Related papers: Negative thermal expansion in single-component sys…
For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for system in…
Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal-organic framework (MOF). Incorporation of correlated vacancy defects within…
We present a model to probe metamagnetic properties in systems with an arbitrary number of interacting spins. Thermodynamic properties such as the magnetization per particle $m(B,T,N)$, linear susceptibility $\chi_1(T)$, nonlinear…
Recent experimental work has revealed that the unusually strong, isotropic structural negative thermal expansion in cubic perovskite ionic insulator ScF3 occurs in excited states above a ground state tuned very near a structural quantum…
We present a general method for the high-temperature expansion of the self-energy of interacting particles. Though the method is valid for fermions and bosons, we illustrate it for spin one half fermions interacting via a zero range…
The structural dynamics of a 1D mixed-metal cyanide, Cu$_{1/3}$Ag$_{1/3}$Au$_{1/3}$CN, with intriguing thermal properties is explored. All the current known related compounds with straight-chain structures, such as CuCN, AgCN, AuCN and…
The common wisdom that volume decreases with pressure and increases with temperature is analyzed in terms of Hillert nonequilibrium thermodynamics in the present work. It is shown that the derivative of volume to pressure in a stable system…
We study the monodomain (single-crystal) nematic elastomer materials, all side-chain siloxane polymers with the same mesogenic groups and crosslinking density, but differing in the type of crosslinking. Increasing the proportion of long…
We use a symmetry-motivated approach to analysing X-ray pair distribution functions to study the mechanism of negative thermal expansion in two ReO$_3$-like compounds; ScF$_3$ and CaZrF$_6$. Both average and local structure suggest that it…
Negative entropy in connection with the Casimir effect at uniform temperature is a phenomenon rooted in the circumstance that one is describing a nonclosed system, or only part of a closed system. In this paper we show that the phenomenon…
A molecular dynamics study of a two dimensional system of particles interacting through a Lennard-Jones pairwise potential is performed at fixed temperature and vanishing external pressure. As the temperature is increased, a solid-to-liquid…
Casimir entropies due to quantum fluctuations in the interaction between electrical bodies can often be negative, either caused by dissipation or by geometry. Although generally such entropies vanish at zero temperature, consistent with the…
Thermodynamics properties of an interacting system of bosons are considered at finite temperatures and zero chemical potential within the Skyrme-like mean-field model. An interplay between attractive and repulsive interactions is…
We investigate the non-equilibrium behavior of the $3d$ random field Ising model at finite temperature, as an external field is increased through its coercive field. We show by numerical simulations that the phenomenology of avalanches --…
We present a mesoscopic model for thermoelectric phenomena in terms of an interacting particle system, a lattice electron gas dynamics that is a suitable extension of the standard simple exclusion process. We concentrate on electronic heat…
The Ising-like anisotropy parameter $\delta$ in the Kondo necklace model is analyzed using the bond-operator method at zero and finite temperatures for arbitrary $d$ dimensions. A decoupling scheme on the double time Green's functions is…
As demand rises for flexible electronics, traditionally prepared sintered ceramic sensors must be transformed into fully new sensor materials that can bend and flex in use and integration. Negative temperature coefficient of resistance…
Organic charge transfer salts exhibit thermal expansion anomalies similar to those found in other strongly correlated electron systems. The thermal expansion can be anisotropic and have a non-monotonic temperature dependence. We show how…
We study non-canonical relaxation in a composite cold atoms system, consisting of subsystems that possess negative microcanonical specific heat. The system exhibits pre-thermalization far away from integrability due to the appearance of a…
One-dimensional systems, such as nanowires or electrons moving along strong magnetic field lines, have peculiar thermalization physics. The binary collision of point-like particles, typically the dominant process for reaching thermal…