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We present uniaxial pressure structural relaxations for CaFe2As2 and BaFe2Ase2 within density functional theory and compare them with calculations under hydrostatic pressure conditions as well as available experimental results. We find that…

Strongly Correlated Electrons · Physics 2012-03-19 Milan Tomic , Roser Valenti , Harald O. Jeschke

We studied the temperature-pressure phase diagram of EuFe2As2 by measurements of the electrical resistivity. The antiferromagnetic spin-density-wave transition at T_0 associated with the FeAs-layers is continuously suppressed with…

Superconductivity · Physics 2009-06-20 C. F. Miclea , M. Nicklas , H. S. Jeevan , D. Kasinathan , Z. Hossain , H. Rosner , P. Gegenwart , C. Geibel , F. Steglich

We report a systematic and ab-initio electronic structure calculation of Ca0.75 M0.25 Fe2 As2 with M = Ca, Sr, Eu, La, Ce, Pr, Nd, Pm, Sm, Na, K, Rb. The recently reported experimentally observed structural trends in rare earths-doped CaFe2…

Superconductivity · Physics 2014-06-26 A. Sanna , G. Profeta , S. Massidda , E. K. U. Gross

CaFe2As2 exhibits collapsed tetragonal (cT) structure and varied exotic behavior under pressure at low temperatures that led to debate on linking the structural changes to its exceptional electronic properties like superconductivity,…

Superconductivity · Physics 2017-12-12 Khadiza Ali , Kalobaran Maiti

The magnetic structure of superconducting Eu(Fe0.82Co0.18)2As2 is unambiguously determined by single-crystal neutron diffraction. A long-range ferromagnetic order of the Eu2+ moments along the c-direction is revealed below the magnetic…

Superconductivity · Physics 2014-05-06 W. T. Jin , S. Nandi , Y. Xiao , Y. Su , O. Zaharko , Z. Guguchia , Z. Bukowski , S. Price , W. H. Jiao , G. H. Cao , Th. Brueckel

Single crystal neutron and high-energy x-ray diffraction have identified the phase lines corresponding to transitions between the ambient-pressure tetragonal (T), the antiferromagnetic orthorhombic (O) and the non-magnetic collapsed…

With the proposed Hund's rule correlation picture, i.e. the fluctuating Fe local moments with the As-bridged antiferromagnetic superexchange interactions, the exceptional collapsed tetragonal phase and related phase transitions observed in…

Materials Science · Physics 2011-04-28 Wei Ji , Xun-Wang Yan , Zhong-Yi Lu

CaFe$_2$As$_2$ has been found to be exceptionally sensitive to the application of hydrostatic pressure and superconductivity has been found to exist in a narrow pressure region that appears to be at the interface between two different phase…

Superconductivity · Physics 2009-11-13 Milton S. Torikachvili , Sergey L. Bud'ko , Ni Ni , Paul C. Canfield

In the temperature-concentration phase diagram of most iron-based superconductors, antiferromagnetic order is gradually suppressed to zero at a critical point, and a dome of superconductivity forms around that point. The nature of the…

We report the observation of the pressure-induced, fully-collapsed tetragonal phase of CaRbFe4As4 for P~ 22 GPa via high-pressure x-ray diffraction and magnetotransport measurements. The x-ray measurements, along with resistivity…

We present the results of electrical resistivity, ac specific heat, magnetic susceptibility, X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) of the ternary iron arsenide EuFe2As2 single crystal under…

We perform first principles calculations on CaFe2As2 under hydrostatic pressure. Our total energy calculations show that though the striped antiferromagnetic (AFM) orthorhombic (OR) phase is favored at P=0, a non-magnetic collapsed…

Strongly Correlated Electrons · Physics 2015-06-05 Michael Widom , Khandker Quader

In contrast to SrFe2As2, where only the iron possesses a magnetic moment, in EuFe2As2 an additional large, local magnetic moment is carried by Eu2+. Like SrFe2As2, EuFe2As2 exhibits a spin-density wave transition at high temperatures, but…

Superconductivity · Physics 2011-03-03 M. Nicklas , M. Kumar , E. Lengyel , W. Schnelle , A. Leithe-Jasper

We report pressure-induced superconductivity in a single crystal of CaFe2As2. At atmospheric pressure, this material is antiferromagnetic below 170 K but under an applied pressure of 0.69 GPa becomes superconducting, with a transition…

Superconductivity · Physics 2008-07-18 Tuson Park , Eunsung Park , Hanoh Lee , T. Klimczuk , E D Bauer , F Ronning , J D Thompson

Single crystals of Ca(Fe1-xRux)2As2 (0<x<0.065) and Ca1-yLay(Fe0.973Ru0.027)2As2 (0<y<0.2) have been synthesized and studied with respect to their structural, electronic and magnetic properties. The partial substitution of Fe by Ru induces…

Strongly Correlated Electrons · Physics 2015-12-23 K. Zhao , C. Stingl , R. S. Manna , C. Q. Jin , P. Gegenwart

Motivated by pressure experiments on FeAs-122 superconductors, we propose a scenario based on local-moment physics to explain the simultaneous disappearance of magnetism, reduction of the unit cell volume, and decrease in resistivity. In…

Superconductivity · Physics 2015-05-13 Andreas Hackl , Matthias Vojta

High pressure electrical resistance and x-ray diffraction measurements have been performed on ruthenium-doped Ba(Fe0.9Ru0.1)2As2, up to pressures of 32 GPa and down to temperatures of 10 K, using designer diamond anvils under…

Superconductivity · Physics 2014-04-15 Walter Uhoya , Georgiy M. Tsoi , Yogesh K. Vohra , Athena S. Sefat , Samuel T. Weir

The density functional non-interacting susceptibility has been analyzed in different phases of CaFe2As2 and compared with similar data for pure d-metals. The conditions for the "no local moment" itinerant state with large frustrations are…

Superconductivity · Physics 2009-11-13 G. D. Samolyuk , V. P. Antropov

The recent discovery and subsequent developments of FeAs-based superconductors have presented novel challenges and opportunities in the quest for superconducting mechanisms in correlated-electron systems. Central issues of ongoing studies…

Compounds with a tetragonal ThCr$_{2}$Si$_{2}$-type structure are characterized by the possibility of the isostructural phase transition from the tetragonal phase to the collapsed tetragonal phase induced by the external pressure. An…

Superconductivity · Physics 2019-04-16 Andrzej Ptok , Małgorzata Sternik , Konrad Jerzy Kapcia , Przemysław Piekarz