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Graphene is one of the most promising 2D materials for various applications due to its unique electronic properties and high thermal stability. In previous studies, it was shown that when graphene is deposited onto some transition metal…

Materials Science · Physics 2018-02-13 Tianbai Li , Jory A. Yarmoff

Chemically doped graphene could support plasmon excitations up to telecommunication or even visible frequencies. Apart from that, the presence of dopant may influence electron scattering mechanisms in graphene and thus impact the plasmon…

Materials Science · Physics 2017-10-06 Dino Novko

We report significant changes of optical conductivity in single layer graphene induced by mild oxygen plasma exposure, and explore the interplay between carrier doping, disorder, and many-body interactions from their signatures in the…

The chemical reactivity of graphene under ultraviolet (UV) light irradiation is investigated under positive and negative gate electric fields. Graphene edges are selectively etched when negative gate voltages are applied, while the…

Materials Science · Physics 2013-11-15 Nobuhiko Mitoma , Ryo Nouchi

Graphene modifications with oxygen or hydrogen are well known in contrast to carbon attachment to the graphene lattice. The chemical modification of graphene sheets with aromatic diazonium ions (carbon attachment) is analyzed by confocal…

Materials Science · Physics 2010-06-23 Fabian M. Koehler , Arnhild Jacobsen , Klaus Ensslin , Christoph Stampfer , Wendelin J. Stark

The environmental aging effect of doped graphene is investigated as a function of the organic doping species, humidity, and the number of graphene layers adjacent to the dopant by studies of the Raman spectroscopy, x-ray and ultraviolet…

Mesoscale and Nanoscale Physics · Physics 2016-08-17 J. -K. Chang , C. -C. Hsu , S. -Y. Liu , C. -I Wu , M. Gharib , N. -C. Yeh

Graphene is a fascinating 2D material that is being widely investigated for use in electronic devices due to its unique electronic and materials properties. Also, because of its high thermal stability and inertness, it is considered a…

Mesoscale and Nanoscale Physics · Physics 2017-10-25 Tianbai Li , Jory A. Yarmoff

Based on first principles density functional theory calculations we explored energetics of oxygen reduction reaction over pristine and nitrogen-doped graphene with different amounts of nitrogen doping. The process of oxygen reduction…

Materials Science · Physics 2012-05-04 Danil W. Boukhvalov , Young-Woo Son

With first-principles DFT calculations, the interaction between graphene and SiO2 surface has been analyzed by constructing the different configurations based on {\alpha}-quartz and cristobalite structures. The single layer graphene can…

Materials Science · Physics 2015-05-28 X. F. Fan , W. T. Zheng , Z. X. Shen , Jer-Lai Kuo

Graphene has recently attracted a great deal of interest in both academia and industry because of its unique electronic and optical properties [1,2], as well as its chemical, thermal, and mechanical properties. The superb characteristics of…

Materials Science · Physics 2010-06-29 Mingsheng Xu , Daisuke Fujita , Keisuke Sagisaka , Eiichiro Watanabe , Nobutaka Hanagata

Electronic properties of graphene oxides enriched by the strong chemical bondings are investigated using first-principle calculations. They are very sensitive to the changes in the number of graphene layer, stacking configuration, and…

Materials Science · Physics 2015-07-28 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Yu-Tsung Lin , Ming-Fa Lin

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au and Pt, while…

Materials Science · Physics 2009-11-13 G. Giovannetti , P. A. Khomyakov , G. Brocks , V. M. Karpan , J. van den Brink , P. J. Kelly

Adsorption of molecular oxygen on B-, N-, Al-, Si-, P-, Cr- and Mn-doped graphene is theoretically studied using density functional theory in order to clarify if O2 can change the possibility of using doped graphene for gas sensors,…

Mesoscale and Nanoscale Physics · Physics 2015-03-14 Jiayu Dai , Jianmin Yuan

Doped graphene sheets are pseudochiral two-dimensional Fermi liquids with abnormal electron-electron interaction physics. We address graphene's Fermi liquid properties quantitatively using a microscopic random-phase-approximation theory and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Marco Polini , Reza Asgari , Yafis Barlas , T. Pereg-Barnea , A. H. MacDonald

Graphene - a monolayer of carbon atoms densely packed into a hexagonal lattice - has one of the strongest possible atomic bonds and can be viewed as a robust atomic-scale scaffold, to which other chemical species can be attached without…

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

Using micro-Raman spectroscopy and scanning tunneling microscopy, we study the relationship between structural distortion and electrical hole doping of graphene on a silicon dioxide substrate. The observed upshift of the Raman G band…

Materials Science · Physics 2012-01-23 Sunmin Ryu , Li Liu , Stephane Berciaud , Young-Jun Yu , Haitao Liu , Philip Kim , George W. Flynn , Louis E. Brus

Although defects on graphene can degrade electron transport and its ability for use as a protection layer, they can also be helpful to tailor the local properties or activate new sites for particular adsorbates. Here, carbon vacancy defects…

Materials Science · Physics 2018-05-23 Tianbai Li , Jory A. Yarmoff

We have theoretically investigated the electronic and magnetic properties of graphene whose zigzag edges are oxidized. The alteration of these properties by adsorption of $\mathrm{H_{2}O}$ and $\mathrm{NH_3}$ molecules have been considered.…

Chemical Physics · Physics 2015-05-14 Julia Berashevich , Tapash Chakraborty

Graphene, due to its superior stretchability, exhibits rich structural deformation behaviors and its strain-engineering has proven useful in modifying its electronic and magnetic properties. Despite the strain-sensitivity of the Raman G and…

Materials Science · Physics 2012-09-04 Ji Eun Lee , Gwanghyun Ahn , Jihye Shim , Young Sik Lee , Sunmin Ryu
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