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The mechanical properties of $\beta$-Sn single crystals have been systematically investigated using a combined methodology of micropillar tests and rate-dependent crystal plasticity modelling. The slip strength and rate sensitivity of…

We calculate the electronic structure of germanium-tin (Ge$_{1-x}$Sn$_{x}$) binary alloys for $0 \leq x \leq 1$ using density functional theory (DFT). Relaxed alloys with semiconducting or semimetallic behaviour as a function of Sn…

Materials Science · Physics 2021-05-26 Conor O'Donnell , Alfonso Sanchez-Soares , Christopher A. Broderick , James C. Greer

Due to their narrow band gap and compatibility with silicon processing, germanium-tin (Ge$_{1-x}$Sn$_x$) alloys are a versatile platform for scalable integrated mid-infrared photonics. These semiconductors are typically grown on silicon…

A systematic analysis of thermodynamic properties performed on Ce-base exemplary compounds allows to identify different types of behaviors as the system approaches the quantum critical region. They are recognized in the respective magnetic…

Strongly Correlated Electrons · Physics 2011-08-02 Julian G. Sereni

SnTe, an archetypical topological crystalline insulator, often shows a transition from a highly symmetric cubic phase to a rhombohedral structure at low temperatures. In order to achieve the highly symmetric cubic phase at low temperatures…

Materials Science · Physics 2022-04-06 Ayanesh Maiti , Ankita Singh , Kartik K. Iyer , Arumugam Thamizhavel

Solid solubility (SS) is one of the most important features of alloys, which is usually difficult to be largely tuned in the entire alloy concentrations by external approaches. Some alloys that were supposed to have promising physical…

Materials Science · Physics 2020-02-12 Shiqiao Du , Jianfeng Wang , Lei Kang , Bing Huang , Wenhui Duan

Understanding the unique properties of ultra-wide band gap semiconductors requires detailed information about the exact nature of point defects and their role in determining the properties. Here, we report the first direct microscopic…

Raman light scattering, low-temperature photoluminescence, light-scattering tomography, and hydrogenation were used to investigate optical properties of defects in strain-relaxed Si_{1-x}Ge_x (0.05 \le x \le 0.50) alloys. The…

Materials Science · Physics 2021-10-12 Seref Kalem

Tin-chalcogenides SnX (X = Te, Se and S) have been arousing research interest due to their thermoelectric physical properties. The two-dimensional (2D) counterparts, which are expected to enhance the property, nevertheless, have not been…

Materials Science · Physics 2019-01-15 Baojuan Dong , Zhenhai Wang , Nguyen T. Hung , Artem R. Oganov , Teng Yang , Riichiro Saito , Zhidong Zhang

The electronic and optical properties of (Zn,Mg)(S,Se) wide-gap solid solutions are studied using ab initio techniques and starting from the previously determined atomistic structure of the alloy. Compositional disorder is shown to close…

Materials Science · Physics 2007-05-23 Antonino Marco Saitta , Stefano de Gironcoli , Stefano Baroni

High-entropy alloys (HEAs), which have been intensely studied due to their excellent mechanical properties, generally refer to alloys with multiple equimolar or nearly equimolar elements. According to this definition, Si-Ge-Sn alloys with…

Materials Science · Physics 2020-01-08 D. Wang , L. Liu , W. Huang , H. L. Zhuang

We report superconductivity in Sn$_{x}$NbSe$_{2-\delta}$, a topological nodal-line semimetal candidate with a noncentrosymmetric crystal structure. The superconducting transition temperature $T_{c}$ of this compound is extremely sensitive…

MnBi2Te4 is a versatile platform for exploring diverse topological quantum states, yet its potential is hampered by intrinsic antisite defects. While Sb substitution has been employed to tune the Fermi level towards the charge neutral…

In this article we employ density functional theory in the generalized gradient approximation to investigate the structural and electronic properties of the solid solution alloy $\text{Zn}\text{Se}_x\text{S}_{1-x}$ in the wurtzite…

Materials Science · Physics 2022-05-18 S. Sarkar , O. Eriksson , D. D. Sarma , I. Di Marco

We report on the structural, electronic and vibrational properties of the Ga$_{1-x}$In$_x$N alloy using virtual crystal approximation (VCA) from first-principles. A band gap bowing parameter of 3.85 eV is obtained with the TB09 functional.…

Materials Science · Physics 2015-09-17 Jian Liu

We report the discovery of superconductivity in binary alloy Sn$_{1-x}$Sb$_{x}$ with $x$ in the range of 0.43 to 0.6, which possesses a modulated rhombohedral structure due to the incommensurate ordering of Sn and Sb layers along the…

We characterize germanium-vacancy GeVn complexes in silicon using first-principles Density Functional Theory calculations with screening-dependent hybrid functionals. We report on the local geometry and electronic excited states of these…

Computational Physics · Physics 2019-01-30 Simona Achilli , Nicola Manini , Giovanni Onida , Takahiro Shinada , Takashi Tanii , Enrico Prati

Local composition fluctuations in random alloys become crucial when one or more dimensions are reduced to the nanoscale. Using extended H\"uckel theory, we study the semiconductor random alloy SiGe sandwiched between Si due to its relevance…

Mesoscale and Nanoscale Physics · Physics 2026-03-20 Daniel Dick , Florian Fuchs , Sibylle Gemming , Jörg Schuster

The cubic $Ia\bar{3}$ (BC8) and tetragonal $P4_32_12$ (ST12) high pressure modifications of Si and Ge are attractive candidates for applications in optoelectronic, thermoelectric or plasmonic devices. Si$_x$Ge$_{1-x}$ alloys in BC8/ST12…

Materials Science · Physics 2020-08-26 Johannes Wagner , Maribel Núñez-Valdez

Several approaches have been used to investigate the impact of Nitrogen (N) on the electronic structure of GaAs$_{1-x}$N$_{x}$ alloys, however, there is no agreement between theory and experiments about the importance of the different N…

Materials Science · Physics 2019-02-27 J. D. Querales-Flores , C. I. Ventura , J. D. Fuhr