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We present detailed ab-initio lattice dynamical analysis of the Fe-O infinite-layer compounds CaFeO2 and SrFeO2 in various magnetic configurations. These indicate strong spin-phonon coupling in SrFeO2 in contrast to that in case of CaFeO2.…

Materials Science · Physics 2016-09-13 M. K. Gupta , R. Mittal , S. L. Chaplot , Cedric Tassel , Hiroshi Kageyama

Following previous works reporting an anomalous behavior of several zone-center optical phonons across the magnetic transition of square lattice iridates Sr2IrO4 and Sr3Ir2O7, we have investigated the lattice dynamics as a function of…

Strongly Correlated Electrons · Physics 2022-02-02 K. Sen , R. Heid , S. M. Souliou , D. Boll , A. Bosak , N. H. Sung , J. Bertinshaw , H. Gretarsson , B. J. Kim , F. Weber , M. Le Tacon

We report a first-principles study of SrFeO$_2$, an infinite-layer oxide with Fe atoms in a perfect square-planar coordination down to essentially 0 K. Our results reveal this striking behavior relies on the double occupation of the…

Materials Science · Physics 2009-12-17 J. M. Pruneda , Jorge Iniguez , Enric Canadell , Hiroshi Kageyama , Mikio Takano

Lattice dynamics and molecular dynamics studies of the oxides UO2 and Li2O in their normal as well as superionic phase are reported. Lattice dynamics calculations have been carried out using a shell model in the quasiharmonic approximation.…

Materials Science · Physics 2011-11-10 Prabhatasree Goel , N. Choudhury , S. L. Chaplot

We present a comprehensive investigation of lattice dynamics in the double-helix antiferromagnet FeP by means of high-resolution time-of-flight neutron spectroscopy and ab-initio calculations. Phonons can hybridize with the magnetic…

We compute lattice dynamical properties of iron at the bcc-fcc phase transition using dynamical mean-field theory implemented with the frozen-phonon method. Electronic correlations are found to have a strong effect on the lattice stability…

Materials Science · Physics 2015-05-30 I. Leonov , A. I. Poteryaev , V. I. Anisimov , D. Vollhardt

Au-Fe alloys are of immense interest due to their biocompatibility, anomalous hall conductivity, and applications in various medical treatment. However, irrespective of the method of preparation, they often exhibit a high-level of disorder,…

Materials Science · Physics 2017-09-27 Jiban Kangsabanik , Rajiv K. Chouhan , D. D. Johnson , Aftab Alam

Polycrystalline samples of the layered iron arsenides Sr2CrO3FeAs and Ba2ScO3FeAs were synthesized by high temperature solid state reactions and their crystal structures determined by the X-ray powder diffraction. Their structures are…

The calculations are performed for a broad range of the properties of Ca and Sr in the fcc and bcc phases. A detailed information on the magnitude and character of temperature dependence of anharmonic effects in the lattice dynamics over…

Materials Science · Physics 2017-08-23 M. I. Katsnelson , A. V. Trefilov , M. N. Khlopkin , K. Yu. Khromov

We report here first extensive measurements of the temperature dependence of phonon density of states of BaFe2As2, the parent compound of the newly discovered FeAs-based superconductors, using inelastic neutron scattering. The experiments…

Superconductivity · Physics 2008-09-17 R. Mittal , Y. Su , S. Rols , T. Chatterji , S. L. Chaplot , H. Schober , M. Rotter , D. Johrendt , Th. Brueckel

We recently proposed a high-pressure and high-temperature P-62m-symmetry polymorph for CaF2 on the basis of ab-initio random structure searching and density-functional theory calculations [Phys. Rev. B 95, 054118 (2017)]. We revisit this…

Materials Science · Physics 2018-12-13 Joseph R. Nelson , Richard J. Needs , C. J. Pickard

We measured the Raman and the Infrared phonon spectrum of SmFeAsO polycrystalline samples. We also performed Density Functional Theory calculations within the pseudopotential approximation to obtain the structural and dynamical lattice…

We report the development of a forcefield capable of reproducing accurate lattice dynamics of metal-organic frameworks. Phonon spectra, thermodynamic and mechanical properties, such as free energies, heat capacities and bulk moduli, are…

Materials Science · Physics 2016-10-28 J. K. Bristow , J. M. Skelton , K. L. Svane , A. Walsh , J. D. Gale

Possible variations in the dynamical behaviour of LiYF$_{4}$ due to its several structural changes under pressure are examined by making use of the complementary techniques of quasi-harmonic lattice dynamics and molecular dynamics…

Materials Science · Physics 2007-05-23 A. Sen , S. L. Chaplot , R. Mittal

Density functional based simulations are employed to explore magnetoelectric effects in iron-based oxides, showing a unique layered structure. We theoretically predict CaFeO2 to be a promising magnetoelectric, showing…

Strongly Correlated Electrons · Physics 2015-06-15 Kunihiko Yamauchi , Tamio Oguchi , Silvia Picozzi

The layered cobaltate CaCoO$_2$ exhibits a unique herringbone-like structure. Serving as a potential prototype for a new class of complex lattice patterns, we study the properties of CaCoO$_2$ using X-ray absorption spectroscopy (XAS) and…

We present a model of the lattice dynamics of the rare earth titanate pyrochlores R2Ti2O7 (R=Tb, Dy, Ho), which are important materials in the study of frustrated magnetism. The phonon modes are obtained by density functional calculations,…

The ferropnictide superconductors exhibit a sensitive interplay between the lattice and magnetic degrees of freedom, including a number of phonon modes that are much softer than predicted by nonmagnetic calculations using density functional…

Superconductivity · Physics 2014-03-13 D. Parshall , R. Heid , J. L. Niedziela , Th. Wolf , M. B. Stone , D. L. Abernathy , D. Reznik

We study the lattice dynamics of antiferromagnetic transition-metal oxides by using self-consistent Hubbard functionals. We calculate the ground states of the oxides with the on-site and intersite Hubbard interactions determined…

Strongly Correlated Electrons · Physics 2022-06-01 Wooil Yang , Bo Gyu Jang , Young-Woo Son , Seung-Hoon Jhi

We have discovered new layered oxyarsenides (Fe2As2)(Sr4M2O6) (M = Sc, Cr: M-22426). These materials are isostructural with (Fe2P2)(Sr4Sc2O6), which was found in our previous study. The new compounds are tetragonal with a space group of…

Superconductivity · Physics 2009-06-24 Hiraku Ogino , Yukari Katsura , Shigeru Horii , Kohji Kishio , Jun-ichi Shimoyama
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