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Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$) and Yb$^+$, and between Li and Yb$^+$, are studied theoretically, using accurate effective-core-potential based…

Atomic Physics · Physics 2015-06-23 Humberto Da Silva , Maurice Raoult , Mireille Aymar , Olivier Dulieu

We investigate the formation of ultracold NaCs molecules by photoassociation of Na and Cs atoms.

Chemical Physics · Physics 2010-08-09 Xuan Li

Ultracold gases in optical lattices are of great interest, because these systems bear a great potential for applications in quantum simulations and quantum information processing, in particular when using particles with a long-range…

Statistical Mechanics · Physics 2007-05-23 T. Volz , N. Syassen , D. M. Bauer , E. Hansis , S. Dürr , G. Rempe

We consider the use of pulse-shaped broadband femtosecond lasers to optically cool rotational and vibrational degrees of freedom of molecules. Since this approach relies on cooling rotational and vibrational quanta by exciting an electronic…

Atomic Physics · Physics 2017-09-13 Chien-Yu Lien , Scott R. Williams , Brian Odom

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

A novel atom-molecule conversion technique has been investigated. Ultracold 85Rb atoms sitting in a DC magnetic field near the 155G Feshbach resonance are associated by applying a small sinusoidal oscillation to the magnetic field. There is…

Other Condensed Matter · Physics 2009-11-11 S. T. Thompson , E. Hodby , C. E. Wieman

We demonstrate the conversion of cold Cs_{2} molecules initially distributed over several vibrational levels of the lowest triplet state a^{3}\Sigma_{u}^{+} into the singlet ground state X^{1}\Sigma_{g}^{+}. This conversion is realized by a…

We show that it is possible to excite higher rotational states J > 2 in ultracold photoassociation by two laser fields. Usually higher J states are suppressed in photoassociation at ultracold temperatures in the regime of Wigner threshold…

Atomic Physics · Physics 2015-05-14 Jisha Hazra , Bimalendu Deb

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

We report efficient all-optical creation of an ultracold gas of alkaline-earth-metal dimers, $^{88}\rm{Sr}_2$, in their absolute ground state. Starting with weakly bound singlet molecules formed by narrow-line photoassociation in an optical…

Atomic Physics · Physics 2021-11-01 K. H. Leung , E. Tiberi , B. Iritani , I. Majewska , R. Moszynski , T. Zelevinsky

We describe the generation and properties of a cryogenic beam of $^7$Li$_2$ dimers from sublimation of a neon matrix where lithium atoms have been implanted via laser ablation of solid precursors of metallic lithium or lithium hydride…

Complex organic molecules (COMs) have been detected in the gas-phase in cold and lightless molecular cores. Recent solid-state laboratory experiments have provided strong evidence that COMs can be formed on icy grains through…

Solar and Stellar Astrophysics · Physics 2020-10-21 D. Qasim , G. Fedoseev , K. -J. Chuang , V. Taquet , T. Lamberts , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

We present a technique for engineering quantum magnets via ultracold polar molecules in optical lattices and explore exotic interplay between its spin superfluidity and solidity. The molecular ground and first excited rotational states are…

Quantum Gases · Physics 2009-10-27 Hongyi Yu , W. M. Liu , Chaohong Lee

We propose high-spin $\Sigma$-state polar molecules assembled from ultracold atoms to probe charge-parity violating physics beyond the Standard Model. We identify YbCr as a prime candidate to search for the electric dipole moment of the…

Quantum Gases · Physics 2026-03-16 Alessio Ciamei , Adam Koza , Marcin Gronowski , Michał Tomza

We study the growth dynamics of ordered structures of strongly interacting polar molecules in optical lattices. Using dipole blockade of microwave excitations, we map the system onto an interacting spin-1/2 model possessing ground states…

Quantum Gases · Physics 2012-09-17 Mikhail Lemeshko , Roman V. Krems , Hendrik Weimer

Atomic-resolution-imaging approaches for single molecules, such as coherent x-ray diffraction at free-electron lasers, require the delivery of high-density beams of identical molecules. However, even very cold beams of biomolecules…

Chemical Physics · Physics 2018-06-01 Nicole Teschmit , Daniel A. Horke , Jochen Küpper

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

Laser cycling of resonances can remove entropy from a system via spontaneously emitted photons, with electronic resonances providing the fastest cooling timescales because of their rapid relaxation rates. Although atoms are routinely laser…

We demonstrate the coherent creation of a single NaCs molecule in its rotational, vibrational, and electronic (rovibronic) ground state in an optical tweezer. Starting with a weakly bound Feshbach molecule, we locate a two-photon transition…

Recently, the quest for an ultracold and dense ensemble of polar molecules has attracted strong interest. Polar molecules have bright prospects for novel quantum gases with long-range and anisotropic interactions, for quantum information…

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