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Using non-resonant Fe K-beta x-ray emission spectroscopy, we reveal that Sr-doping of CaFe2As2 decouples the Fe moment from the volume collapse transition, yielding a collapsed-tetragonal, paramagnetic normal state out of which…

Structural and electronic characterization of (Ca0.67Sr0.33)Fe2As2 has been performed as a func- tion of pressure up to 12 GPa using conventional and designer diamond anvil cells. The compound (Ca0.67Sr0.33)Fe2As2 behaves intermediate…

Superconductivity · Physics 2015-06-04 J. R. Jeffries , N. P. Butch , K. Kirshenbaum , S. R. Saha , S. T. Weir , Y. K. Vohra , J. Paglione

The antiferromagnet CaFe$_2$As$_2$ does not become superconducting when subject to ideal hydrostatic pressure conditions, where crystallographic and magnetic states also are well defined. By measuring electrical resistivity and magnetic…

Superconductivity · Physics 2009-08-01 Hanoh Lee , Eunsung Park , Tuson Park , V. A. Sidorov , F. Ronning , E. D. Bauer , J. D. Thompson

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

Superconductivity · Physics 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

The relationship between antiferromagnetic spin fluctuations and superconductivity has become a central topic of research in studies of superconductivity in the iron pnictides. We present unambiguous evidence of the absence of magnetic…

Inelastic neutron scattering measurements of CaFe2As2 under applied hydrostatic pressure show that the antiferromagnetic spin fluctuations observed in the ambient pressure, paramagnetic, tetragonal (T) phase are strongly suppressed, if not…

At ambient pressure CaFe2As2 has been found to undergo a first order phase transition from a high temperature, tetragonal phase to a low temperature orthorhombic / antiferromagnetic phase upon cooling through T ~ 170 K. With the application…

Using {\it ab initio} molecular dynamics we investigate the electronic and lattice structure of $A$Fe$_2$As$_2$ ($A$=Ca, Sr, Ba) under pressure. We find that the structural phase transition (orthorhombic to tetragonal symmetry) is always…

Superconductivity · Physics 2009-10-13 Yu-Zhong Zhang , Hem C. Kandpal , Ingo Opahle , Harald O. Jeschke , Roser Valenti

A well-known feature of CaFe$_{2}$As$_{2}$-based superconductors is the pressure-induced collapsed tetragonal phase that is commonly ascribed to the formation of an interlayer As-As bond. Using detailed X-ray scattering and spectroscopy, we…

By performing pressure simulations within density functional theory for the family of iron-based superconductors $Ae{}A$Fe$_4$As$_4$ with $Ae$ = Ca, Sr, Ba and $A$ = K, Rb, Cs we predict in these systems the appearance of two consecutive…

Materials Science · Physics 2018-08-29 Vladislav Borisov , Paul C. Canfield , Roser Valenti

We present detailed electronic structure calculations for CaFe2As2. We investigate in particular the `collapsed' tetragonal and orthorhombic regions of the temperature-pressure phase diagram and find properties that distinguish CaFe2As2…

Strongly Correlated Electrons · Physics 2009-03-27 D. A. Tompsett , G. G. Lonzarich

The surprising discovery of tripling the superconducting critical temperature of KFe$_2$As$_2$ at high pressures issued an intriguing question of how the superconductivity in the collapsed tetragonal phase differs from that in the…

Strongly Correlated Electrons · Physics 2017-11-29 J. Srpcic , P. Jeglic , I. Felner , Bing Lv , C. W. Chu , D. Arcon

75As-zero-field nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements are performed on CaFe2As2 under pressure. At P = 4.7 and 10.8 kbar, the temperature dependences of nuclear-spin-lattice relaxation rate…

Superconductivity · Physics 2015-05-18 S. Kawasaki , T. Tabuchi , X. F. Wang , X. H. Chen , Guo-qing Zheng

CaFe2As2 single crystals under uniaxial pressure applied along the c axis exhibit the coexistence of several structural phases at low temperatures. We show that the room-temperature tetragonal phase is stabilized at low temperatures for…

Recent high-pressure studies found that superconductivity can be achieved under very low pressure in the parent iron arsenide compound CaFe2As2, although details of the sharpness and temperature of transitions vary between liquid medium and…

Superconductivity · Physics 2009-11-13 W. Yu , A. A. Aczel , T. J. Williams , S. L. Bud'ko , N. Ni , P. C. Canfield , G. M. Luke

Recently, KFe$_2$As$_2$ was shown to exhibit a structural phase transition from a tetragonal to a collapsed tetragonal phase under applied pressure of about $15~\mathrm{GPa}$. Surprisingly, the collapsed tetragonal phase hosts a…

Superconductivity · Physics 2015-04-14 Daniel Guterding , Steffen Backes , Harald O. Jeschke , Roser Valenti

We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of…

Recent studies reveal a pressure induced transition from a paramagnetic tetragonal phase (T) to a collapsed tetragonal phase (CT) in $CaFe_2As_2$, which was found to be superconducting with non-hydrostatic pressure at low temperature. We…

Superconductivity · Physics 2015-06-22 Subhasish Mandal , R. E. Cohen , K. Haule

We report $^{75}$As NMR studies on single crystals of rare-earth doped iron pnictides superconductor Ca$_{1-x}$Pr$_{x}$Fe$_{2}$As$_{2}$ ($x$=0.075 and 0.15). The $^{75}$As spectra show a chemical pressure effect with doping and a first…

Superconductivity · Physics 2013-04-16 Long Ma , G. F. Ji , J. Dai , S. R. Saha , J. Paglione , Weiqiang Yu

By performing high-pressure single-crystal neutron diffraction measurements, the evolution of structure and magnetic ordering in EuFe2As2 under hydrostatic pressure were investigated. Both the tetragonal-toorthorhombic structural transition…

Superconductivity · Physics 2019-07-24 W. T. Jin , Y. Xiao , S. Nandi , S. Price , Y. Su , K. Schmalzl , W. Schmidt , T. Chatterji , A. Thamizhavel , Th. Brueckel
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