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Grazing-incidence X-ray diffraction (GIXRD) is a scattering technique which allows one to characterize the structure of fluid interfaces down to the molecular scale, including the measurement of the surface tension and of the interface…

Soft Condensed Matter · Physics 2024-04-10 Felix Höfling , Siegfried Dietrich

Grazing incidence x-ray surface scattering has been used to investigate liquid surfaces down to the molecular scale. The free surface of water is well described by the capillary wave model (<z(q)z(-q)> ~ q-2 spectrum) up to wavevectors >…

There are various routes for deriving partial radial distribution functions of disordered systems from experimental diffraction (and/or EXAFS) data. Due to limitations and errors of experimental data, as well as to imperfections of the…

Disordered Systems and Neural Networks · Physics 2012-07-16 Z. Steinczinger , L. Pusztai

Surface waves on liquids act as a dynamical phase grating for incident light. In this article, we revisit the classical method of probing such waves (wavelengths of the order of mm) as well as inherent properties of liquids and liquid films…

Optics · Physics 2009-11-11 Tarun Kr. Barik , Partha Roy Chaudhuri , Anushree Roy , Sayan Kar

We have developed x-ray diffraction measurements with high energy-resolution and accuracy to study water structure at three different temperatures (7, 25 and 66 C) under normal pressure. Using a spherically curved Ge crystal an energy…

Soft Condensed Matter · Physics 2017-09-13 Congcong Huang , K. T. Wikfeldt , D. Nordlund , U. Bergmann , T. McQueen , J. Sellberg , L. G. M. Pettersson , A. Nilsson

We describes a new approach for performing quantitative structure-factor analysis and density measurements of liquids using x-ray diffraction with a pink-spectrum x-ray source. The methodology corrects for the pink beam effect by performing…

We achieved a tripling of the maximum range of perpendicular momentum transfer (q_z) of X-ray scattering from liquid surfaces using a double crystal deflector setup to tilt the incident X-ray beam. This is obtained by using Miller indices…

Materials Science · Physics 2022-10-28 Oleg Konovalov , Valentina Belova , Mehdi Saedi , Irene Groot , Gilles Renaud , Maciej Jankowski

We propose a method of transformation from a force curve obtained with a surface force apparatus (SFA) to a density distribution of a liquid near a surface. The method is based on the statistical mechanics of liquids. As a first step, we…

Data Analysis, Statistics and Probability · Physics 2015-11-17 Ken-ich Amano , Ohgi Takahashi

Grazing Incidence X-ray Diffraction (GIXD) is a surface sensitive X-ray investigation technique (or geometry configuration) that can reveal the structural properties of a film deposited on a flat substrate. The term grazing indicates that…

Soft Condensed Matter · Physics 2015-12-29 Samuele Lilliu , Thomas Dane

Several computer simulation studies of aqueous dimethylsulfoxyde with different force field models, and conducted by different authors, point out to an anomalous depressing of second and third neighbour correlations of the water-water…

Chemical Physics · Physics 2018-09-26 Aurélien Perera , Bernarda Lovrinčević

We examine the applicability of various model profiles for the liquid/vapor interface by X-ray reflectivities on water and ethanol and their mixtures at room temperature. Analysis of the X-ray reflecivities using various density profiles…

Soft Condensed Matter · Physics 2014-04-30 Wei Bu , Doseok Kim , David Vaknin

An image plate (IP) detector coupled with high energy synchrotron radiation was used for atomic pair distribution function (PDF) analysis, with high probed momentum transfer \Qmax $\leq 28.5$ \RAA from crystalline materials. Materials with…

Due to the simultaneous presence of bulk-like and interfacial fluctuations the understanding of the structure of liquid-vapour interfaces poses a long-lasting and ongoing challenge for experiments, theory, and simulations. We provide a new…

Statistical Mechanics · Physics 2015-02-24 F. Höfling , S. Dietrich

Optical methods are most convenient to analyze spatially periodic patterns with wavevector $\bm q$ in a thin layer of a nematic liquid crystal. In the standard experimental setup a beam of parallel light with a 'short' wavelength $\lambda…

Soft Condensed Matter · Physics 2015-06-15 Werner Pesch , Alexei Krekhov

Grazing incidence X-ray diffraction (GIXD) is widely used for the structural characterization of thin films, particularly for analyzing phase composition and the orientation distribution of crystallites. While various tools exist for…

This paper describes the application of a laser diffraction technique to the study of electroconvection in nematic liquid crystal cells. It allows a real-time quantitative access to pattern wave lengths and amplitudes. The diffraction…

Strongly Correlated Electrons · Physics 2009-11-07 Th. John , U. Behn , R. Stannarius

We demonstrate a strategy for simulating wide-range X-ray scattering patterns, which spans the small- and wide scattering angles as well as the scattering angles typically used for Pair Distribution Function (PDF) analysis. Such simulated…

The phase-separation kinetics of binary fluids in shear flow is studied numerically in the framework of the continuum convection-diffusion equation based on a Ginzburg-Landau free energy. Simulations are carried out for different…

Condensed Matter · Physics 2009-10-31 F. Corberi , G. Gonnella , A. Lamura

We study the density-density correlation function $G({\bf r},{\bf r}')$ in the interfacial region of a fluid (or Ising-like magnet) with short-ranged interactions using square gradient density functional theory. Adopting a simple double…

Statistical Mechanics · Physics 2015-06-19 A. O. Parry , C. Rascón , G. Willis , R. Evans

We report x-ray reflectivity (XR) and small angle off-specular diffuse scattering (DS) measurements from the surface of liquid Indium close to its melting point of $156^\circ$C. From the XR measurements we extract the surface structure…

Materials Science · Physics 2009-11-10 Holger Tostmann , Oleg Shpyrko , Peter S. Pershan , Elaine Dimasi , Ben Ocko , Moshe Deutsch
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