefficient (A) of the quadratic…
The filled-skutterudite compound CeRu$_4$Sb$_{12}$ shows a pseudo-gap structure in the optical conductivity spectra similar to the Kondo insulators, but metallic behavior below 80 K. The resistivity shows a large peak at 80 K, and the…
Possible Kondo effect in Pr skutterudite is studied with attention to characteristic features of low-lying crystalline electric field (CEF) levels and the conduction band. A mechanism for the small CEF splitting between a singlet and a…
The heavy quasiparticle bands in Kondo materials which originate in the hybridization of f- and conduction electrons exhibit numerous, sometimes coexisting, broken symmetry phases. Most notable are unconventional superconductivity,…
The low-temperature properties of CeOBiS$_2$ single crystals are studied by electrical resistivity, magnetization, and specific heat measurements. Ce 4f -electrons are found to be in a well-localized state split by…
p-type Ce1.05Fe4Sb12.04 filled skutterudites with much improved thermoelectric properties have been synthesized by rapidly converting nearly amorphous ribbons into crystalline pellets under pressure. It is found that this process greatly…