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A novel electrochemical means to generate atomic hydrogen, simplifying the synthesis and controllability of graphane formation on graphene is presented. High quality, vacuum grown epitaxial graphene (EG) was used as starting material for…

Graphene based sheets have stimulated great interest due to their superior mechanical, electrical and thermal properties. A general visualization method that allows quick observation of these single atomic layers would be highly desirable…

Materials Science · Physics 2009-12-15 Jaemyung Kim , Laura J. Cote , Franklin Kim , Jiaxing Huang

Heavily doping graphene by intercalation can raise its Fermi level near an extended van Hove singularity, potentially inducing correlated electronic phases. Intercalation also modifies the band structure: dopants may hybridize with carbon…

The effect of oxygen adsorption on the local structure and electronic properties of monolayer graphene grown on SiC(0001) has been studied by means of Low Energy Electron Microscopy (LEEM), microprobe Low Energy Electron Diffraction…

Materials Science · Physics 2015-06-05 C. Mathieu , B. Lalmi , T. O. Mentes , E. Pallecchi , A. Locatelli , S. Latil , R. Belkhou , A. Ouerghi

It is generally accepted that the hydrophilic property of graphene can be affected by the underlying substrate. However, the role of intrinsic vs. substrate contributions and the related mechanisms are vividly debated. Here we show that the…

Single-layer graphene structures and devices are commonly defined using reactive ion etching and plasma etching with O2 or Ar as the gaseous etchants. Although optical microscopy and Raman spectroscopy are widely used to determine the…

Materials Science · Physics 2013-05-21 Mariana C. Prado , Deep Jariwala , Tobin J. Marks , Mark C. Hersam

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

For carbon-based materials, in contrast to metal surfaces, the relationship between strain and reactivity is not yet established, even though there are literature reports on strained graphene. Knowledge of such relationships would be…

The interband and intraband conductivities of doped graphene were theoretically investigated beyond the linear response. The new dependences of induced currents on frequency and amplitude of external electric field, the graphene temperature…

Mesoscale and Nanoscale Physics · Physics 2013-08-19 B. M. Ruvinskii , M. A. Ruvinskii

Graphene is a promising material for sensing applications because of its large specific surface area and low noise. In many applications, graphene will inevitably be in contact with oxygen since it is the second most abundant gas in the…

Mesoscale and Nanoscale Physics · Physics 2023-09-12 Alexandro de Moraes Nogueira , Afsal Kareekunnan , Masashi Akabori , Hiroshi Mizuta , Manoharan Muruganathan

Application of graphene-type materials in electrocatalysis is a topic of growing scientific and technological interest. A tremendous amount of research has been carried out in the field of oxygen electroreduction, particularly with respect…

Materials Science · Physics 2018-05-23 Jerzy K. Zak , Enrico Negro , Iwona A. Rutkowska , Beata Dembinska , Vito Di Noto , Pawel J. Kulesza

Graphene-based sponges doped with atomic nitrogen and boron were applied for the electrochemical degradation of persistent organic contaminants in one-pass, flow-through mode, and in a low-conductivity supporting electrolyte. The B-doped…

Chemical Physics · Physics 2021-09-30 Luis Baptista-Pires , Giannis-Florjan Norra , Jelena Radjenovic

Graphene is a true two dimensional material with exceptional electronic properties and enormous potential for practical applications. Graphene's promise as a chemical sensor material has been noted but there has been relatively little work…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ye Lu , Brett R. Goldsmith , Nicholas J. Kybert , A. T. Charlie Johnson

High quality epitaxial graphene films can be applied as templates for tailoring graphene-substrate interfaces that allow for precise control of the charge carrier behavior in graphene through doping and many-body effects. By combining…

The production of multiple types of graphene, such as free standing, epitaxial graphene on silicon carbide and metals, graphene in solution, chemically grown graphene-like molecules, various graphene nanoribbons, and graphene oxide with…

Materials Science · Physics 2013-01-14 D. W. Boukhvalov

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

Graphene is a 2D material that displays excellent electronic transport properties with prospective applications in many fields. Inducing and controlling magnetism in the graphene layer, for instance by proximity of magnetic materials, may…

Contact angle goniometry is conducted for epitaxial graphene on SiC. Although only a single layer of epitaxial graphene exists on SiC, the contact angle drastically changes from 69{\deg} on SiC substrates to 92{\deg} with graphene. It is…

Efforts aimed at scaling fabrication processes to the level of single atoms, dubbed atom-by-atom fabrication or atomic fabrication, invariably encounter the obstacle of atomic scale cleanliness. When considering atomic fabrication,…

Materials Science · Physics 2024-12-03 Ondrej Dyck , Aisha Okmi , Kai Xiao , Sidong Lei , Andrew R. Lupini , Stephen Jesse

Hysteresis and commonly observed p-doping of graphene based field effect transistors (FET) was already discussed in reports over last few years. However, the interpretation of experimental works differs; and the mechanism behind the…

Mesoscale and Nanoscale Physics · Physics 2012-09-25 Alina Veligura , Paul J. Zomer , Ivan J. Vera-Marun , Csaba Józsa , Pavlo I. Gordiichuk , Bart J. van Wees